Physical Sciences and Mathematics Commons^™

Thermocatalytic Plasma-Assisted Dry Reforming Of Methane Over Ni/Al2o3 Catalyst, Tyler Wong

Seton Hall University Dissertations and Theses (ETDs)

Plasma catalysis is an advantageous approach that combines the effects of plasma with the enhancements of a catalyst. By utilizing a nickel catalyst in the plasma discharge zone of a dielectric barrier discharge (DBD), it can give an enhancement to the electrical field, boost microdischarges, and increase conversion and selectivity rates of CH₄ and CO₂ in the dry reforming of methane (DRM) reaction.

Industrial application of nickel catalysts in DBD Plasma DRM process are limited by poor stability, which is caused by the sintering of active metal particles and coke deposition on the catalyst surface. In this work, …

A Theoretical Study Of Elementary Processes In Interstellar Plasma, Joshua Forer

Graduate Thesis and Dissertation 2023-2024

Interstellar plasma — interstellar clouds in particular — play an important role in determining the structure and evolution of galaxies. Understanding the time evolution of such plasmas requires knowledge of the chemical processes that drive their dynamics. Two processes are studied in this dissertation: radiative electron attachment (REA) via dipole-bound states (DBSs) and dissociative recombination (DR). Of the several hundred molecules detected in the interstellar medium, only eight anions have been detected: CN-, C3N-, C5N-, C7N-, C4H-, C6H-, C8H-, and C10H-. Their production mechanism is not well known; REA was suggested as a possible formation pathway, but previous theoretical studies …

A Study Of Electron Plasma Oscillations Using The Nimrod Code, Mckay Murphy

All Graduate Plan B and other Reports, Spring 1920 to Spring 2023

A plasma, whether ”hot” or ”cold,” magnetized or unmagnetized, electrostatic or electromagnetic, exhibits normal modes of oscillation. Critical to understanding the stability of a plasma is the study of these normal modes. Waves originate from the long-range electric interactions between charged particles. This work will consider a class of waves known as Langmuir waves. These waves occur when a group of electrons are displaced with respect to the ions, with the electric Coulomb force playing the role of the restoring force of the oscillation [1]. Since the mass of ions is much greater than that of electrons, we can approximate …

Ultrashort Pulse Laser Filamentation Electrical And Optical Diagnostic Comparison, James E. Wymer

Optical Science and Engineering ETDs

Results presented here examine the effect of changing gas pressure on the radio frequency (RF) emissions of an ultrashort pulse laser filament plasma and how those emissions vary longitudinally in the laser focal region. We use a WR284 rectangular waveguide with a 1.5 cm hole that allows the beam through. A 3.2 GHz microwave signal is emitted in the waveguide, and signals are received through a waveguide-to-coax antenna connected to an HP8470B Schottky diode. By enabling and disabling the 3.2 GHz signal, we measure both the self-emitted RF from a USPL filament and subsequently the degree of attenuation a filament …

Electrothermal Plenum Thruster Simulations Varying Input Pressure And Voltage, Naomi Nicole Ingram

Open Access Theses & Dissertations

A radiofrequency electrothermal thruster is designed and simulated to create a low ionization energy plasma from a neutral propellant using a radio-frequency power. With an asymmetrical surface area ratio between the grounded and powered electrode, ion-neutral charge exchange collisions occurring within the propellant result in propellant heating. The Electrothermal Plenum Thruster conducts this propellant heating in an annular plenum chamber in attempt to maximize propellant heating. A software called CFD-ACE+ is utilized to demonstrate the effects of an enhanced sheath from the asymmetrical power coupling arrangement. Two sets of simulations are run to understand how input variables affect the plasma …

Whistler Waves: Modeling And Observations, Daniel Williams

Doctoral Dissertations and Master's Theses

The thesis presents the results of all the research from the published and in publication process research in the Journal of Geophysical Research [1]. This research focuses on whistler wave ducting events in the equatorial magnetosphere. High-density ducts are the main focus of whistler study in both studies as they are commonly observed by the Van Allen Probe satellites. A three-step procedure based on the analysis of the whistler wave dispersion relation and numerical simulations of the electron magnetohydrodynamics model. We use this model to identify the parallel and perpendicular wave numbers of the “most trapped” wave in an attempt …

