Physical Sciences and Mathematics Commons^™

Investigation Of Prussian Blue Analogues As Cathode Materials For Next Generation Batteries, Neal Walters Kuperman

Dissertations and Theses

Since the beginning of the industrial revolution, the average global temperature has risen about 1 °C due increases in anthropogenic greenhouse gases emitted into the atmosphere. Of all human produced greenhouse gases, carbon dioxide is the most prevalent, with the production of electricity from fossil fuels being the major contributor.

Solar and wind power are promising net zero emission energy sources but only accounted for ~5% of global electricity generation in 2016. The most significant hurdle hindering their widespread adoption is the intermittent nature of the electricity generation. To overcome this limitation, significant resources need to be put into the …

The Gauge Principle From The Schrodinger-Born Wave Mechanics, P. T. Leung

Physics Faculty Publications and Presentations

We propose an elementary way of introducing the gauge principle to beginners with a background in only mechanics, electromagnetism, and quantum mechanics. This evolves from an apparent conflict in the Schrodinger-Born formulation of wave mechanics, and does not have to resort to advanced concepts like covariant derivative and minimal coupling. With such an approach, one would have appreciated how interactions can be dictated from consideration of internal symmetry of a physical system, which serves as a principle underlying the foundation of almost all modern physics. In addition, the gauge principle also serves as a resource providing consistency between the Born …

Genetically Encoded Phase Contrast Agents For Digital Holographic Microscopy, Arash Farhadi, Manuel Bedrossian, Justin Lee, Gabrielle H. Ho, Mikhail G. Shapiro, Jay Nadeau

Physics Faculty Publications and Presentations

Quantitative phase imaging and digital holographic microscopy have shown great promise for visualizing the motion, structure and physiology of microorganisms and mammalian cells in three dimensions. However, these imaging techniques currently lack molecular contrast agents analogous to the fluorescent dyes and proteins that have revolutionized fluorescence microscopy. Here we introduce the first genetically encodable phase contrast agents based on gas vesicles. The relatively low index of refraction of the air-filled core of gas vesicles results in optical phase advancement relative to aqueous media, making them a “positive” phase contrast agent easily distinguished from organelles, dyes, or microminerals. We demonstrate this …

Investigation Of Magnetism In Transition Metal Chalcogenide Thin Films, Michael Adventure Hopkins

Dissertations and Theses

Layered two dimensional films have been a topic of interest in the materials science community driven by the intriguing properties demonstrated in graphene. Tunable layer dependent electrical and magnetic properties have been shown in these materials and the ability to grow in the hexagonal phase provides opportunities to grow isostructural stacked heterostructures. In this investigation, cobalt selenide (CoSe) and nickel selenide (NiSe) were grown in the hexagonal phase, which consist of central metal atoms that are natively ferromagnetic in bulk, hence providing the potential for interesting magnetic phases in thin film arrangements as well. These structures may play a role …

Electromagnetic Reciprocity In The Presence Of Topological Insulators, Huai-Yi Xie, P. T. Leung

Physics Faculty Publications and Presentations

Electromagnetic reciprocity is studied in the presence of topological insulators (TI) with application of axion electrodynamics for harmonic electromagnetic fields. The corresponding generalized Lorentz and Feld-Tai type lemmas are derived in terms of the axion coupling parameter, and their correlation to the conditional symmetry in source-observer coordinates for the various Green dyadics is established subjected to different types of boundary conditions. Possible application of the results to the probing of the topological magneto-electric effects from TI is discussed.

Reducing A Class Of Two-Dimensional Integrals To One-Dimension With An Application To Gaussian Transforms, Jack C. Straton

Physics Faculty Publications and Presentations

Quantum theory is awash in multidimensional integrals that contain exponentials in the integration variables, their inverses, and inverse polynomials of those variables. The present paper introduces a means to reduce pairs of such integrals to one dimension when the integrand contains powers multiplied by an arbitrary function of xy/ (x + y) multiplying various combinations of exponentials. In some cases these exponentials arise directly from transition-amplitudes involving products of plane waves, hydrogenic wave functions, and Yukawa and/or Coulomb potentials. In other cases these exponentials arise from Gaussian transforms of such functions.

