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Full-Text Articles in Physical Sciences and Mathematics
Nanostructured Cerium Oxide Based Catalysts: Synthesis, Physical Properties, And Catalytic Performance, Yunyun Zhou
Nanostructured Cerium Oxide Based Catalysts: Synthesis, Physical Properties, And Catalytic Performance, Yunyun Zhou
Department of Chemistry: Dissertations, Theses, and Student Research
Cerium oxide is an extensively used industrial catalyst with applications as diverse as catalysts for automobile exhaust, petroleum cracking and organic chemicals synthesis. The catalytic activity of cerium oxide is dependent upon its structural properties, especially the oxygen vacancy defects. While recent advances in characterization techniques have dramatically improved our understanding of cerium oxide functionality, many atomic features in cerium oxide contributing to the overall catalytic reactivity are not yet well-understood. This dissertation focuses on the structural studies of catalytically active cerium oxides with different compositions, phases and morphologies, and their utilizations to establish fundamental understandings of cerium oxide based …
Analysis And Comparison Of The Photodecomposition Reaction Of Methanol On Ceo2 Impregnated Tio2 Surfaces Versus Bare Tio2 Surfaces, Christopher A. Estes
Analysis And Comparison Of The Photodecomposition Reaction Of Methanol On Ceo2 Impregnated Tio2 Surfaces Versus Bare Tio2 Surfaces, Christopher A. Estes
Master of Science in Chemical Sciences Theses
Titanium dioxide (TiO2) has been well-studied primarily due to its unique photocatalytic activity. Different preparation techniques have been developed to increase its photocatalytic activity by various means, including simply increasing the surface area, changing the makeup of the framework, and modifying the surface with a dopant. This study focuses on the effect cerium oxide (CeO2) has on the photocatalytic activity of TiO2 by depositing CeO2 on the TiO2 surface. Methanol is used as a probe reactant for these experiments due to its wide use in heterogeneous catalysis research and the limited products that …