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Full-Text Articles in Physical Sciences and Mathematics

The Use Of Sodium Persulfate In Hydraulic Fracturing Fluids: A Degradation Study Based On Furfural, Katherine Elizabeth Manz Aug 2016

The Use Of Sodium Persulfate In Hydraulic Fracturing Fluids: A Degradation Study Based On Furfural, Katherine Elizabeth Manz

Masters Theses

Hydraulic fracturing has allowed natural gas to become a viable energy source via extraction of unconventional shale reserves, but this process requires an enormous amount of water. To ensure a productive fracture, a proprietary blend of chemical additives is added to the water. In this research, a hydraulic fracturing chemical additive – an enzyme breaking agent – is analyzed for organic components using gas chromatography mass spectrometry. The chemical changes that occur over the course of a fracture are also investigated using one model chemical found in the additive, furfural, in order to help assess the environmental risk that hydraulic …


Oxidative Dehydrogenation Of Light Alkanes With Carbon Dioxide, Marktus A. Atanga Jan 2016

Oxidative Dehydrogenation Of Light Alkanes With Carbon Dioxide, Marktus A. Atanga

Masters Theses

”Most experts studying the global ecosystem and climate suggest that rising anthropogenic CO2 emissions have contributed to significant global climate change in the last half-century. The development of effective strategies that convert CO2 into energy, fuels, and chemicals are greatly preferable to oceanic or geologic sequestration options because they offer the potential to create new commercially-viable products from renewable carbon feedstock. On the other hand, the selective oxidative dehydrogenation of light alkanes (C2-C4) to corresponding olefins, methane reforming, and methane coupling are the major challenges for producing valuable and versatile feedstocks. The oxidative dehydrogenation …


White-Rot Fungi As Pretreatment Agents For Wood Destined For Biofuel Applications, Ryan M. Kalinoski Jan 2016

White-Rot Fungi As Pretreatment Agents For Wood Destined For Biofuel Applications, Ryan M. Kalinoski

Masters Theses

Efficient and economical conversion of lignocellulosic biomass to biofuels is often hampered by the chemical recalcitrance of the material. Inexpensive and environmentally-friendly pretreatment processes are therefore desirable in order to lower the cost of biofuel production and minimize negative environmental impacts. To that end, we have explored the use of a naturally occurring white-rot fungus, Trametes versicolor, as a direct pretreatment agent for hardwood destined for biofuel applications. Specifically, we examined the pretreatment effects on the hardwood mixture after treatment with the wild-type strain of T. versicolor (52J) compared with those from a cellobiose dehydrogenase (CDH)-deficient strain (m4D) , …