Physical Sciences and Mathematics Commons^™

Time Resolved X-Ray Spectroscopy Of Highly Charged Ar, Nd, And Pr, Timothy Burke

All Dissertations

Highly Charged Ions (HCIs) may be considered ideal mini-laboratory in which one can study the physics of matter and light in an environment of high internal electric field that can not be recreated with standard lab equipment. The remaining electron(s) exist in the extremely large electric field of the nucleus and therefore measurements of electronic transitions in these systems provide stringent tests of our understanding of physics in extreme conditions. Quantum electrodynamics (QED) despite being a powerful theory exhibits large discrepancies for systems under extreme conditions. The work here investigates the atomic properties within non-Maxwellian plasmas. The HCI plasmas studied …

Oscillations Of Capillary Surfaces With Volume And Edge Effects, Dingqian Ding

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Capillary surfaces are defined by an interface endowed with surface tension that is partially supported by a solid substrate and are susceptible to oscillations reflecting a balance between fluid inertia and the restorative force of surface tension. The wave dynamics strongly depend upon volume change within the domain and edge effects through the boundary conditions applied at the contact-line formed at the liquid-gas-solid interface, while the spatial wave structure conforms to the geometry of the capillary surface. This dissertation develops mathematical models to address these effects for several canonical capillary surfaces, which are organized into two parts that are focused …

Numerical Simulation Of Laser Induced Elastic Waves In Response To Short And Ultrashort Laser Pulses., Alireza Zarei

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In an era of intensified market competition, the demand for cost-effective, high-quality, high-performance, and reliable products continues to rise. Meeting this demand necessitates the mass production of premium products through the integration of cutting-edge technologies and advanced materials while ensuring their integrity and safety. In this context, Nondestructive Testing (NDT) techniques emerge as indispensable tools for guaranteeing the integrity, reliability, and safety of products across diverse industries.

Various NDT techniques, including ultrasonic testing, computed tomography, thermography, and acoustic emissions, have long served as cornerstones for inspecting materials and structures. Among these, ultrasonic testing stands out as the most prevalent method, …

Photobiomodulation Of Bovine Oocytes During Maturation Increases Atp Content And Enhances Subsequent Embryonic Development, Kendall Richey

All Theses

Bovine in-vitro production(IVP) of embryos is a growing field for producing offspring with desirable genetics in the cattle industries. While IVP is effective, oocyte cytoplasmic maturation is compromised, and bovine oocytes matured in-vitro have reduced metabolic activity than those matured in-vivo. Mitochondria are the central unit of oocyte metabolism, producing ATP through OXPHOS. Photobiomodulation is a light treatment reported to improve metabolic activity. In five experiments, we measured the effects of photobiomodulation treatment with red LED at 16-(L-16) and 20 h(L-20) of bovine oocyte in-vitro maturation on subsequent embryonic development, mitochondrial activity and nuclear progression. Bovine COCs were aspirated …

Design, Fabrication, And Characterization Of Advanced High-Power Single-Mode 9xxnm Semiconductor Lasers, Xiaolei Zhao

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This thesis presents the comprehensive design, fabrication, and demonstration of advanced high-power, high-efficiency single-mode semiconductor lasers operating at a wavelength of 9xxnm. We begin with the design of the laser epitaxial structure, serving as the cornerstone for achieving high-power high-efficiency lasers. Our methodology integrates a semi-analytical calculation model, which accounts for Longitudinal Spatial Hole Burning (LSHB) and Two-Photon Absorption (TPA) effects, facilitating a thorough exploration of how design parameters influence output power and conversion efficiency. This approach offers an effective and time-efficient epitaxial structure optimization strategy compared to conventional full 3D simulation models.

