Physical Sciences and Mathematics Commons^™

Enabling A Sustainable Economy Through Energy Systems Modeling: Solar-Centric, Efficient, Integrated And Continuous Process Synthesis And Optimization, Emre Gencer

Open Access Dissertations

The expected increase in food, energy and water demand due to increase in population and change in consumption habits in conjunction with diminishing fossil fuel reserves and increasing greenhouse gas emissions urge the development and implementation of alternative energy conversion techniques using renewable energy for a sustainable economy. Among renewable energy sources, solar energy is prominent due to its abundance. A sustainable economy can be created by producing building blocks foundational to meeting all basic human needs of daily existence. However, intermittencies and limitations on land area dedicated to harness solar energy are the major obstacles on widespread implementation of …

Electricity Generation, Electricity Consumption, And Energy Efficiency In The United States: A Dual Climatic-Behavioral Approach, Christopher A. Craig

Graduate Theses and Dissertations

Much of the United States (US) has seen an increase in warm days, decrease in cool days, and increase in extreme weather events. These trends are projected to continue across much of the US and in turn increase the demand for electricity and subsequent greenhouse gas emissions. Ambitious energy efficiency (EE) programs are used across the US by energy utility organizations to reduce electricity demand and emissions. This study examined the impact of climatic variability on electricity consumption, as well as how pro-conservation interventions such as EE programs and experiential learning can be utilized to mitigate residential electricity consumption and …

Design Of A Nutrient Reclamation System For The Cultivation Of Microalgae For Biofuel Production And Other Industrial Applications, Heather Sandefur

Graduate Theses and Dissertations

Microalgal biomass has been identified as a promising feedstock for a number of industrial applications, including the synthesis of new pharmaceutical and biofuel products. However, there are several economic limitations associated with the scale up of existing algal production processes. Critical economic studies of algae-based industrial processes highlight the high cost of supplying essential nutrients to microalgae cultures. With microalgae cells having relatively high nitrogen contents (4 to 8%), the N fertilizer cost in industrial-scale production is significant. In addition, the disposal of the large volumes of cell residuals that are generated during product extraction stages can pose other economic …

Algal Wastewater Treatment And Biofuel Production: An Assessment Of Measurement Methods, And Impact Of Nutrient Availability And Species Composition, John F. Chamberlin

Graduate Theses and Dissertations

In order to move towards a more sustainable future, human civilization will need to decrease its impacts on air and water quality and minimize consumption of fossil fuels. Using algae for wastewater treatment and biofuel production offers one approach to progress towards these goals simultaneously. Algae are capable of removing nutrients from wastewater and carbon dioxide from the air, and the biomass formed in that process can be used to generate a wide-range of products including fertilizer or fuels that could power combustion engines, power plants, or zero-emission fuel cell vehicles. Using wastewater for biofuel production has the potential to …

The Mass Flux Of Non-Renewable Energy For Humanity, Edwin Dale Solomon

Graduate Theses and Dissertations

The global energy supply relies on non-renewable energy sources, coal, crude oil, and natural gas, along with nuclear power from uranium and these finite resources are located within the upper few kilometers of the Earth’s crust. The total quantity of non-renewable energy resources consumed relative to the total quantity available is an essential question facing humanity. Analyses of energy consumption was conducted for the period 1800 – 2014 using data from the U. S. Energy Information Administration (EIA) and World Energy Production, 1800-1985 to determine the balance between non-renewable energy resources consumed and ultimately recoverable reserves. Annual energy consumption was …

Electric Power And The Global Economy: Advances In Database Construction And Sector Representation, Jeffrey C. Peters

Open Access Dissertations

The electricity sector plays a crucial role in the global economy. The sector is a major consumer of fossil fuel resources, producer of greenhouse gas emissions, and an important indicator and correlate of economic development. As such, the sector is a primary target for policy-makers seeking to address these issues. The sector is also experiencing rapid technological change in generation (e.g. renewables), primary inputs (e.g. horizontal drilling and hydraulic fracturing), and end-use efficiency. This dissertation seeks to further our understanding of the role of the electricity sector as part of the dynamic global energy-economy, which requires significant research advances in …

