Physical Sciences and Mathematics Commons^™

A Computational Kinetics Model To Quantify Radiation Induced Chemical Products Of Atmospheric Gas Mixtures, Patrick Ables

Dissertations

This research is focused on the development of a computational model which will calculate the effects of radiation on the chemical composition of the atmosphere. The approach utilizes the open-source chemical kinetics toolkit Cantera to model the creation of radiation-induced reactant species within irradiated air mixtures. Chemical solutions are iteratively stepped toward chemical equilibrium within a ‘constantly stirred’ (homogeneous) reactor of fixed volume. Three different radiation chemistry models are implemented in several different pulsed and continuous radiation schemes. The first model includes the mechanisms and rates of a pulse radiation model from the literature to test the validity of the …

Origin And Structure Of The First Sharp Diffraction Peak Of Amorphous Solids, Devilal Dahal

Dissertations

Several explanations have been reported in the literature about the origin of extended-range oscillations (EROs) in the atomic pair-correlation function of amorphous materials. Although the radial ordering beyond the short-range order of about 5 Å has been extensively studied in amorphous materials, the exact nature of the radial ordering beyond a nanometer is still not resolved. This dissertation address this problem and explains the nature of the EROs by using high-quality models of amorphous silicon (a-Si) obtained from Monte Carlo and Molecular Dynamics simulations. The extended-range ordering in a-Si is examined through radial oscillations on the length …

A New Model For Predicting The Drag And Lift Forces Of Turbulent Newtonian Flow On Arbitrarily Shaped Shells On The Seafloor, Carley R. Walker, James V. Lambers, Julian Simeonov

Dissertations

Currently, all forecasts of currents, waves, and seafloor evolution are limited by a lack of fundamental knowledge and the parameterization of small-scale processes at the seafloor-ocean interface. Commonly used Euler-Lagrange models for sediment transport require parameterizations of the drag and lift forces acting on the particles. However, current parameterizations for these forces only work for spherical particles. In this dissertation we propose a new method for predicting the drag and lift forces on arbitrarily shaped objects at arbitrary orientations with respect to the direction of flow that will ultimately provide models for predicting the sediment sorting processes that lead to …

Data-Driven Approaches To Complex Materials: Applications To Amorphous Solids, Dil Kumar Limbu

Dissertations

While conventional approaches to materials modeling made significant contributions and advanced our understanding of materials properties in the past decades, these approaches often cannot be applied to disordered materials (e.g., glasses) for which accurate total-energy functionals or forces are either not available or it is infeasible to employ due to computational complexities associated with modeling disordered solids in the absence of translational symmetry. In this dissertation, a number of information-driven probabilistic methods were developed for the structural determination of a range of materials including disordered solids to transition metal clusters. The ground-state structures of transition-metal clusters of iron, nickel, and …

Structural Origin Of Thermal, Mechanical Properties And Morphological Behaviors Of Semiconducting Polymers, Song Zhang

Dissertations

The past decades have witnessed a surging exploration of semiconducting polymers for the application of wearable and flexible organic electronic devices. Despite the increased amounts of molecular engineered polymers and their much-improved electrical performances, a systematic study of the structure-thermal/mechanical property-morphology relationship of semiconducting polymers is still less investigated.

To understand the thin-film mechanical properties, a pseudo-free standing tensile tester was self-built and utilized to obtain their real-time stress-strain behaviors through uniaxial stretching on top of the water surface. It also enables the first quantitative measurement of fracture energy on ultrathin polymeric films. Through multiple mechanical testing methods (i.e., strain-rate …

Perturbation Of Lagrange Points In Effective Potential Simulations, Swapnil Bhatta

Honors Theses

Lagrange points are analytically proven to exist at certain positions in a two-body gravitational system, simply as a function of the gravitational force governing the motion of the bodies and the centrifugal potential due to rotation, providing regions of varying effective potentials. In a system involving interactions between the gravitational forces of multiple bodies however, the position of the Lagrange points ought to change. The purpose of this research project is to verify that the change does indeed occur when a new body is introduced, and compute the perturbation in the position of these points given various parameters.

