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Preparation Of Perylene Bisimide Acceptors With Ethylcarboxyl And Pyrenylcyclohexyl Imide Groups, Michael Cashen Stark
Preparation Of Perylene Bisimide Acceptors With Ethylcarboxyl And Pyrenylcyclohexyl Imide Groups, Michael Cashen Stark
Honors Theses
Multiple attempts were made to deprotect TBDMS-protected (tert-butyldimethylsilyl protected) serinol and swallowtailed PBI (Compound 2), synthesized by past researcher Tarrah Frederick, to generate Compound 1. The theoretical Compound 1 product is intended for use in molecular rectification of electricity because the perylene core acts as a good acceptor with high electron affinity, and it does not require an electron donor group. Many rectification molecules are amphiphilic Donor-σ-Acceptor compounds, which allow for electron transfer through localized molecular orbitals when placed between electrodes (Langmuir-Blodgett Method). However, PBIs can transfer electrons from one electrode, through the LUMO of perylene, and to the other …