Modifying A Cow-Calf Biophysical Simulation Model For Analyses Of Alternative Enterprises, Jennifer L. Lutes

Graduate Theses and Dissertations

Cow-calf producers in the United States, tasked with providing beef calves for the beef industry, have had a multitude of difficulties to overcome in recent years. Producers in northwest Arkansas were negatively impacted by high hay prices coupled with low beef cattle market prices due to severe drought experienced in portions of 2010, 2011, and 2012. During this time they also faced high grain prices, due to a record low harvest, combined with portions of the corn harvest diverted from human and animal feed to ethanol production. Tight lending policies of this time, reminiscent of the housing market crash in …

Compounds Released From Biomass Deconstruction: Understanding Their Effect On Cellulose Enzyme Hydrolysis And Their Biological Activity, Angele Djioleu

Graduate Theses and Dissertations

The effect of compounds produced during biomass pretreatment on cellulolytic enzyme was investigated. Liquid prehydrolyzates were prepared by pretreating switchgrass using 24 combinations of temperature, time, and sulfuric acid concentration based on a full factorial design. Temperature was varied from 140°C to 180°C; time ranged from 10 to 40 min; and the sulfuric acid concentrations were 0.5% or 1% (v/v). Identified products in the prehydrolyzates included xylose, glucose, hydroxymethylfurfural (HMF), furfural, acetic acid, formic acid, and phenolic compounds at concentration ranging from 0 to 21.4 g/L. Pretreatment conditions significantly affected the concentrations of compounds detected in prehydrolyzates. When assayed in …

Synthesis Of Palladium And Palladium-Copper Nanostructures As Electrocatalysts, Haibin Wu

Graduate Theses and Dissertations

Pd and its alloys are alternatives of Pt as promising catalysts and electrocatalysts for many reactions. Size controlled synthesis of nanoparticles remains a major research subject, since smaller size particles show better catalytic performance. In this work, we developed a modified chemical wet method to prepare Pd and Pd-Cu nanostructures with uniform small size. Different sizes and shapes of Pd nanostructures were successfully synthesized by using the two reducing agents (i.e., L-ascorbyl-6-palmitate or phenylphosphinic acid). The reducing agents play a role to control the final morphologies and sizes of particles. The use of L-ascorbyl-6-palmitate favors to form irregular branch shapes …

Top-Down Aluminum Induced Crystallization For Photovoltaics, Seth Daniel Shumate

Graduate Theses and Dissertations

Passivating silicon solar cell surfaces is critical to fabricating very high efficiency and low cost photovoltaic devices. The sun-facing surface of the solar cell, known as the emitter, is particularly important when designing a solar cell. This work focused first on an alternative method of forming the emitter of silicon solar cells, and secondly on a method for improving the surface passivation of both these non-traditional and standard n-type solar cells.

Top-down aluminum induced crystallization (TAIC) was used for forming a polycrystalline silicon layer from amorphous silicon using aluminum to catalyze the crystallization at much lower temperatures than otherwise possible. …

Enhancement Of The Performance Of Gaas Based Solar Cells By Using Plasmonic, Anti-Reflection Coating And Hydrophobic Effects, Yahia Fayiz Makableh

Graduate Theses and Dissertations

Investigation of renewable energy resources is gaining huge momentum in recent years due to the limited fossil fuels, and their detriment impact on the environment. Solar energy is promising to meet the increased energy demand. In order to achieve this goal, solar energy has to be harvested efficiently at low cost. Therefore, higher efficiency solar cells are the primary focus of research worldwide. Photovoltaics based on InAs/GaAs intermediate band solar cells and their device performance enhancements are investigated in this dissertation. The device enhancement is carried out by surface modification methods. The dissertation work is inspired by the need of …

Transformation Of Swine Manure And Algal Consortia To Value-Added Products, Mahmoud A. Sharara

Graduate Theses and Dissertations

The swine production sector is projected to grow globally. In the past, this growth manifested itself in increased herd sizes and geographically concentrated production. Although economically sound, these trends had negative consequences on surrounding ecosystems. Over-application of manure resulted in water quality degradation, while long-term storage of manure slurries was found to promote release of potent GHG emissions. There is a need for innovative approaches for swine manure management that are compatible with current scales of production, and increasingly strict environmental regulations.

