Physical Sciences and Mathematics Commons^™

Biomolecular Function From Structural Snapshots, Roshanak Etemadpour

Theses and Dissertations

Biological molecules can assume a continuous range of conformations during function. Near equilibrium, the Boltzmann relation connects a particular conformation's free energy to the conformation's occupation probability, thus giving rise to one or more energy landscapes. Biomolecular function proceeds along minimum-energy pathways on such landscapes. Consequently, a comprehensive understanding of biomolecular function often involves the determination of the free-energy landscapes and the identification of functionally relevant minimum-energy conformational paths on these landscapes. Specific techniques are necessary to determine continuous conformational spectra and identify functionally relevant conformational trajectories from a collection of raw single-particle snapshots from, e.g. cryogenic electron microscopy (cryo-EM) …

Two-Dimensional Crystal Phases Of Graphene Monoxide & Interaction Of Lithium With Graphene Monoxide, Danylo Radevych

Theses and Dissertations

This work explores the possible existence, properties, and potential applications of different polytypes of graphene monoxide (GmO) - two-dimensional crystalline monolayers composed of equal numbers of O and C atoms. In addition to previously experimentally discovered and theoretically modeled α phase, prediction and discovery of the second phase - β-GmO - is reported along with evaluation of six other possible phases. Structural parameters, electronic and mechanical properties of all the phases, including α-GmO, are determined using density functional calculations and compared. It is suggested that multiple phases of GmO can co-exist in the same composite, and developing a synthesis process …

Construction Of Zinc Oxide And Magnesium Oxide Heterostructures By Atomic Layer Deposition, Netra Sharma

Theses and Dissertations

Zinc oxide (ZnO) has gained wide technological interest due to its direct bandgap of ~3.37 eV and high exciton binding energy of ~60 meV and has exhibited promise for numerous electronics and opto-electronics applications. ZnO can also be alloyed with materials like magnesium oxide (MgO) to tailor the bandgap. Such heterostructures (Zn, Mg)O can be used in optoelectronic devices like quantum well lasers, photodetectors, etc.In this work, we studied the physical properties of zinc oxide (ZnO), magnesium oxide (MgO) and the heterostructures of zinc and magnesium oxide (Zn,Mg)O grown by atomic layer deposition (ALD) using a homemade viscous flow type …

Topological Superconductors And Dark Matter Searches In Gravitational Wave Interferometers, Han Gyeol Suh

Theses and Dissertations

This work is comprised of research in two areas: superconductors and gravitational waves.

Superconductors have led to novel fundamental discoveries, including new topological states. These states are robust, in that they are not altered by common changes to their environment. Here, I will introduce three studies focused on topological properties of various superconductors. First, newly proposed even-parity superconducting state in Sr$_2$RuO$_4$ introduces the emergence of topologically protected Bogoliubov Fermi surfaces. Next, I will discuss topological bands and odd-parity superconductivity in UTe$_2$, which suggest Weyl nodes and their potential topological properties. Lastly, anomalous pseudospin in non-symmorphic materials shows different symmetry properties …

Synthesis, Characterization, And Simulation Of Two-Dimensional Materials, Lawrence Hudy

Theses and Dissertations

ABSTRACT

SYNTHESIS, CHARACTERIZATION, AND SIMULATION OF TWO-DIMENSIONAL MATERIALS

by

Lawrence Hudy

The University of Wisconsin-Milwaukee, 2023Under the Supervision of Professor Michael Weinert

This dissertation focuses on my journey through many aspects of surface science leading to the first principles investigation of transition metal dichalcogenides studying the impact of defects, twist, and decreasing interlayer separation to probe their effect on the electronic properties of these materials. My journey started out learning many aspects of material science such as methods for material synthesis and characterization but later ended on simulation of material properties using density functional theory. In the first experiments, we …

Cellulose Nanocrystal Dielectric Elastomers, David Frailey

Theses and Dissertations

Optical devices, such as filters and sensors, have numerous advantages including compactness in size and immunity from electromagnetic interference. The fabrication of optical devices often requires precision and complicated processing, resulting in expensive and delicate components. Cellulose nanocrystals (CNCs) are biomaterials that can self-assemble into liquid crystals, similar to those used in electronic displays. This material can function as an optical grating by reflecting/transmitting circularly polarized light at certain wavelengths and viewing angles. Since gratings are building blocks of optical systems, like lasers and lidars, their fabrication at low costs will enable the further proliferation of optical technologies. Furthermore, if …