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Articles 1 - 9 of 9
Full-Text Articles in Physical Sciences and Mathematics
Antimicrobial Nanoparticles: A Green And Novel Approach For Enhancing Bactericidal Efficacy Of Commercial Antibiotics, Monic Shah
Masters Theses & Specialist Projects
On the verge of entering the post-antibiotic era, numerous efforts are in place to regain the waning charm of antibiotics which are proving ineffective against most “Superbugs”. Engineered nanomaterials, especially gold nanoparticles (GNPs) capped with antibacterial agents, are proving to be an effective and novel strategy against multidrug resistant (MDR) bacteria. In this study, we report a one-step synthesis of antibioticcapped GNPs (25 ± 5 nm) utilizing the combined reducing and capping ability of a cephalosporin antibiotic, ceftazidime. No signs of aggregation or leaching of ceftazidime from GNP surface was observed upon its storage. Antibacterial testing showed dosedependent broad spectrum …
Green Synthesis And Evaluation Of Catalytic Activity Of Sugar Capped Gold Nanoparticles, Yogesh A. Kherde
Green Synthesis And Evaluation Of Catalytic Activity Of Sugar Capped Gold Nanoparticles, Yogesh A. Kherde
Masters Theses & Specialist Projects
Owing to the importance of gold nanoparticles in catalysis, designing of them has become a major focus of the researchers. Most of the current methods available for the synthesis of gold nanoaprticles (GNPs) suffer from the challenges of polydispersity, stability and use of toxic and harmful chemicals. To overcome these limitations of conventional methods, in our present study, we made an attempt to design a method for the green synthesis of monodispersed and stable gold nanoparticles by sugars which act as reducing and stabilizing agent. Characterization of synthesized nanoparticles was done by using various analytical techniques such as transmission electron …
Selective Oxidations By Iron(Iii) Porphyrins And Iron(Iii) Corroles, Aaron Dalnamath Carver
Selective Oxidations By Iron(Iii) Porphyrins And Iron(Iii) Corroles, Aaron Dalnamath Carver
Masters Theses & Specialist Projects
The selective oxidation of organic compounds represents a leading technology for chemical industries. They are used in chemical synthesis in the pharmaceutical and petrochemicals industries, and possible the decontamination of harmful substances. However, oxidations reaction are among the most challenging processes to control. Many stoichiometric oxidants with heavy metals are expensive, or toxic maybe both, and therefore unfeasible to be utilized. The ideal processes for catalytic oxidation would use molecular oxygen or hydrogen peroxide as the primary oxygen source, with transition metal catalysts to mimic the predominant oxidation catalysts in Nature, the cytochrome P450 enzymes. This study focuses on the …
Selective Oxidations By Metalloporphyrins And Metallocorroles, Tse-Hong Chen
Selective Oxidations By Metalloporphyrins And Metallocorroles, Tse-Hong Chen
Masters Theses & Specialist Projects
Highly reactive transition metal-oxo intermediates are important active oxidant involved in numerous enzymes such as cytochrome P450 monooxygenases as well as in many useful metal-catalyzed oxidations. Many transition metal catalysts are designed for biomimetic studies of the predominant oxidation catalysts in Nature, the cytochrome P450 enzymes. In this work, a series of metalloporphyrin and metallocorrole complexes have been successfully synthesized and spectroscopically characterized by UV-vis, GCMS and 1H-NMR. The utilization of these complexes as catalysts for selective oxidation of sulfides and photocatalytic aerobic oxidations of activated hydrocarbons were investigated. Ruthenium(II) porphyrin complexes (2) and iron(III) corrole complexes (4) with …
Functionalization And Modification Of Naphthaquinone Analogs As Her2 Kinase Inhibitors, Divya Jyothi Lella
Functionalization And Modification Of Naphthaquinone Analogs As Her2 Kinase Inhibitors, Divya Jyothi Lella
Masters Theses & Specialist Projects
