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Mechanisms And Dynamics Of The Metastable Decay In Ar-2(+), J. Fedor, K. Gluch, R. Parajuli, S. Matt-Leubner, Olof E. Echt, P. Scheier, T. D. Mark
Mechanisms And Dynamics Of The Metastable Decay In Ar-2(+), J. Fedor, K. Gluch, R. Parajuli, S. Matt-Leubner, Olof E. Echt, P. Scheier, T. D. Mark
Physics & Astronomy
A detailed experimental as well as theoretical investigation of the properties of the metastable dissociation Ar-2(+)-->Ar++Ar is presented. The mass-analyzed ion kinetic energy (MIKE) scan technique has been performed using a three sector field mass spectrometer. The possible mechanisms of the metastability of Ar-2(+) have been examined and the observed decay process is assigned to the II(1/2)(u)-->I(1/2)(g) bound to continuum radiative transition, in agreement with earlier work. The calculation of the theoretical shape of the kinetic energy release distribution of fragment ions allowed us to construct the theoretical MIKE peak and compare it with the raw experimental data. …
Kinetic-Energy Release In Coulomb Explosion Of Metastable C3h52+, K. Gluch, J. Fedor, S. Matt-Leubner, Olof E. Echt, A. Stamatovic, M. Probst, P. Scheier, T. D. Mark
Kinetic-Energy Release In Coulomb Explosion Of Metastable C3h52+, K. Gluch, J. Fedor, S. Matt-Leubner, Olof E. Echt, A. Stamatovic, M. Probst, P. Scheier, T. D. Mark
Physics & Astronomy
C3H52+, formed by electron impact ionization of propane, undergoes metastable decay into C2H2++CH3+. We have monitored this reaction in a magnetic mass spectrometer of reversed geometry that is equipped with two electric sectors (BEE geometry). Three different techniques were applied to identify the fragment ions and determine the kinetic-energy release (KER) of spontaneous Coulomb explosion of C3H52+ in the second and third field free regions of the mass spectrometer. The KER distribution is very narrow, with a width of about 3% [root-mean square standard deviation]. An average KER of 4.58+/-0.15 eV is derived from the distribution. High level ab initio …