Subsequently, we demonstrate high-power, high-efficiency ridge waveguide …

Redesign Of X-Ray Irradiator To Expand Research Of Low-Dose X-Ray Radiation, Lauren Ulbrich

All Theses

The effects of high-dose radiation are well-documented, and are understood to be harmful to the human body. On the other hand, the effects of low-dose radiation are much less understood. There is debate over whether or not there are negative, positive, or no effects at all from low-dose radiation. One of the reasons why these effects are not well known is because there aren't as many studies done on this type of radiation. It is a lot harder to classify the effects of radiation at low doses due to many external factors. However, the Clemson Medical Physics lab has been …

Mechanical And Thermal Measurement Techniques For Crystalline-Core/Crystalline-Clad Optical Fibers, Evan Watkins

All Theses

Optical fiber laser systems offer advantages such as high optical gain, efficient cooling, and the production of high-quality optical beams. Fiber lasers are characterized by their unique core-cladding structure, providing optical benefits and mechanical properties that impact their performance. Interests in materials such as yttrium aluminum garnets (YAG) and lutetium oxide (Lu2O3 also lutetia) as laser mediums are due to their high average power capabilities, but thermal management remains a challenge. This thesis discusses the choice of ytterbium (Yb3+) as a dopant in YAG and lutetia, exploring its electronic structure and relevance to thermal properties. The thesis focuses on the …

Experimental Analyses Of Emission Lines In The Uv/Vis/Nir Range For Astrophysically-Important Elements: From The Iron Group To R-Process Elements, Brynna Neff

All Dissertations

Analysis of astrophysical phenomena requires an understanding of the electronic

structure and transition probabilities of the elements present in that environment,

yet there are still many charge states of heavy elements whose electronic

structures and spectroscopic properties are not yet well understood. To address this,

we investigated the spectroscopic properties of three different elements through an

analysis of spectra collected from three different experimental apparatuses.

In order to better understand the spectroscopic properties of Ni I and II, we

analyzed spectra collected from the Compact Toroidal Hybrid (CTH) apparatus at

Auburn University. In this experiment, a nickel sample was inserted …

Radiation Exposure Calibration Of The Al2o3:C With Radium-226 And Cesium-137 Using The Osl Method, Selma Tepeli Aydin

All Theses

Optically stimulated luminescence (OSL) dosimetry was utilized to calibrate Al₂O₃:C powder dosimeters, available commercially as the nanoDot® from Landauer Inc., and compare the dosimeter response to radium-226 (²²⁶Ra) and cesium-137 (¹³⁷Cs). The signal from the OSL was quantified using a microSTARii^® OSL reader also produced by Landauer Inc. Dose-response curves were developed for ²²⁶Ra and ¹³⁷Cs experiments (5 dosimeters each) at thirteen absorbed doses. Individual dosimeter response was tracked by serial number. Linear regression analysis was performed to determine if there were significant differences between the intercepts of the …

Aspects Of Stochastic Geometric Mechanics In Molecular Biophysics, David Frost

All Dissertations

In confocal single-molecule FRET experiments, the joint distribution of FRET efficiency and donor lifetime distribution can reveal underlying molecular conformational dynamics via deviation from their theoretical Forster relationship. This shift is referred to as a dynamic shift. In this study, we investigate the influence of the free energy landscape in protein conformational dynamics on the dynamic shift by simulation of the associated continuum reaction coordinate Langevin dynamics, yielding a deeper understanding of the dynamic and structural information in the joint FRET efficiency and donor lifetime distribution. We develop novel Langevin models for the dye linker dynamics, including rotational dynamics, based …

Controlled Manipulation And Transport By Microswimmers In Stokes Flows, Jake Buzhardt

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Remotely actuated microscale swimming robots have the potential to revolutionize many aspects of biomedicine. However, for the longterm goals of this field of research to be achievable, it is necessary to develop modelling, simulation, and control strategies which effectively and efficiently account for not only the motion of individual swimmers, but also the complex interactions of such swimmers with their environment including other nearby swimmers, boundaries, other cargo and passive particles, and the fluid medium itself. The aim of this thesis is to study these problems in simulation from the perspective of controls and dynamical systems, with a particular focus …

Nonlinear Charge And Spin Currents In Non-Centrosymmetric Electron Systems, Aniruddha Pan

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In this thesis, we discuss the existence of spin and charge currents in systems with broken spin inversion symmetry proportional to the magnitude square of the driving electric and thermal fields. This outcome is predicated on symmetry considerations in the momentum space, whereby the product between the current operator and the out-of-equilibrium distribution function has to be even.