Impurity Production And Transport In The Prototype Material Plasma Exposure Experiment, Clyde J. Beers

Doctoral Dissertations

The Prototype Material Plasma Exposure eXperiment (Proto-MPEX) is a linear pulse plasma device at Oak Ridge National Laboratory with the purpose of doing the research and development for the heating concepts on the planned full MPEX device. The goal of MPEX is to perform material studies at fusion relevant conditions. To understand the conditions at the material target for performing plasma-material interaction studies the ion temperature and density, the electron temperature and density, and the particle flux and fluence must be known. Impurities within Proto-MPEX can alter the desired conditions at the material target and need to be understood for …

Plasma-Laser Wakefield Acceleration, Jonathan Babu

Physics

Many texts detailing the derivations and science of Wakefield Acceleration are aimed at graduate and doctorate level scholars, and these may seem intimidating to new physics students. This paper is meant to be an introduction to the nature of plasmas, lasers, laser-plasma interactions, and Laser Wakefield Acceleration (LWFA), with sources given where extra detail may be required. I recognize that this paper is not meant to be an all-encompassing review on the nature of the topics, as these topics are complex and subject of entire textbooks. Instead, I aim to provide an introduction to these topics to a college-level scholar …

Plasma Aerodynamics: Experimental Quantification Of The Lift Force Generated On An Airfoil Using Plasma Actuation To Estimate Power Requirements In Small Uav Applications, Getachew Ashenafi

UNLV Theses, Dissertations, Professional Papers, and Capstones

This research addressed the amount of electric power required to induce specific changes in lift force using a NACA 2127 airfoil with a chord length of ~28 mm, connected to a micro load cell, in a wind tunnel of 103 square centimeter cross-section. A DBD plasma actuator supplied by a ZVS driven high voltage pulsed DC circuit, operating at a frequency of 17.4 kHz, was utilized for voltages of up to 5000 V. Two configurations of electrode gapping were compared to determine the efficient use of power. The configuration with a gap of ~1 mm between the upstream and downstream …

Finite Different Time-Domain Simulation Of Terahertz Waves Propagation Through Unmagnetized Plasma, Aditha Srikantha Senarath

Browse all Theses and Dissertations

In order to support ongoing terahertz time-domain spectroscopic experiments involving plasma characterization, it is beneficial to simulate the interaction of THz pulses with varying plasma configurations. In this approach, a 1-D Finite Difference Time Domain (FDTD) model was constructed to simulate the interaction of terahertz radiation with a plasma medium. In order to incorporate the plasma properties into the simulation, a Z-transformation was applied. This model is capable of simulating the following properties of plasmas including electron density, collision frequency, and the interaction length of the plasma medium. The simulated model was characterized using terahertz time-domain spectroscopy. The effects of …

Investigation Of The Chemical Kinetics In An Atmospheric Cold Plasma Towards Co2 Conversion, Daniel Piatek

Seton Hall University Dissertations and Theses (ETDs)

Hydrogenation of carbon dioxide (CO2) to methanol (CH3OH) is a promising route for utilization of excess and residual CO2. The conversion of CO to methanol is a well-developed process but the ability to use CO2 as a feed gas still requires high pressures (30-300 atm) to attain conversion. In this work, the hydrogenation of CO2 is explored using H2O as well as H2 in an atmospheric pressure nonthermal (cold) plasma created with a dielectric barrier discharge (DBD) reactor. Different gas mixtures such as argon (Ar) and helium (He) are used to understand their interactions in the process of CO2 hydrogenation. …

Characterization Of A Novel Double Cooled Electrode Dbd Reactor For Ozone Generation, Gustavo Duarte

Seton Hall University Dissertations and Theses (ETDs)

The Dielectric Barrier Discharge (DBD) is used to generate atmospheric or higher-pressure non-thermal plasmas and has found various commercial applications such as in industrial large-scale ozone generation. Ozone (O₃ ) is a powerful chemical reactant that is used to kill bacteria, to deodorize and to perform water purification. The effectiveness of the DBD reactors depends on the electrode arrangements, gap lengths, dielectric materials, operating gases and feed gas quality to name a few. However, the production of O₃ is heat sensitive. In order to prevent O₃ destruction thermal cooling of the DBD is needed. The industry approach …

