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Full-Text Articles in Physical Sciences and Mathematics

Toward Non-Invasive Measurement Of Atmospheric Temperature Using Vibro-Rotational Raman Spectra Of Diatomic Gases, Tyler Capek, Jacek Borysow, Claudio Mazzoleni, Massimo Moraldi Dec 2020

Toward Non-Invasive Measurement Of Atmospheric Temperature Using Vibro-Rotational Raman Spectra Of Diatomic Gases, Tyler Capek, Jacek Borysow, Claudio Mazzoleni, Massimo Moraldi

Michigan Tech Publications

We demonstrate precise determination of atmospheric temperature using vibro-rotational Raman (VRR) spectra of molecular nitrogen and oxygen in the range of 292–293 K. We used a continuous wave fiber laser operating at 10 W near 532 nm as an excitation source in conjunction with a multi-pass cell. First, we show that the approximation that nitrogen and oxygen molecules behave like rigid rotors leads to erroneous derivations of temperature values from VRR spectra. Then, we account for molecular non-rigidity and compare four different methods for the determination of air temperature. Each method requires no temperature calibration. The first method involves fitting …


Processing And Characterization Of Spin-Coated As2s3 Films For Direct Laser Writing, Mia Truman May 2020

Processing And Characterization Of Spin-Coated As2s3 Films For Direct Laser Writing, Mia Truman

Physics and Astronomy Presentations

Diffraction gratings, waveguides, and resonators are components of photonic devices that can be fabricated using chalcogenide glasses. These chalcogenide components can be made through a process of direct laser writing and etching to reveal targeted structures on the surface of the films. Thermal deposition in combination with targeted laser irradiation has been used on As2S3 films with excellent results, but spin-coating as a method of deposition has been less explored. Spin-Coating is a relatively inexpensive procedure where a bulk glass is dissolved into a solution using amines and “spun” onto a substrate. This is a low-cost alternative …


Can Ethanol Affect The Cell Structure - A Dynamic Molecular And Raman Spectroscopy Study, Luis Felipe Carvalho, Laurita Dos Santos, Kate O'Callaghan, Franck Bonnier, Steven Flint, Fiona Lyng, Hugh Byrne Feb 2020

Can Ethanol Affect The Cell Structure - A Dynamic Molecular And Raman Spectroscopy Study, Luis Felipe Carvalho, Laurita Dos Santos, Kate O'Callaghan, Franck Bonnier, Steven Flint, Fiona Lyng, Hugh Byrne

Articles

The role that tobacco consumption plays in the etiology of oral cancer carcinogenesis, and of alcohol consumption acting as a co-factor, have been well established. However, in recent years, the contribution of alcohol consumption alone to oral cancer has been proposed. In fact, a high percentage of patients who develop oral cancer have both habits (tobacco and alcohol consumption), and other small patient groups only consume alcohol or do not have any other identifiable bad habits. In the present study, we demonstrate for the first time, using a combination of dynamic molecular modelling and Raman spectroscopy, that ethanol has a …


Quantitative Analysis Of Human Blood Serum Using Vibrational Spectroscopy., Hugh Byrne, Franck Bonnier, Jennifer Mcintyre, Drishya Rajan Parachalil Jan 2020

Quantitative Analysis Of Human Blood Serum Using Vibrational Spectroscopy., Hugh Byrne, Franck Bonnier, Jennifer Mcintyre, Drishya Rajan Parachalil

Articles

Analysis of bodily fluids using vibrational spectroscopy has attracted increasing attention in recent years. In particular, infrared spectroscopic screening of blood products, particularly blood serum, for disease diagnostics has been advanced considerably, attracting commercial interests. However, analyses requiring quantification of endogenous constituents or exogenous agents in blood are less well advanced. Recent advances towards this end are reviewed, focussing on infrared and Raman spectroscopic analyses of human blood serum. The importance of spectroscopic analysis in the native aqueous environment is highlighted, and the relative merits of infrared absorption versus Raman spectroscopy are considered, in this context. It is argued that …