First, we derive the second-order correction to the particle distribution function $\delta f^{(2)}$ in a semi-classical approximation, considering the local change in the equilibrium distribution function caused by external fields. Our approach departs significantly from the previous theory where $\delta f^{(2)}$ is …

Hybridly Integrated Semiconductor Lasers And Amplifiers On Iii-V/Si3n4 Platform For Beam Combining And Other Advanced Applications, Siwei Zeng

All Dissertations

Photonic integrated circuits (PICs) are devices that integrate multiple photonic functions on a small chip and allow for accurate dimension control and massive production. Similar to electronic integrated circuits, PICs can significantly reduce the system cost, size, weight, and operation power (CSWaP). Recently, the PIC technology has transformed many optical technologies which traditionally rely on tabletop systems and bulky components, such as optical interconnects, nonlinear optics, and quantum photonics, into a chip-scale platform. This device and system miniaturization has successfully led to a wide range of practical applications in computing, sensing, spectroscopy, and communication. However, the traditional passive PIC platform …

The Influence Of Allostery Governing The Changes In Protein Dynamics Upon Substitution, Joseph Hess

All Dissertations

The focus of this research is to investigate the effects of allostery on the function/activity of an enzyme, human immunodeficiency virus type 1 (HIV-1) protease, using well-defined statistical analyses of the dynamic changes of the protein and variants with unique single point substitutions ¹. The experimental data¹ evaluated here only characterized HIV-1 protease with one of its potential target substrates. Probing the dynamic interactions of the residues of an enzyme and its variants can offer insight of the developmental importance for allosteric signaling and their connection to a protein’s function. The realignment of the secondary structure elements can …

Study Of Highly Charged Ion Charge Exchange With Applications To X-Ray Astrophysics, Richard Mattish

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Highly charged ions (HCIs) exist in many hot astrophysical environments where they play an important role in plasma dynamics. Charge exchange involving highly charged ions has been shown to be responsible for many observed X-ray emissions from a variety of astrophysical sources. Proper modeling of these environments requires an understanding of this process, including the electronic structure of each ion species as well as their charge exchange cross sections. This dissertation investigates charge exchange processes with highly charged ions which are present in astrophysical environments via a laboratory-based study.

The Clemson University electron beam ion trap (CUEBIT) laboratory was utilized …

The Search For Heavily Obscured Active Galactic Nuclei In The Local Universe, Ross Silver

All Dissertations

Active galactic nuclei (AGN) are supermassive black holes (SMBHs) in the center of galaxies that accrete surrounding gas and emit across the entire electromagnetic spectrum. They are the most energetic persistent emitters in the Universe, capable of outshining their host galaxies despite their emission originating from a region smaller than our Solar System. AGN were some of the first sources discovered that helped teach us that there were galaxies outside of our own, and they proved the existence of black holes. Moreover, AGN can give us valuable insights into other branches of astrophysics. For example, they can be used to …

Machine Learning-Based Data And Model Driven Bayesian Uncertanity Quantification Of Inverse Problems For Suspended Non-Structural System, Zhiyuan Qin

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Inverse problems involve extracting the internal structure of a physical system from noisy measurement data. In many fields, the Bayesian inference is used to address the ill-conditioned nature of the inverse problem by incorporating prior information through an initial distribution. In the nonparametric Bayesian framework, surrogate models such as Gaussian Processes or Deep Neural Networks are used as flexible and effective probabilistic modeling tools to overcome the high-dimensional curse and reduce computational costs. In practical systems and computer models, uncertainties can be addressed through parameter calibration, sensitivity analysis, and uncertainty quantification, leading to improved reliability and robustness of decision and …

Studies Of The Ionosphere-Thermosphere Responses To Multi-Scale Energy Deposition Processes, Haonan Wu

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The Ionosphere-Thermosphere (I-T) system is greatly affected by the magnetospheric energy deposition from above and subjected to forcing from the lower atmosphere simultaneously. A central problem in studying the coupled I-T system is to analyze the multi-scale processes naturally embedded in both ways. Magnetospheric energy input such as auroral precipitation and electric field demonstrates multi-scale structures during magnetic storms, resulting in multi-scale I-T responses when deposited into the I-T system. To better quantify the multi-scale aurora and electric field, we developed a new data assimilation model based on a multi-resolution Gaussian process model to synthesize empirical models and observational data …

Apparatus And Instrumentation Design For Investigation Of Surface Impact Effects On Superconductivity, Austin Back

All Theses

The effects of ion irradiation on the physical properties of materials make EBITs an invaluable tool for many scientific and engineering fields. Many experiments rely on the use of these lab setups to test for device reliability, explore surface physics phenomena, and replicate the environment for many physical systems that are not readily accessible. We seek to extend the capabilities of these experiments using the CUEBIT and a new sample holder installed in section 3.

