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Physical Chemistry

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Electronic Thesis and Dissertation Repository

2013

Carbon steel

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A Study Of Gamma Radiation Induced Carbon Steel Corrosion, Kevin Daub Jan 2013

A Study Of Gamma Radiation Induced Carbon Steel Corrosion, Kevin Daub

Electronic Thesis and Dissertation Repository

This thesis presents work on the development of a mechanistic understanding of the effect of ionizing radiation on the aqueous corrosion kinetics of carbon steel. Exposed to ionizing radiation, water decomposes into a range of oxidizing (O2, •OH, HO2•, H2O2) to reducing (•eaq, •O2, •H) species. The production of the redox active species by radiolysis can have a significant effect on the corrosion behaviour of a metal. Of particular interest is the effect of radiolysis on corrosion when the solution environment, such as temperature, pH, and …