This study aims to investigate the potential for incorporating gasification as part of a novel swine manure management …

The Power Behind The Controversy: Understanding Local Policy Elites' Perceptions On The Benefits And Risks Associated With High Voltage Power Line Installation In The State Of Arkansas, Rachael Marie Moyer

Graduate Theses and Dissertations

Following a proposal for the installation of high voltage power lines in northwest Arkansas, a controversial policy debate emerged. Proponents of the transmission line argue that such an installation is inevitable and necessary to efficiently and reliably support the identified electric load in the region. Opponents claim that the lines will degrade the natural environment and hamper the tourism-based local economy in affected regions, notably in Ozark Mountain areas. This study seeks to understand how local policy elites perceive the benefits and risks associated with proposed transmission lines, which is a critical step in comprehending the formation and changes of …

Characterization Of Cellulase Enzyme Inhibitors Formed During The Chemical Pretreatments Of Rice Straw, Kalavathy Rajan

Graduate Theses and Dissertations

Production of fuels and chemicals from a renewable and inexpensive resource such as lignocellulosic biomass is a lucrative and sustainable option for the advanced biofuel and bio-based chemical platform. Agricultural residues constitute the bulk of potential feedstock available for cellulosic fuel production. On a global scale, rice straw is the largest source of agricultural residues and is therefore an ideal crop model for biomass deconstruction studies. Lignocellulosic biofuel production involves the processes of biomass conditioning, enzymatic saccharification, microbial fermentation and ethanol distillation, and one of the major factors affecting its techno-economic feasibility is the biomass recalcitrance to enzymatic saccharification. Preconditioning …

Experimental Verification And Integration Of A Next Generation Smart Power Management System, Tavis Clemmer

Graduate Theses and Dissertations

With the increase in energy demand by the residential community in this country and the diminishing fossil fuel resources being used for electric energy production there is a need for a system to efficiently manage power within a residence. The Smart Green Power Node (SGPN) is a next generation energy management system that automates on-site energy production, storage, consumption, and grid usage to yield the most savings for both the utility and the consumer. Such a system automatically manages on-site distributed generation sources such as a PhotoVoltaic (PV) input and battery storage to curtail grid energy usage when the price …

Incorporating Environmental And Social Factors Into Decision-Making Of An Oil And Gas Industry To Improve Sustainability, Gaurav Dabhadkar

Graduate Theses and Dissertations

The energy industry (including the oil and gas industry) is facing unparalleled scrutiny and demands from stakeholders including investors, regulators (industry and environmental), communities, and other stakeholders. Sustainable development is one of the major concerns of the oil and gas industry. Companies are seeking to increase sustainability of their operations by considering environmental and Social concerns in addition to economic concerns. Oil and gas companies need to take decisions at different stages of the product life cycle (e.g. planning, design, exploration, production, and clean-up) which have direct or indirect impact on the organization's objectives. Addressing economic, technical, Social, and environmental …

Waste Heat Recovery Options In A Large Gas-Turbine Combined Power Plant, Ularee Upathumchard

Open Access Theses

This study focuses on power plant heat loss and how to utilize the waste heat in energy recovery systems in order to increase the overall power plant efficiency. The case study of this research is a 700-MW natural gas combined cycle power plant, located in a suburban area of Thailand. An analysis of the heat loss of the combustion process, power generation process, lubrication system, and cooling system has been conducted to evaluate waste heat recovery options. The design of the waste heat recovery options depends to the amount of heat loss from each system and its temperature. Feasible waste …

High Voltage Rear Electric Drivetrain Design For A Parallelthrough-The-Road Plug-In Hybrid Electric Vehicle, Adam Garrett Fogarty