The Variability Of High-Frequency Motions And Their Interactions With The Mesoscale On The Mississippi Shelf, Jordan Earls

Master's Theses

In this study, we examine the spatial and temporal variability of high-frequency and low-frequency motions across the Mississippi Shelf and how the high-frequency motions are modulated by low-frequency mesoscale motions. For this purpose, we use Acoustic Doppler Current Profiler (ADCP) measurements collected at nearshore (23 m), mid-shelf (60 m), and shelf break (88 m) stations. High-frequency motions are defined as motions with periods less than 36 hours, whereas mesoscale motions have larger periods. The collected datasets are analyzed through bandpass filtering, least square harmonic analysis, spectral analysis, and empirical orthogonal functions (EOF). We find that along-shelf barotropic mesoscale motions contain …

Extended-Range Oscillations And The First Sharp Diffraction Peak In Amorphous Silicon: A Systematic Study, Devilal Dahal

Master's Theses

The first sharp diffraction peak (FSDP), which characterizes the static structure factor of many glassy systems near the wave vector region of 1-2 Å^-1 has been observed depending on the temperature, pressure and the degree of annealing of the system. The presence of the FSDP is indicative of the intermediate range order (IRO). In current work, we study the role of the extended- range oscillations on the parameters of the FSDP, i.e., intensity, position, area, and the full width at half maximum (FWHM) by using high-quality simulated models of amorphous silicon. The radial distance up to half of the …

Morphological Study Of Voids In Ultra-Large Models Of Amorphous Silicon, Durga Prasad Paudel

Dissertations

The microstructure of voids in pure and hydrogen-rich amorphous silicon (a:Si) network was studied in ultra-large models of amorphous silicon, using classical and quantum- mechanical simulations, on the nanometer length scale. The nanostructure, particularly voids of device grade ultra-large models of a:Si was studied, in which observed three-dimensional realistic voids were extended using geometrical approach within the experimental limit of void-volume fractions. In device-grade simulated models, the effect of void morphology; size, shape, number density, and distribution on simulated scattering intensities in small- angle region were investigated. The evolution of voids on annealing below the crystallization temperature …

Predicted Deepwater Bathymetry From Satellite Altimetry: Non-Fourier Transform Alternatives, Maxsimo Salazar

Dissertations

Robert Parker (1972) demonstrated the effectiveness of Fourier Transforms (FT) to compute gravitational potential anomalies caused by uneven, non-uniform layers of material. This important calculation relates the gravitational potential anomaly to sea-floor topography. As outlined by Sandwell and Smith (1997), a six-step procedure, utilizing the FT, then demonstrated how satellite altimetry measurements of marine geoid height are inverted into seafloor topography. However, FTs are not local in space and produce Gibb’s phenomenon around discontinuities. Seafloor features exhibit spatial locality and features such as seamounts and ridges often have sharp inclines. Initial tests compared the windowed-FT to wavelets in reconstruction of …

Computational Modeling Of Radiation Interactions With Molecular Nitrogen, Tyler Reese

Dissertations

The ability to detect radiation through identifying secondary effects it has on its surrounding medium would extend the range at which detections could be made and would be a valuable asset to many industries. The development of such a detection instrument requires an accurate prediction of these secondary effects. This research aims to improve on existing modeling techniques and help provide a method for predicting results for an affected medium in the presence of radioactive materials. A review of radioactivity and the interactions mechanisms for emitted particles as well as a brief history of the Monte Carlo Method and its …

A System For Conducting Laser-Induced Fluorescence Measurements On Gas Mixtures Exposed To Alpha Radiation, Patrick Ables