This thesis begins by presenting an overview of the CUEBIT and the basic operations of the equipment. This is followed by a brief explanation of …

The Characterization Of Atmospheric Turbulence And Its Effect On Laser Beam Propagation, Michael Cox

All Theses

Having a controlled environment to measure atmospheric turbulence is essential to understanding its effects on different laser beam characteristics. The Clemson Variable Turbulence Generator (VTG) has the capability to propagate a laser beam up to 100 m and be able to dial many turbulence settings up to a heat flux of 357 W/m². A high-speed camera, power detector, and high-resolution temperature probes characterize the VTG with theoretical turbulence spectrums. The exponent associated with the Rayleigh-Bénard (RB) temperature structure constant equation is studied. Two different laser beam profiles are used throughout this work: Gaussian and Asymmetric Perfect Vortex (APV). …

Oam-Based Wavelets In A High Speed Optical Probing System For Measuring The Angular Decomposition Of The Environment, Justin Free

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This thesis presents the theoretical development of orbital angular momentum (OAM) based wavelets for the analysis of localized OAM information in space. An optical probing system for generating and detecting these wavelets is demonstrated; individual wavelets can scan the environment in 10µs or less. The probing system was applied to a three-dimensional atmospheric turbulence distribution to obtain a continuous wavelet transform of the angular information of the turbulent propagation path about a fixed radius. An entire continuous wavelet transform was measured in 3.8ms; the measurements are much faster than the turbulence and give insight into the short time scale of …

Electrical And Optical Characterization Of Two-Dimensional Semiconductors Using Ultrafast Spectroscopy, Pan Adhikari

All Dissertations

The emergence of two-dimensional (2D) layered materials provides unprecedented opportunities for studying excitonic physics due to the strong Coulomb interaction between the electron-hole pair. Because of the reduced dimensionality and weak dielectric screening, the exciton is stable at room temperature, unlike bulk semiconductors. The evolution from low to high carrier density for optical gain in 2D semiconductors involves insulating exciton gas, exciton condensation, co-existence of various excitonic complexes, electron-hole plasmas (EHPs), or electron-hole liquids (EHLs), leading to the Mott transition. Strong interaction among the excitons, such as exciton-exciton annihilation (EEA), serves as a hot-carrier generation. A bound exciton dissociates into …

Revealing The Role Of Electrostatics In Molecular Recognition, Ion Binding And Ph-Dependent Phenomena, Mihiri Hewa Bosthanthirige

All Dissertations

In this dissertation, we study the role of electrostatics in molecular recognition, ion binding and pH-dependent phenomena. In this work that includes three different research projects, the Poisson-Boltzmann (PB) model is used to describe the biological system and Delphi (which is a popular tool for solving the PB equation (PBE)) to study the electrostatics of biomolecular systems.

Chapter two aims to investigate the role of electrostatic forces in molecular recognition. We calculated electrostatic forces between binding partners separated at various distances. To accomplish this goal, we developed a method to find an appropriate direction to move one chain of protein …

Controlled Manipulation Of Droplets On Fibers: Fundamentals And Printing Applications, Yueming Sun

All Dissertations

In this dissertation, the drop interactions with a single fiber is discussed under an application angle for the development on new Drop-on-Demand (DOD) printhead using a fiber-in-a-tube platform[1] to print highly viscous materials[2]. To control the drop formation and manipulation on fiber, one needs to know how the fiber wetting properties and the fiber diameter influence drop formation. And then, one needs to know the effects of fiber movement in the device on drop formation. These two questions constitute the main theme of this dissertation.