Electrical And Chemical Characterization Of A Helium-Air Non-Thermal Atmospheric Pressure Plasma Jet, Adam Zandani

Seton Hall University Dissertations and Theses (ETDs)

Plasma is one of the most complicated, yet promising fields in physics due to its high efficiency and multitude of crucial applications such as biological sterilization, polymer modification, surface treatments, etching, agriculture, and facilitation of selective catalytic processes to name a few. With these advantages, mysteries still remain. With this in mind, in order to accurately gauge the total influence of the plasma applied in various processes, understanding what is being produced and how the production occurs is vital. To understand this, optical emission spectroscopy was used to gauge how the species generated are influenced by operation parameters such as …

Characterization Of A Plasma Source Simulating Solar Wind Plasma In A Vacuum Chamber, Blake Anthony Folta

Masters Theses

"The United States has set an aggressive time line to not only return to the Moon, but also to establish a sustained human presence. In the Apollo missions dust was a significant factor, but the duration of those missions was short so dust and surface charging were problems, but they did not pose an immediate threat. For a long-term mission, these problems instead become incredibly detrimental. Because of this, research needs to be conducted to investigate these phenomena so that mitigation techniques can be developed and tested. To this end, this thesis serves to demonstrate the Gas and Plasma Dynamics …

Evolution Of Electron Properties After Nanosecond Repetitively Pulsed Discharges In Air Measured By Thomson Scattering, Chase S. Murray

Browse all Theses and Dissertations

This work was an investigation of nanosecond repetitively pulsed discharges in air by measuring the evolution of electron density and electron temperature between pulses using Thomson scattering of laser light. Bursts of repetitive pulses within several microseconds after the initial pulse were found to exhibit a coupling effect and create an even higher electron density than the initial pulse. The wide range of temperatures and densities of the electrons existing between pulses allow an opportunity to explore both the collective and non-collective regimes of Thomson scattering. By measuring electron density and temperature at a variety of times, an accurate description …

One-Dimensional Kinetic Particle-In-Cell Simulations Of Various Plasma Distributions, Richard N. Vanderburgh

Browse all Theses and Dissertations

A one-dimensional kinetic particle-in-cell (PIC) MATLAB simulation was created to demonstrate the time-evolution of various plasma distributions. Building on previous plasma PIC programs written in FORTRAN and Python, this work recreates the computational and diagnostic tools of these packages in a more user- and educational-friendly development environment. Plasma quantities such as plasma frequency and species charge-mass ratios are arbitrarily defined. A one-dimensional spatial environment is defined by total length and number and size of spatial grid points. In the first time-step, charged particles are given initial positions and velocities on a spatial grid. After initialization, the program solves for the …

Designing A Modified Zeeman Slower For The Paschen-Back Magnetic Regime, Leo Michael Nofs

Master's Theses and Doctoral Dissertations

Controlled study of high-density plasmas, such as those found in fusion reactions and stars, is difficult due to their highly-magnetized environments. A specialized high magnetic field (High-B) trap was developed at the University of Michigan in Georg Raithel's research group to study such highly magnetized, high density plasmas using rubidium atoms. By replacing the atom source with a Zeeman slower, a well-studied device to slow and cool atoms, the atom flux could be increased by a factor more than 1000, leading to higher High-B plasma densities. The goal of this project is to design a Zeeman slower that differs from …

Evaluation Of X-Ray Spectroscopic Techniques For Determining Temperature And Density In Plasmas, Theodore Scott Lane

Graduate Theses, Dissertations, and Problem Reports

Temperature and density measurements of plasmas are important for understanding various phenomena. For example, equations of state, most scaling arguments for Inertial Confinement Fusion and laboratory astrophysics all rely upon accurate knowledge of temperature and density. Spectroscopy is a non-invasive technique to measure these quantities. In this work we establish a new spectroscopic technique by using it to determine temperature. We also compare and contrast the capability of two codes, PrismSPECT and ATOMIC, to infer electron density from experimentally acquired spectra via Stark broadening.

