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Organic Chemistry

Fluorine compounds

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Preparation, Chemistry, And Characterization Of Hypervalent Organosulfur Fluorides, Paul R. Savoie Jan 2015

Preparation, Chemistry, And Characterization Of Hypervalent Organosulfur Fluorides, Paul R. Savoie

Legacy Theses & Dissertations (2009 - 2024)

Since the discovery of the pentafluorosulfanyl (SF5) group around the 1960s, progress in exploring the chemistry of aliphatic SF5-containing compounds stagnated because of a lack of efficient synthetic methods. More recent developments in the preparations of SF5-containing compounds afforded easier access to these compounds, and sparked great interest in exploring their chemistry. Chapter 1 discusses the development of efficient methods used to prepare SF5-containing aliphatic compounds.