Before this study, it was accepted that the liquids could not form axisymmetric droplets if …

Subwavelength Engineering Of Silicon Photonic Waveguides, Farhan Bin Tarik

All Dissertations

The dissertation demonstrates subwavelength engineering of silicon photonic waveguides in the form of two different structures or avenues: (i) a novel ultra-low mode area v-groove waveguide to enhance light-matter interaction; and (ii) a nanoscale sidewall crystalline grating performed as physical unclonable function to achieve hardware and information security. With the advancement of modern technology and modern supply chain throughout the globe, silicon photonics is set to lead the global semiconductor foundries, thanks to its abundance in nature and a mature and well-established industry. Since, the silicon waveguide is the heart of silicon photonics, it can be considered as the core …

In Situ Study Of Ultrafast Carrier Transport Dynamics In Perovskite Thin-Films, Kanishka Kobbekaduwa

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Perovskites are a novel class of materials that have piqued the interest of researchers in photovoltaics, photodetectors, and optoelectronics. In this study, we measure and elucidate in situ ultrafast carrier dynamics in both organic and inorganic, lead, and non-lead-based halide perovskite thin films using ultrafast photocurrent spectroscopy (UPCS) with a sub-25 ps time resolution. The UPCS technique enables us to define carrier transport dynamics in spatial, temporal, and energy landscapes via measurements at different electric fields, laser intensities, and temperatures. Here we explore and analyze solution-processed bulk MAPbI₃ and nanocrystalline CsPbI₃-based devices and novel non-lead double-layered perovskite …

Quantum-Mechanical Evaluation Of Defects In Uranium-Bearing Materials, Megan Hoover

All Dissertations

Quantum-mechanical calculations using density functional theory with the generalized gradient approximation were employed to investigate the effects dopants have on the uranium dioxide (UO₂) structure. Uraninite is a common U⁴⁺ mineral in the Earth's crust and an important material used to produce energy and medical isotopes. Though the incorporation mechanism remains unclear, divalent cations are known to incorporate into the uranium dioxide system. Three charge-balancing mechanisms were evaluated to achieve a net neutral system, including the substitution of (1) a divalent cation for a tetravalent uranium atom and oxygen atom; (2) two divalent cations for a tetravalent …

Developing A Software Defined Radio Based Faraday Receiver, Alvaro J. Guerra

All Theses

The ionosphere can be approximated as a magnetized plasma. This results in wave- particle interactions driving a large quantity of ionospheric phenomena. To understand these phenomena, it is important to quantify and measure certain key plasma parameters. One such parameter is electron density. The Faraday Experiment was developed for the purpose of measuring electron density in the D-region of the ionosphere. This experiment was made popular by Martin Friedrich in the 1970s and is currently one of the only ways to provide high resolution measurements of electron density in the D-region without actively disturbing the surrounding plasma. This thesis aims …

Porous Silicon Photonics For Label-Free Interferometric Biosensing And Flat Optics, Tahmid Hassan Talukdar

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This dissertation uses porous silicon as a material platform to explore novel optical effects in three domains: (i) It studies dispersion engineering in integrated waveguides to achieve high performance group index sensing. With proper design parameters, the sensor waveguides can theoretically achieve 6 times larger group index shift compared to the actual bulk effective refractive index shift. We demonstrate the guided mode confinement factor to be a key parameter in design and implementation of these waveguides. (ii) It explores multicolor laser illumination to experimentally demonstrate perceptually enhanced colorimetric sensing, overcoming the limitations faced by many contemporary colorimetric sensors. Our technique …

Optimization Of Modular, Long-Range, Ultra-Fast Optical Tweezers With Fluorescence Capabilities For Single-Molecule And Single-Cell Based Biophysical Measurements, Subash C. Godar

All Dissertations

An Optical tweezer is a tightly focused laser beam that applies and senses precise and localized optical force to a dielectric microsphere and offers a unique and effective tool for manipulating the single cell or cell components, including nucleotides and dynein motor proteins. Here, I used highly stabilized optomechanical components and ultra-sensitive detection modules to significantly improve the measurement capabilities over a wide range of temporal and spatial scales. I combined the optical tweezer-based force spectroscopy technique with fluorescence microscopy to develop an integrated high-resolution force-fluorescence system capable of measuring displacements at sub-nanometer, forces at sub-piconewton over a temporal range …