Master's Theses

This paper documents modifications to an existing vacuum system to allow laser-induced fluorescence spectroscopy measurements within simulated atmospheres under a variety of conditions. This added capability will expand the laboratory’s ability to experimentally validate a computational model that calculates the effects of radiation within the atmosphere. The computational model could reveal radiation-induced chemical products that can be used to develop an alternative detection method that can be implemented from a safe distance. The selection of molecules for experimental validation has been limited to those which can be detected utilizing cavity ringdown spectroscopy. The current model indicates nitric oxide and ozone …

Experimentally Investigating Water Aerosol Formation Via Alpha Radiation In A Humid Nitrogen Atmosphere, Megan Payne

Honors Theses

This project aims to verify the formation of water aerosols induced by an ionizing radiation source in a Nitrogen atmosphere with various levels of humidity. This work is part of an effort to characterize the overall signature of ionizing radiation in Earth’s typical atmosphere. By signature, it is meant all the chemical reactions and physical processes that take place between Earth’s atmosphere and the ionizing radiation. This signature can potentially be used to identify a radiation source out in the field. The identification of a radiation source could potentially be used in a variety of defense applications. To characterize this …

A Case Study In The Application Of Model-Based Systems Engineering To Laboratory Research Science, Brad Crochet

Dissertations

This dissertation presents an exploration of the application of Model-Based Systems Engineering (MBSE) tools and methods to the design and execution of sophisticated laboratory experiments. An experiment to measure the first excited state diffusion coefficient, recently attempted by the author, is used as an example. Several MBSE analysis methods are applied, retrospectively, to the process by which the experiment in question was planned and executed. The potential for increased efficiency in managing the diverse types of information associated with such laboratory experiments is demonstrated, as well as possible further avenues for future research.

Solution Of Pdes For First-Order Photobleaching Kinetics Using Krylov Subspace Spectral Methods, Somayyeh Sheikholeslami

Dissertations

We solve the first order reaction-diffusion equations which describe binding-diffusion kinetics using a photobleaching scanning profile of a confocal laser scanning microscope approximated by a Gaussian laser profile. We show how to solve these equations with prebleach steady-state initial conditions using a time-domain method known as a Krylov Subspace Spectral (KSS) method. KSS methods are explicit methods for solving time- dependent variable-coefficient partial differential equations (PDEs). KSS methods are advantageous compared to other methods because of their stability and their superior scalability. These advantages are obtained by applying Gaussian quadrature rules in the spectral domain developed by Golub and Meurant. …

Cavity Ringdown Spectroscopy In Nitrogen/Oxygen Mixtures In The Presence Of Alpha Radiation, Sidney John Gautrau

Master's Theses

This research was part of an effort to experimentally validate computational models under development for radiation-induced atmospheric effects. Cavity Ringdown Spectroscopy (CRDS) was used to measure the concentration of chemical products generated as a result of radiation interactions in a controlled atmosphere. Experiments were conducted in a vacuum chamber interfaced with a gas introduction system that controlled the initial atmospheric composition. A quadrupole mass spectrometer and tunable dye laser were integrated to confirm initial atmospheric composition, and provide wavelength flexibility for detecting a variety of chemical products generated by radiation interactions. CRDS measurements were made for ozone production resulting from …

Detection Of Acoustic Sources Using Time-Reversal Methods, Grant E. Tingstrom

Honors Theses

The goal of this research is to characterize the impact of using an equivalent-fluid method for a solid seabed on the use of time reversal procedures for detecting the origin location of an emitted sound. There are two different ways of modeling how sound propagates through water: modeling sound as a ray and modeling sound as a wave. It is easier to model the propagation of sound through water with a ray model; using a ray model allows for the collection of grazing angles with respect to the bottom. These will be important when determining bottom intensity loss of the …

