Open Access. Powered by Scholars. Published by Universities.®

Physical Sciences and Mathematics Commons

Open Access. Powered by Scholars. Published by Universities.®

Physical Chemistry

Journal

2022

Electrolysis

Articles 1 - 2 of 2

Full-Text Articles in Physical Sciences and Mathematics

Study On Electrochemical Conversion Of Ammonium Sulfate To Ammonium Persulfate In Acetylpyrazine Wastewater, Yi-Jie Wang, Dong-Fang Niu, Xin-Sheng Zhang Apr 2022

Study On Electrochemical Conversion Of Ammonium Sulfate To Ammonium Persulfate In Acetylpyrazine Wastewater, Yi-Jie Wang, Dong-Fang Niu, Xin-Sheng Zhang

Journal of Electrochemistry

Acetylpyrazine is an important spice and also plays important roles in biology, medicine and other fields. However, the wastewater containing ammonium persulfate, ferric ion (Fe3+), pyrazine, and a large amount of ammonium sulfate was produced during the production of acetylpyrazine. In this study, ammonium sulfate in acetylpyrazine wastewater was electrolytically converted into ammonium persulfate for economic benefits. Using platinum as an anode and graphite as a cathode, the influence factors of the electrolysis process (including the composition of the anolyte, the current density, the temperature, etc.) were firstly investigated without interference from other compositions. Under the optimal condition, namely, the …


Oxidative Efficiency Of Ozonation Coupled With Electrolysis For Treatment Of Acid Wastewater, Ze-You Hu, Feng-Yun Xiang, Ji-Qiang Mao, Ya-Lei Ding, Shao-Ping Tong Jan 2022

Oxidative Efficiency Of Ozonation Coupled With Electrolysis For Treatment Of Acid Wastewater, Ze-You Hu, Feng-Yun Xiang, Ji-Qiang Mao, Ya-Lei Ding, Shao-Ping Tong

Journal of Electrochemistry

Establishment of an ozone-based advanced oxidation process (AOPs-O3) for effective treatment of acid wastewater is an important and difficult task. The process of ozonation coupled with electrolysis (electrolysis-ozonation, E-O3) has been reported to effectively degrade pollutants in neutral solution. We studied the efficiency of E-O3 for degradation of acetic acid (HAc, an ozone inert chemical) in acid solution and found that E-O3 had high oxidative efficiency at pH less than 3. For example, 52.2% of 100 mg·L-1 HAc could be removed by E-O3 in 120 min at pH 1.0, but only 2.2% and …