We compare and contrast the capability of isoelectronic line ratios and inter-stage line ratios in an …

A Multi-Frequency Study Of Arecibo Pulsars, Timothy Eugene Edward Olszanski

Graduate College Dissertations and Theses

Compact Objects (Neutron Stars) form in the last moments of a star's life, during the violent events known as supernovae. As the star's core fusion falters, matter undergoes a dramatic gravitational compression resulting in internal densities rivaling subatomic particles. Ever since their discovery in the mid-twentieth century, these highly magnetized and rapidly rotating balls of condensed matter have provided a bountiful playground for astronomers seeking out exotic physics.

Neutron Stars that emit electromagnetic radiation are seen by observers as Pulsars, named such for the pulse of intensity as the pulsar's radiation beam passes into our line of sight. These beams …

A Parallel Spectral Method Approach To Model Plasma Instabilities, Kevin S. Scheiman

Browse all Theses and Dissertations

The study of solar-terrestrial plasma is concerned with processes in magnetospheric, ionospheric, and cosmic-ray physics involving different particle species and even particles of different energy within a single species. Instabilities in space plasmas and the earth's atmosphere are driven by a multitude of free energy sources such as velocity shear, gravity, temperature anisotropy, electron, and, ion beams and currents. Microinstabilities such as Rayleigh-Taylor and Kelvin-Helmholtz instabilities are important for the understanding of plasma dynamics in presence of magnetic field and velocity shear. Modeling these turbulences is a computationally demanding processes; requiring large memory and suffer from excessively long runtimes. Previous …

Nonlinear Waves, Instabilities And Singularities In Plasma And Hydrodynamics, Denis Albertovich Silantyev

Mathematics & Statistics ETDs

This work concentrates on Langmuir wave filamentation instability in the kinetic regime of plasma and computation of Stokes wave with high precision using conformal maps.

Nonlinear effects are present in almost every area of science as soon as one tries to go beyond the first order approximation. In particular, nonlinear waves emerge in such areas as hydrodynamics, nonlinear optics, plasma physics, quantum physics, etc. The results of this work are related to nonlinear waves in two areas, plasma physics and hydrodynamics, united by concepts of instability, singularity and advanced numerical methods used for their investigation.

The first part of this …

On Laser-Induced Plasma Containing Hydrogen, Ghaneshwar Gautam

Doctoral Dissertations

Laser-induced micro-plasma dynamics are investigated in laboratory air, ultra-high-pure hydrogen gas, and hydrogen-nitrogen gas mixtures. The dissertation focuses on atomic spectroscopy of hydrogen in the visible region.

Line-of-sight measurements are analyzed to obtain spatial distributions of electron densities and excitation temperatures. The studies include evaluation of self-absorption phenomena. The plasma dynamics occur initially well above re-entry speeds and diminish to hypersonic and then supersonic expansions. Expansion velocities are measured that are above three hundred times the speed of sound in standard atmosphere. Optical breakdown is induced by using pulsed laser radiation. Emission spectra are collected by employing a spectrometer equipped …

Investigation Of Pyrolysis Gas Chemistry In An Inductively Coupled Plasma Facility, Corey Tillson

Graduate College Dissertations and Theses

The pyrolysis mechanics of Phenolic Impregnated Carbon Ablators (PICA) makes it a valued material for use in thermal protection systems for spacecraft atmospheric re-entry. The present study of the interaction of pyrolysis gases and char with plasma gases in the boundary layer over PICA and its substrate, FiberForm, extends previous work on this topic that has been done in the UVM 30 kW Inductively Coupled Plasma (ICP) Torch Facility. Exposure of these material samples separately to argon, nitrogen, oxygen, air, and carbon dioxide plasmas, and combinations of said test gases provides insight into the evolution of the pyrolysis gases as …

Intensity Control Of Dielectric Barrier Discharge Filaments, Matthew Crawford Paliwoda

Masters Theses

"When operated in a filamentary mode, a volume dielectric barrier discharge (DBD) is known to produce patterned plasma structures. These structures are currently being explored for reconfigurable metamaterial applications. In this work the presence and intensity of a single filament, within an array of filaments, was controlled by adjusting the voltage to that filament's individual needle electrode. The current, voltage, and time-averaged normalized light intensity were measured while varying the voltage of the needle through a self-biasing resistance. For a 7.5 kV, 3.2 kHz DBD in air, the needle-controlled filament intensity varies from that of the surrounding filaments to zero …