Momentum Transfer To A Simplified Wind Turbine Blade, Myer D. Milbrath

Honors Theses

This project looks into the potential of simplified simulations as a supplement to wind turbine blade designs. The idea is to take a two-dimensional representation of a wind turbine blade and attempt to use a fluid flow simulation to determine which "aspect ratio" is the most efficient in the transfer of momentum. This is then compared to the current requirements for wind turbine blades to judge how accurate the simulation was. It was found that an aspect ratio of 16.66 percent was most efficient, however when compared to the requirements for a wind turbine blade this ratio only falls into …

Hydrogen Bond-Mediated Structural Order In Hydroxylated Bis-Mpa Dendritic Polymers: Experimental And Molecular Dynamics Simulation Study, Maliha N. Syed

Dissertations

Dendritic architectures are echoed throughout nature. While the significance of these pervasive patterns is not entirely clear, connections between their structures and physical properties are fascinating to contemplate. Particular interest has been paid to a family of synthetically manufactured and commercially available dendritic polymers based on 2,2-bis(hydroxymethyl) propionic acid (bis-MPA) as a monomer. Composed of two hydroxyls and a carboxyl group, bis-MPA based structures hydrogen bond (H-bond) profusely. Given the high concentration and unique spatial orientation of end-groups, as well as the multitude of carbonyl, ester, and ether interior H-bond acceptors, a set of distinct H-bond organizations may be observed …

Lorentz Invariant Spacelike Surfaces Of Constant Mean Curvature In Anti-De Sitter 3-Space, Jamie Patrick Lambert

Master's Theses

In this thesis, I studied Lorentz invariant spacelike surfaces with constant mean curvature H = c in the anti-de Sitter 3-space H³₁(−c²) of constant curvature −c². In particular, I construct Lorentz invariant spacelike surfaces of constant mean curvature c and maximal Lorentz invariant spacelike surfaces in H³₁(−c²). I also studied the limit behavior of those constant mean curvature c surfaces in H³₁(−c²). It turns out that they approach a maximal catenoid in Minkowski 3-space E³₁ as c → …

Relativistic And Non-Relativistic Proton-Nucleus Scattering, Kinsey Ann Elisabeth Zarske-Williamson

Honors Theses

Calculations for proton-nucleus scattering often rely on transition amplitudes. We implement new transition amplitudes [7] with the relativistic equations. We can find the matrix elements of the operators between the usual Dirac spinor basis or the helicity spinor basis. The operators can also be written as a linear combination of non-relativistic spin operators. To transform from one basis to another, we need to find a transformation matrix. We must establish what one of the factors that appears in the transformed expression means in order to correctly complete our transformation matrix. Once this is resolved, our transformation matrix will be complete.

Development And Applications Of The Expanded Equivalent Fluid Method, Bharath Kumar Kandula

Dissertations

Ocean acoustics is the study of sound in the oceans. Electromagnetic waves attenuate rapidly in the water medium. Sound is the best means to transmit information underwater. Computational numerical simulations play an important role in ocean acoustics. Simulations of acoustic propagation in the oceans are challenging due to the complexities involved in the ocean environment. Different methods have been developed to simulate underwater sound propagation. The Parabolic-Equation (PE) method is the best choice in several ocean acoustic problems. In shallow water acoustic experiments, sound loses some of its energy when it interacts with the bottom. An equivalent fluid technique was …

Microstructure, Vacancies And Voids In Hydrogenated Amorphous Silicon, Rajendra Timilsina

Dissertations

This dissertation presents a theoretical and computational study of microstructure, vacancies and voids in hydrogenated amorphous silicon (a-Si:H). The microstructure consists of all possible silicon-hydrogen bonding configurations such as SiH, SiH₂, SiH₃ and SiH₄. However, it is highly dominated (approximately 75% or even more) by monohydride (SiH) configurations. Furthermore, the hydrogen atoms locate in both clustered and diluted phases; as a result, the distribution becomes highly inhomogeneous. Approximately 5% of hydrogen atoms reside in a form of isolated monohydrides at the lower (7 at.%) concentration whereas such configurations do not appear at the higher concentrations …

