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Physical Sciences and Mathematics Commons

Open Access. Powered by Scholars. Published by Universities.®

Oceanography and Atmospheric Sciences and Meteorology

Faculty Publications

2019

Dolostones; laser ablation ICPMS; rare earth elements; RARE-EARTH-ELEMENTS; ISOTOPIC EVIDENCE; VOLCANIC ASH; REE PATTERNS; PORE WATERS; DOLOMITIZATION; ORIGIN; SEAWATER; CARBONATES; LAURENTIA

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Full-Text Articles in Physical Sciences and Mathematics

In Situ Geochemistry Of Middle Ordovician Dolomites Of The Upper Mississippi Valley, Achim D. Herrmann Feb 2019

In Situ Geochemistry Of Middle Ordovician Dolomites Of The Upper Mississippi Valley, Achim D. Herrmann

Faculty Publications

The dolomitization and diagenetic history of Ordovician carbonates of southern Wisconsin is complex. Previous studies attributed dolomitization to various diagenetic factors and environments. In this study, high-resolution, in situ laser ablation inductively coupled mass spectrometry analysis of rare earth element patterns of dolomite was used to assess the diagenetic fluids responsible for dolomitization of the Ordovician Decorah Formation. Integrated geochemical data and petrographic evidence suggest that the dolostones are formed in two different diagenetic realms: shallow burial and hydrothermal. Shallow burial dolomites exhibit three distinct rare earth element patterns. Dolomite from the middle portion of the Guttenberg Member exhibits light …