Improving The Efficiency And Resolution Of Time Of Flight (Tof) Mass Spectrometer For Magnetospheric Applications., Zain Abbas

Honors Theses and Capstones

The Earth magnetosphere is the volume of space formed by the Earth magnetic field in response to the flow of plasma from the solar wind. Although the magnetopause shields us from the solar wind there are far more particles that penetrate with energy, and momentum to the Earths magnetosphere and interacts with the Earth’s magnetic field to create various plasmas and currents which shape and couple different regions of magnetosphere. The study of the dynamics of ions in and outside of the magnetosphere is done through mass spectrometer. Over the years, CODIF Ion TOF spectrometer have been used to understand …

Construction And Optimization Of A Tapered Amplifier System For Applications In Ultra-Cold Plasma Research, Ryan Cole

Honors Theses

The number density of cold atoms confined in a magneto-optical trap (MOT) is critically dependent on the intensity of the lasers used to cool the sample. To generate large optical powers while retaining the practicality of homemade external cavity diode lasers (ECDLs), a tapered amplifier (TA) system was designed and constructed to amplify the output of an existing 780 nm, continuous-wave ECDL. The amplifier’s performance is discussed in terms of its gain and power output. Under standard operating conditions, optical amplification of 12 dB is achieved, with a maximum power output of 0.75 W. The completed amplifier is installed into …

Laser-Induced Breakdown Spectroscopy For Analysis Of High Density Methane-Oxygen Mixtures, Matthew Dackman

Masters Theses

The applicability of laser-induced breakdown spectroscopy (LIBS) toward greater than atmospheric density combustion diagnostics is examined. Specifically, this involves ascertaining the feasibility of measuring chemical equivalence ratios directly from atomic emission spectra at high density. The need for such measurement arises from the desire to quantify real time, localized combustion performance in weakly mixed flows. Insufficiently mixed flows generally result in unwanted byproducts, possess the propensity for overall combustion instability, and are increasingly likely to experience localized flame extinction.

We simulate methane/oxygen combustion in ambient pressures ranging 1 to 4 atmospheres, demonstrating these results to be analogous to what would …

Particle Swarms In Confining Geometries, Eric Robert Boomsma

Open Access Dissertations

The transport of micro- and nano-particles in subsurface fluid deposits is an area of increasing interest due to the rising use of these particles for consumer and industrial purposes. Subsurface particle transport is complicated by the presence of fractures and fracture networks which govern the paths that particles will be able to take. In this thesis, subsurface particle transport will be investigated using particle swarms; collections of hydro-dynamically interacting particles which exhibit group behavior. The effects of fluid viscosity, particle properties, fracture geometry, and fracture aperture on swarm behavior were experimentally investigated. ^ Swarm parameters were examined in time with …

High Resolution Time-Resolved Imaging System In The Vacuum Ultraviolet Region, Yuseong Jang

Electronic Theses and Dissertations

High-power debris-free vacuum ultraviolet (VUV) light sources have applications in several scientific and engineering areas, such as high volume manufacturing lithography and inspection tools in the semiconductor industry, as well as other applications in material processing and photochemistry. For the past decades, the semiconductor industry has been driven by what is called "Moore's Law". The entire semiconductor industry relies on this rule, which requires chip makers to pack transistors more tightly with every new generation of chips, shrinking the size of transistors. The ability to solve roadmap challenges is, at least partly, proportional to our ability to measure them. The …

Fully Coupled Fluid And Electrodynamic Modeling Of Plasmas: A Two-Fluid Isomorphism And A Strong Conservative Flux-Coupled Finite Volume Framework, Richard Joel Thompson

Doctoral Dissertations

Ideal and resistive magnetohydrodynamics (MHD) have long served as the incumbent framework for modeling plasmas of engineering interest. However, new applications, such as hypersonic flight and propulsion, plasma propulsion, plasma instability in engineering devices, charge separation effects and electromagnetic wave interaction effects may demand a higher-fidelity physical model. For these cases, the two-fluid plasma model or its limiting case of a single bulk fluid, which results in a single-fluid coupled system of the Navier-Stokes and Maxwell equations, is necessary and permits a deeper physical study than the MHD framework. At present, major challenges are imposed on solving these physical models …