Numerical Model Of A Radio Frequency Ion Source For Fusion Plasma Using Particle-In-Cell And Finite Difference Time Domain, Augustin L. Griswold

University Honors Theses

Radio frequency (RF) plasma sources are common tool for application and study, and of particular interest for inertial electrostatic (IEC) fusion. Computational analysis is often carried out using particle in cell (PIC) methods or finite difference time domain (FDTD). However, a more holistic analysis is necessary as the particle distribution is highly dependant on the fields created by the plasma source. Herein, an analysis of a particular planar RF electrode with deuterium gas is provided which covers the fields and the particle behaviour using first FDTD then PIC. Further applications are discussed as well as further directions for this study.

A New Look At The Quantum Liouville Theorem, P. T. Leung, G. I. Ni

Physics Faculty Publications and Presentations

We clarify certain confusions in the literature of the density operator in quantum mechanics, and demonstrate that the quantum Liouville theorem has the same form in both the Schrodinger and the Heisenberg pictures. Our starting point is to treat the density operator as an observable which has its specific time dependence in each of the two pictures. It is further shown that such a formulation will provide the exact correspondence between classical and quantum statistical mechanics with the Liouville theorem being interpreted as a conservation law, which is derivable from the equation of motion only in the quantum case.

Improving The Understanding Of Jet Grooming In Perturbation Theory, Andrew J. Larkoski

Portland Institute for Computational Science Publications

Jet grooming has emerged as a necessary and powerful tool in a precision jet physics program. In this paper, we present three results on jet grooming in perturbation theory, focusing on heavy jet mass in e⁺e⁻ → hadrons collisions, groomed with the modified mass drop tagger. First, we calculate the analytic cross section at leading-order. Second, using the leading-order result and numerical results through next-to-next-to-leading order, we show that cusps in the distribution on the interior of phase space at leading-order are softened at higher orders. Finally, using analytic and numerical results, we show that terms that …

Analytical Results For The Three-Body Radiative Attachment Rate Coefficient, With Application To The Positive Antihydrogen Ion H̄+, Jack C. Straton

Physics Faculty Publications and Presentations

To overcome the numerical difficulties inherent in the Maxwell–Boltzmann integral of the velocity-weighted cross section that gives the radiative attachment rate coefficient αRA for producing the negative hydrogen ion H⁻ or its antimatter equivalent, the positive antihydrogen ion H¯⁺ , we found the analytic form for this integral. This procedure is useful for temperatures below 700 K, the region for which the production of H¯⁺ has potential use as an intermediate stage in the cooling of antihydrogen to ultra-cold (sub-mK) temperatures for spectroscopic studies and probing the gravitational interaction of the anti-atom. Our results, utilizing a 50-term …

Groomed Jet Mass At High Precision, Adam Kardos, Andrew J. Larkoski, Zoltán Trócsányi

Portland Institute for Computational Science Publications

We present predictions of the distribution of groomed heavy jet mass in electron-positron collisions at the next-to-next-to-leading order accuracy matched with the resummation of large logarithms to next-to-next-to-next-to-leading logarithmic accuracy. Resummation at this accuracy is possible through extraction of necessary two-loop constants and three-loop anomalous dimensions from fixed-order codes.

Teaching Doppler Ultrasound In An Introductory Laboratory For Pre-Health Students, Theodore Stedmark, Thomas Allen, Ralf Widenhorn

Physics Faculty Publications and Presentations

We present a novel activity to demonstrate the Doppler shift of a sound wave, incident at an angle, upon a moving reflector. This activity is intended for use in an introductory physics laboratory focused on preparing students for the health and medical fields. The activity is designed to simulate Doppler velocity measurements from ultrasound imaging. While there have been previous qualitative discussions of blood flow measurements in the physics education literature, they were without associated laboratory activities.1 The lab can be part of a life science physics curriculum that has been identified in need of reforms to meet the …