Open Access Theses

Purdue University was selected as one of 15 universities to participate in a three year Advanced Vehicle Technology Competition (AVTC) called EcoCar2: Plugging Into the Future. The vehicle built by the Purdue team was a Parallel-Through-The-Road Plug-in Hybrid Electric Vehicle (PTTR PHEV). The vehicle utilized a B20 diesel powertrain to power the front wheels, as well as a custom electric drivetrain to power the rear wheels. Using this vehicle during the final year of the competition, the team was successful in placing 4th overall as well as 2nd in the category of Well-To-Wheel (WTW) Greenhouse Gas Emissions. A stock 2013 …

Uncertainty, Irreversibility, And Investment In Secondgeneration Biofuels, Tanner Joseph Mccarty

Open Access Theses

The present study formalizes and quantifies the importance of uncertainty for investment in a corn-stover based cellulosic biofuel plant. Using a real options model we recover prices of gasoline that would trigger entry into the market and calculate the portion of that entry trigger price required to cover cost and the portion that corresponds to risk premium. We then discuss the effect of managerial flexibility on the entry risk premium and the prices of gasoline that would trigger mothballing, reactivation, and exit. Results show that the risk premium required by plants to enter the second-generation biofuel market is likely to …

Propogation Of Wind Turbine Noise Through Wakes And Turbulent Atmosphere, Yuan Peng

Open Access Theses

It is well known that the atmospheric inhomogeneities have great impact on sound propagation over long ranges. For the application of predicting wind turbine noise, either the flow wakes generated by rotating turbine blades or small-scale atmospheric turbulence can affect the propagation of sound over ground surfaces from individual turbines.

In this thesis, the effects of wake and atmospheric turbulence on the propagation of wind turbine noise are investigated. By introducing the Parabolic Equation (PE) method, the effects of atmospheric changes in sound speed can be incorporated at each marching step as the prediction of sound field advances in the …

Catalysts For Portable, Solid State Hydrogen Genration Systems, Jason Robert Gabl

Open Access Theses

Hydrogen and air powered proton exchange membrane fuel cells are a potential alternative to batteries. In portable power systems, the design requirements often focus on cost efficiency, energy density, storability, as well as safety. Ammonia borane (AB), a chemical hydride containing 19.6 wt. % hydrogen, has a high hydrogen capacity and is a stable and non-toxic candidate for storing hydrogen in portable systems.

Throughout this work, Department of Energy guidelines for low power portable hydrogen power systems were used as a baseline and comparison with commercially available systems. In order to make this comparison, the system parameters of a system …

Field To Flight: A Techno-Economic Analysis Of Stover To Aviation Biofuels Supply Chain, Amanda C. Bittner

Open Access Theses

Greenhouse gas emissions have been a growing concern. The transportation sector contributes to one-third of GHG emissions in the United States from fossil fuel burning. The Renewable Fuel Standard set a requirement for 16 billion gallons (ethanol equivalent) of cellulosic biofuels to be used in the market. Aviation biofuels can help to meet both of these problems as well as improve U.S. energy security.

Investment in the biofuel industry carries a lot of risk. The biofuel industry is run by the private sector, but can be incentivized by government. Cellulosic biofuels carry even more risk than first generation biofuels, because …

A Novel Microgrid Demand-Side Management System For Manufacturing Facilities, Terance Jerome Harper

Open Access Theses

Thirty-one percent of annual energy consumption in the United States occurs within the industrial sector, where manufacturing processes account for the largest amount of energy consumption and carbon emissions. For this reason, energy efficiency in manufacturing facilities is increasingly important for reducing operating costs and improving profits. Using microgrids to generate local sustainable power should reduce energy consumption from the main utility grid along with energy costs and carbon emissions. Also, microgrids have the potential to serve as reliable energy generators in international locations where the utility grid is often unstable.