HER2 overexpression in breast cancer tumors predicts lower overall survival. Because of the aggressive nature of HER2 tumors and the association with metastatic disease, the HER2 receptor holds great promise as a therapeutic target in metastatic breast cancer. We are developing small molecule inhibitors that bind to the ATP binding site of the tyrosine kinase domain in order to inhibit tyrosine auto-phosphorylation. This process controls biological pathways that mediate the cell growth. In normal cells this process is highly controlled. We are targeting the modification of the side chain of the hydroxy methyl group of 2-Hydroxy methyl-5,8-dimethoxy-1,4-naphthaquinone. These compounds should …
Electrically Controlled Formation And Release Of Admicelles For Solid Phase Extraction, Sukyeon Lee
Electrically Controlled Formation And Release Of Admicelles For Solid Phase Extraction, Sukyeon Lee
Masters Theses & Specialist Projects
Solid phase extraction is one of the most widely used methods to concentrate diluted compounds in a solution. Substances can be extracted into admicelles and hemimicelles, which are surface adsorbed micelles and surfactant monolayers, respectively. Investigations of the electrical control of surfactants on surfaces for the purpose of analyte preconcentration prior to chromatographic analysis are presented. The surfactant layer serves as the “stationary phase” in a solid phase extraction sorbent scenario. Analytes are adsorbed on this layer, and then released from the solid phase via surfactant removal. The attachment and removal of the surfactant are controlled by means of an …
Enhancing The Photovoltaic Performance Of P3ht/Pdib Silsesquioxane Donor-Acceptor System Using Spray Deposition Fabrication Technique, Venkata Ramana Manda
Enhancing The Photovoltaic Performance Of P3ht/Pdib Silsesquioxane Donor-Acceptor System Using Spray Deposition Fabrication Technique, Venkata Ramana Manda
Masters Theses & Specialist Projects
In the past few years, the solution-processed organic based solar cells gained more importance by meeting the demands for cost effective photovoltaic devices. To date, the focus of the organic photovoltaic devices has been on the optimization of the processing the materials to improve photo conversion efficiency and also by modifying the active components of the organic materials. Recently, it has been recognized that the deposition techniques also plays a major role in enhancing the power conversion efficiencies. Currently, though the most common deposition technique for organic solar cells is spin coating, which does not allow scaling up of the …
Thermal Analysis Of Binding Of Organic Pollutants To Titanium Dioxide, Shashidhar Annarapu
Thermal Analysis Of Binding Of Organic Pollutants To Titanium Dioxide, Shashidhar Annarapu
Masters Theses & Specialist Projects
Conventional waste water treatment processes are not completely effective in removing highly stable organic compounds. Photocatalytic degradation on titanium dioxide is a possible alternative technique for many classes of these compounds. Several studies have been done by other researchers to study mechanisms of photocatalytic degradation, which occurs either through direct oxidation by holes or via indirect oxidation by radical messengers. Titanium dioxide can oxidize substrates directly through hole oxidation mechanisms or indirectly through free radical mechanisms. Substrates must bind onto the catalyst surface to undergo direct oxidation by holes. Thermogravimetric analysis (TGA) was performed on four different classes of compounds; …
Synthesis Of Perylenediimide-Functionalized Silsesquioxane Nanostructures, Lan Xu
Synthesis Of Perylenediimide-Functionalized Silsesquioxane Nanostructures, Lan Xu
Masters Theses & Specialist Projects
Organic semiconductors functionalized nanostructures are becoming as promising materials for electronic device applications including organic photovoltaics (OPVs). Perylenediimide (PDI) derivatives have also been known as one of the best n-type organic semiconductors. PDI derivatives can form bulk materials, which are both photochemically and thermally stable and have been widely used in various optoelectronic devices. Due to the formation of high electron mobility of crystalline domains, they prefer to incorporate into a silsesquioxane network. Here, we describe the potential applicability of perylenediimide functionalized silsesquioxane nanoribbons (PDI-dimethyl nanoribbons) as an acceptor for optoelectronic devices. We have developed synthetic procedures to make the …