Reification: A Process To Configure Java Realtime Processors, John Huddleston Heath

Dissertations

Real-time systems require stringent requirements both on the processor and the software application. The primary concern is speed and the predictability of execution times. In all real-time applications the developer must identify and calculate the worst case execution times (WCET) of their software. In almost all cases the processor design complexity impacts the analysis when calculating the WCET. Design features which impact this analysis include cache and instruction pipelining. With both cache and pipelining the time taken for a particular instruction can vary depending on cache and pipeline contents. When calculating the WCET the developer must ignore the speed advantages …

Effect Of Compactified Dimensions On The Ground State Energy Of The Hydrogen Atom, Floyd Maseda

Honors Theses

The three-dimensional Hydrogen atom has been explored extensively, and a wavefunction and energy expression can be found in closed form. Little work, however, has been done with higher-dimensional atoms. This discussion focuses on the effects of adding first one then two compactified dimensions to a Hydrogen atom. The metric of the 4-D Hydrogen atom is taken to be R3 × S1 while the 5-D metric is taken to be R3 × S2. We first determine the form of the Laplacian operator in each space and use it to find the respective atomic potentials. The variational method is used to determine …

A System For Measuring Radiation Induced Chemical Products In Atmospheric Gases Using Optical Detection Methods, Tyler Webster Reese

Master's Theses

This research is a part of an effort to characterize the chemical products generated by radiation interacting with atmosphere. One method of detecting ionizing radiation is to monitor the radiation induced products in the atmosphere around the source. This project explored the potential for using Cavity Ringdown Spectroscopy to evaluate the presence of chemical products generated by the air-radiation interaction near an alpha radiation source. In particular, measurements of ozone concentration within a controlled atmosphere chamber as affected by radiation exposure were obtained.

The first portion of this thesis provides brief reviews of ionizing radiation and ozone formation as well …

Relativistic Studies Of The Charmonium And Bottomonium Systems Using The Sucher Equation, Charles Martin Werneth

Dissertations

In this dissertation, bound states of quarks and anti-quarks (mesons) are studied with a relativistic equation known as the Sucher equation. Prior to the work in this dissertation, the Sucher equation had never been used for meson mass spectra. Furthermore, a full angular momentum analysis of the Sucher equation has never been studied. The Sucher equation is a relativistic equation with positive energy projectors imposed on the interaction. Since spin is inherent to the equation, the Sucher equation is equivalent to a relativistic Schrödinger equation with a spin-dependent effective potential. Through a complete general angular momentum analysis of the equation, …

Studies Of Meson Mass Spectra In The Context Of Quark-Antiquark Bound States, Mallika Dhar

Dissertations

This dissertation deals with the computation of meson mass spectra in the context of quarkantiquark (q ¯ q) bound-state. Traditionally the q ¯ q bound-state problem is treated by solving the non-relativistic Schrödinger equation in position representation with a linear confining potential and a Coulomb-like attractive potential. For high energy, relativistic kinematics is necessary. It is well known that relativistic kinematics cannot be treated properly in position representation, but it can easily be handled in momentum representation. On the other hand, the linear potential and Coulomb-like potential have singularities in momentum-space and complicated subtraction procedure is necessary to treat the …

African-American College Student Attitudes Toward Physics And Their Effect On Achievement, Carl Timothy Drake

Dissertations

The purpose of this study was to investigate factors affecting the attitudes that African-American college students have towards introductory college physics. The population targeted for this study consisted of African-American males and females enrolled in introductory college physics classes at an urban public historical black college or university (HBCU) located in the southeastern United States. Nine of the Fennema- Sherman Mathematics Attitude Scales, modified for physics, were used to analyze the attitudes of the 135 participants enrolled in an introductory college physics class. The nine scales used to measure the students' attitudes were Attitude Toward Success in Physics Scale (AS), …