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Physical Sciences and Mathematics Commons

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Physical Chemistry

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Purdue University

2014

Mass independent fractionation

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Investigation Of Isotope Effects Of Ozone As A Function Of Temperature, Daniel J. Mcmahon Apr 2014

Investigation Of Isotope Effects Of Ozone As A Function Of Temperature, Daniel J. Mcmahon

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Ozone is an important oxidizer in the atmosphere and plays a crucial role as a cleanser, removing various compounds such NOx and SOx. It also is intriguing to those that study stable isotopes as it has a unique signature found in no other oxygen containing molecule. Ozone is observed to fractionate mass independently, which means it does not follow the typical δ 17 O /δ18 O = 0.52 ratio expected for molecules enriched with 17 O and 18 O. The magnitude of ozone's mass independent enrichment has been studied in laboratory experiments and atmospheric observations but its explanation is still …