Physical Sciences and Mathematics Commons^™

Theoretical Study Of Localized Surface Plasmons Of Metal Nanoparticles, Clusters And Embedded Metal Nanoparticles In Matrices, Masoud Shabani Nezhad Navrood

Dissertations

Localized surface plasmons resonances (LSPRs) in metallic nanoparticles (NPs) arise from the interactions between incident light and conduction electrons and have attracted enormous research interest in recent years both for their fundamental nature as well as applications in interdisciplinary areas of sciences such as biological imaging, plasmonic photo-thermal therapy, photovoltaics, and plasmonic sensors. LSPRs are strongly localized and depend on the shape, size, the composition of the NPs, the polarization direction of the incident light, refractive index (RI) of the surrounding medium as well as on the chemical environment that surrounded NPs. Although significant research has progressed both theoretically and …

High Resolution Solar Observations From First Principles To Applications, Angelo P. Verdoni

Dissertations

The expression "high-resolution observations" in Solar Physics refers to the spatial, temporal and spectral domains in their entirety. High-resolution observations of solar fine structure are a necessity to answer many of the intriguing questions related to solar activity. However, a researcher building instruments for high-resolution observations has to cope with the fact that these three domains often have diametrically opposed boundary conditions. Many factors have to be considered in the design of a successful instrument. Modern post-focus instruments are more closely linked with the solar telescopes that they serve than in past. In principle, the quest for high-resolution observations already …

Carbon Nanotube Electronic Structures As Anti-Corrosion Coatings, Sreeya Sreevatsa

Dissertations

A new concept of corrosion prevention is considered in this study. Diode-like and transistor-like structures have been fabricated and analyzed in the study of ionic flow through the resulting potential barriers. The structures were made of functionalized carbon nanotubes. Carbon nanotubes are known for many remarkable properties among which is being chemically inert. Taking advantage of this property, a study of corrosion of steel was undertaken.

In the first case study, successive layers of functionalized carbon nanotubes were deposited to form p-n junctions on steel substrates. It was demonstrated that the corrosion was indeed impeded by the potential barrier formed …

Probing The Complex Magnetic, Electronic And Structural Properties In Correlated Manganese Oxides, Peng Gao

Dissertations

Rare-earth Manganese Oxides (RMnO₃) exhibit two distinct structural phases: the orthorhombic structure and the hexagonal structure. The doped orthorhombic phase exhibits a metal to insulator transition, charge ordering and a strong response of electron transport properties to magnetic fields (colossal magneto-resistance). At low temperatures, this system may also exhibit a finite polarization which couples to external magnetic fields. The hexagonal phase is known to have a large spontaneous polarization at high temperatures which couples to the low temperature magnetic order. These materials are important from the basic point of view of understanding strong electronic correlations and …

Photoionization Of Rare Gas Clusters, Huaizhen Zhang

Dissertations

This thesis concentrates on the study of photoionization of van der Waals clusters with different cluster sizes. The goal of the experimental investigation is to understand the electronic structure of van der Waals clusters and the electronic dynamics. These studies are fundamental to understand the interaction between UV-X rays and clusters. The experiments were performed at the Advanced Light Source at Lawrence Berkeley National Laboratory. The experimental method employs angle-resolved time-of-flight photoelectron spectrometry, one of the most powerful methods for probing the electronic structure of atoms, molecules, clusters and solids.

The van der Waals cluster photoionization studies are focused on …

Entanglement Perturbation Theory For Antiferromagnetic Spin Chains, Lihua Wang

Dissertations

In this dissertation, we use the recently developed Entanglement Perturbation Theory (EPT) to solve antiferromagnetic spin chain problems, for both spin 1/2 and spin 1. We firs use EPT-g (EPT algorithm for ground state) to get the ground state properties. We calculated precisely energies, magnetization and spin-spin correlations. The precision of the long range spin-spin correlation functions for spin 1/2 chains is unprecedented. Due to its special structure, we also use EPT-g to calculate the firs excited state properties for spin 1 chains. Hence we plotted the phase diagram for spin 1 xxz chains. Also a generalization of EPT (EPT-e) …

African-American College Student Attitudes Toward Physics And Their Effect On Achievement, Carl Timothy Drake

Dissertations

The purpose of this study was to investigate factors affecting the attitudes that African-American college students have towards introductory college physics. The population targeted for this study consisted of African-American males and females enrolled in introductory college physics classes at an urban public historical black college or university (HBCU) located in the southeastern United States. Nine of the Fennema- Sherman Mathematics Attitude Scales, modified for physics, were used to analyze the attitudes of the 135 participants enrolled in an introductory college physics class. The nine scales used to measure the students' attitudes were Attitude Toward Success in Physics Scale (AS), …

Transmission And Guiding Of Fast Electrons Through Insulating Nanocapillaries And Comparison With Ion Guiding, Susanta Das

Dissertations

Transmission and guiding of fast electrons (500 and 1000 eV) through an insulating polyethylene terephthalate nanocapillary foil has been investigated and compared with results for slow highly charged ions. As for slow ions, guiding is attributed to charge-up of the inner walls near the capillary entrance, which, after a characteristic time, electrostatically deflects the traversing ions causing them to be guided through the sample along the capillary axis. The measurements were performed at WMU. Electron guiding is found to decrease faster with both energy and foil tilt angle than for ions. Ions lose negligible energy during the course of guiding, …

Terahertz Response Of Microfluidic-Jetted Fabricated 3d Flexible Metamaterials, Yew Li Hor

Dissertations

Conventional materials exhibit some restrictions on their electromagnetic properties. Especially in terahertz region, for example, materials that exhibit magnetic response are far less common in nature than materials that exhibit electric response. However, materials can be designed, namely artificial man-made metamaterials that exhibit electromagnetic properties that are not found in natural materials by adjusting, for example, the dielectric, magnetic or structural parameters of the constituent elements.

This dissertation demonstrates the use of new fabrication techniques to construct metamaterials in THz range via a material deposition system. The metamaterials are fabricated by stacking alternative layers with conventional designs such as single …

Synchrotron Radiation-Based Characterization Of Gan- Based Mqw Structures And Strongly Correlated Materials, Sean M. O'Malley

Dissertations

The following dissertation applies synchrotron radiation-based characterization techniques to the fields of gallium nitrides, multiferroic manganites, and self-assembled nano-domain oxide films. These material systems were chosen due to their unusual properties and potential device applications, which have made them very attractive to the scientific community.

Synchrotron-based High Resolution X-ray Diffraction (HRXRD) was used to characterize the structural properties of GaN-based multiple quantum well (MQW) structures grown on trapezoidal shaped GaN ridges. Results where interpreted within the framework of vapor-phase diffusion and surface-migration effects during the metalorganic vapor phase epitaxial growth. The relatively short diffusion length of group- III precursors and …

Characterization And Synthesis Of Nanoscale Materials, Jinfeng Wang

Dissertations

This dissertation focuses on the systematic study of techniques for characterization and synthesis of nanoscale materials. We have achieved several goals. Firstly, high number density uniform zinc oxide nanostructure growth has been achieved using thermal evaporation, through control of experimental parameters that include source material temperature, substrate temperature, substrate material, gas flow rate, and choice of catalyst. Aligned zinc oxide nanowires, randomly oriented zinc oxide nanowires, zinc oxide container-shaped structures, and zinc oxide nanobelts have been synthesized with high yield. Secondly, using a one parameter family of lattice fringe geometry curves, we show how to examine the epitaxial relationship between …