Polarization In The Production Of The Antihydrogen Ion, Casey A. Yazejian, Jack C. Straton

Physics Faculty Publications and Presentations

We provide estimates of both the cross section and rate coefficient for the radiative attachment of a second positron to create the H̅+ ion, H̅(1s)+e+→H̅+(1s2 1Se)+ℏω, for which the polarization of the initial state H̅(1s) is taken into account. We show how to analytically integrate the resulting six-dimensional, three-body integrals for wave functions composed of explicitly correlated exponentials, a result that may be extended to Hylleraas wave functions. We extend Bhatia’s polarization results for the equivalent matter problem down to the low temperatures required for the Gravitational Behaviour of Antihydrogen …

Characterization Of Retinol Stabilized In Phosphatidylcholine Vesicles With And Without Antioxidants, Yekaterina G. Chmykh, Jay Nadeau

Physics Faculty Publications and Presentations

Retinol stability has been reported to be improved by encapsulation in liposomes, both with and without cholesterol. However, this improvement is limited because of lipid peroxidation. In this study, we compare the stability of retinol in phosphatidylcholine liposomes under ultraviolet (UV) light or standard room air, with and without the addition of antioxidants. Both butylated hydroxytoluene (BHT) and a proprietary mix (StoppOx) improved the shelf stability from vesicles, including within the aqueous layer. Fluorescence lifetimes were equally heterogeneous. Under UV irradiation, StoppOx protected retinol for significantly longer than BHT and via different mechanisms. This suggests that natural antioxidants work well …

Membraneless H2o2 Fuel Cells Driven By Metallophthalocyanine Electrocatalysts, Bao Nguyen, Neal Kuperman, Gary Goncher, Raj Solanski

Physics Faculty Publications and Presentations

One-compartment hydrogen peroxide fuel cells with Co, Cu, and Fe phthalocyanine (PC) and iron nitride (FexN) as cathodes and Ni anode have been investigated as sustainable energy sources. The cells were operated under acidic conditions and at room temperature. The potentials for onset of the catalytic currents in these cells were determined via cyclic voltammograms. The reduction current onset potentials of FePC, CoPC, CuPC and FexN were 0.56 V, 0.42 V, 0.51 V and 0.57 V, respectively. Potentialcurrent linear sweep voltammetry was utilized to determine the open circuit potentials (OCP) and the power densities the fuel cells. The OCPs for …

Enhancing Final Image Contrast In Off-Axis Digital Holography Using Residual Fringes, Manuel Bedrossian, Kent Wallace, Eugene Serabyn, Chris Lindensmith, Jay Nadeau

Physics Faculty Publications and Presentations

We show that background fringe-pattern subtraction is a useful technique for removing static noise from off-axis holographic reconstructions and can enhance image contrast in volumetric reconstructions by an order of magnitude in the case for instruments with relatively stable fringes. We demonstrate the fundamental principle of this technique and introduce some practical considerations that must be made when implementing this scheme, such as quantifying fringe stability. This work also shows an experimental verification of the background fringe subtraction scheme using various biological samples.

Predicting Densities And Elastic Moduli Of Sio2-Based Glasses By Machine Learning, Yong-Jie Hu, Ge Zhao, Mingfei Zhang, Bin Bin, Tyler Del Rose, Qian Zhao, Qan Zu, Yang Chen, Xuekun Sun, Maarten De Jong, Multiple Additional Authors

Mathematics and Statistics Faculty Publications and Presentations

Chemical design of SiO2-based glasses with high elastic moduli and low weight is of great interest. However, it is difficult to find a universal expression to predict the elastic moduli according to the glass composition before synthesis since the elastic moduli are a complex function of interatomic bonds and their ordering at different length scales. Here we show that the densities and elastic moduli of SiO2-based glasses can be efficiently predicted by machine learning (ML) techniques across a complex compositional space with multiple (>10) types of additive oxides besides SiO2. Our machine learning approach relies on a training set …