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Full-Text Articles in Physical Sciences and Mathematics
Calculating Elastic Properties Of Confined Simple Fluids, Christopher D. Dobrzanski
Calculating Elastic Properties Of Confined Simple Fluids, Christopher D. Dobrzanski
Dissertations
Confinement in nanoporous materials is known to affect many properties of the fluids confined within their pores. The elastic properties are no exception. This dissertation begins with an overview of the relevant literature on ways of obtaining elastic properties of confined fluids. It outlines some fundamental gaps in our understanding. The chapters following address some of these gaps in understanding elastic properties of the confined fluid, in particular, how the shape of the confining pore matters, how supercriticality effects the properties, how an equation of state designed for confined fluids can be used to calculate elastic properties, and if an …
Gas Adsorption In Carbon Nanohorns: Equilibrium And Kinetics, Justin Matthew Petucci
Gas Adsorption In Carbon Nanohorns: Equilibrium And Kinetics, Justin Matthew Petucci
Electronic Theses and Dissertations
A study of gas adsorption has been carried out with the focus of better understanding the relationships between the individual properties of the adsorbent/adsorbate (e.g. material structure, interactions, gas size and shape, etc.) and the overall adsorptive properties of the combined system (e.g. capacity, binding strength, equilibration time, etc.) as a function of thermodynamical variables. This is useful from the perspective of a comprehensive and fundamental understanding as well as for practical applications. The equilibrium regime of adsorption on carbon nanostructure materials (nanohorns, nanotubes, and graphite) is investigated using molecular statics (MS) and grand canonical monte carlo (GCMC) methods for …