For this research, a manufacturing process that had approximately …

High Temperature Flooded Expansion For Solar Thermal Power Generation, Nelson Alexander James

Open Access Theses

Even though solar power usage has seen rapid growth over the past decade, fossil fuel generation sources are still generally a less expensive means of producing power. The Liquid-Flooded Ericsson Cycle (LFEC) was investigated as a high efficiency power cycle for reducing the cost of concentrated solar power (CSP) plants and helping to address this cost disparity. High temperature flooded expansion was identified as one of the main challenges in regards to utilizing the LFEC as a power cycle. Thermodynamic models were developed to help assess the performance of the LFEC and a load stand was constructed to test a …

Identifying, Monitoring, Quantifying And Converting Algae To Bio-Fuels In Bio-Reactors, Alice C. Jernigan

Graduate Theses and Dissertations

Growing algae as a source for bio-fuels has become an area of interest due to concerns about global warming and the reliability and ecology of the production of fossil fuels. Dried algae harvested from a pilot water quality improvement technology at the Rockaway Wastewater Treatment Facility in New York were examined as a source of carbohydrates and lipids for the production of bio-fuels in bio-reactors. The length of storage time, storage conditions, sugar and lipid extraction processes, and fuel production were studied. The results show that if the algae is stored dry (0.015 g/g algae even after a year in …

Cztsse Thin Film Solar Cells : Surface Treatments, Chinmay S. Joglekar

Open Access Theses

Chalcopyrite semiconducting materials, specifically CZTS, are a promising alternative to traditional silicon solar cell technology. Because of the high absorption coefficient; films of the order of 1 micrometer thickness are sufficient for the fabrication of solar cells. Liquid based synthesis methods are advantageous because they are easily scalable using the roll to roll manufacturing techniques.

Various treatments are explored in this study to enhance the performance of the selenized CZTS film based solar cells. Thiourea can be used as a sulfur source and can be used to tune band gap of CZTSSe. Bromine etching can be used to manipulate the …

Determinants Of Energy Efficiency Across Countries, Guolin Yao

Open Access Theses

With economic development, environmental concerns become more important. Economies cannot be developed without energy consumption, which is the major source of greenhouse gas emissions. Higher energy efficiency is one means of reducing emissions, but what determines energy efficiency?

In this research we attempt to find answers to this question by using cross-sectional country data; that is, we examine a wide range of possible determinants of energy efficiency at the country level in an attempt to find the most important causal factors. All countries are divided into three income groups: high-income countries, middle-income countries, and low-income countries. Energy intensity is used …

Usability Testing Of The M.A.E.G.U.S. Serious Game, James He

Open Access Theses

Interpreting raw data in serious games and simulations can be a time consuming and uninteresting task without visualizations. This study proposes one possible solution for an interface that incorporates data visualizations for Whittinghill and Nataraja's (2013) MAEGUS simulation, a serious game used to increase the retention of wind energy and solar energy concepts in students, while still being fun. After the interface was designed and developed, a think aloud usability test was conducted to answer the following research questions: how do students use a series of information visualizations to operate a multi-variate game-based simulation and what are some the usability …

Economic And Policy Analysis For Solar Pv Systems In Indiana, Jinho Jung

Open Access Theses

In recent years, the energy market in the US and globally is expanding the production of renewable energy. With other energy sources, solar energy for electricity is also expanding in the US. Indiana is one of the states expanding solar energy with solar PV systems. However, the economics of solar PV systems in Indiana have not been analyzed and electricity customers in Indiana are not informed enough about the economics of solar PV systems. Therefore, we conduct benefit cost analysis with several uncertain input variables to determine the economics of adopting solar PV systems in Indiana based on policy instruments …

M.A.E.G.U.S: Measuring Alternate Energy Generation Via Unity Simulation, Kavin Muhilan Nataraja

Open Access Theses

This paper presents the MAEGUS serious game and a study to determine its efficacy as a pedagogical tool. The MAEGUS serious game teaches sustainable energy concepts through gameplay simulating wind turbines and solar arrays. Players take the role of an energy manager for a city and use realistic data and information visualizations to learn the physical factors of wind and solar energy generation. The MAEGUS serious game study compares game assisted learning to a more traditional teaching method such as reading material in a crossover study, the results of which can inform future serious game development for educational purposes.