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Articles 1 - 7 of 7
Full-Text Articles in Physical Sciences and Mathematics
Overview Of The 2007 And 2008 Campaigns Conducted As Part Of The Greenland Summit Halogen-HoX Experiment (Gshox), J L. Thomas, Jack E. Dibb, J Stutz, R Von Glasow, Steve Brooks, L Gregory Huey, Barry Lefer
Overview Of The 2007 And 2008 Campaigns Conducted As Part Of The Greenland Summit Halogen-HoX Experiment (Gshox), J L. Thomas, Jack E. Dibb, J Stutz, R Von Glasow, Steve Brooks, L Gregory Huey, Barry Lefer
Earth Sciences
From 10 May through 17 June 2007 and 6 June through 9 July 2008 intensive sampling campaigns at Summit, Greenland confirmed that active bromine chemistry is occurring in and above the snow pack at the highest part of the Greenland ice sheet (72°36´ N, 38°25´ W and 3.2 km above sea level). Direct measurements found BrO and soluble gas phase Br− mixing ratios in the low pptv range on many days (maxima < 10 pptv). Conversion of up to 200 pg m−3 of gaseous elemental mercury (GEM) to reactive gaseous mercury (RGM) and enhanced OH relative to HO2 plus RO2 confirm that active bromine chemistry is …
Spectral Absorption Of Biomass Burning Aerosol Determined From Retrieved Single Scattering Albedo During Arctas, C A. Corr, S R. Hall, B E. Anderson, Kirk Ullman, A J. Beyersdorf, Kenn L. Thornhill, Michael J. Cubison, Jose L. Jimenez, Armin Wisthaler, Jack E. Dibb
Spectral Absorption Of Biomass Burning Aerosol Determined From Retrieved Single Scattering Albedo During Arctas, C A. Corr, S R. Hall, B E. Anderson, Kirk Ullman, A J. Beyersdorf, Kenn L. Thornhill, Michael J. Cubison, Jose L. Jimenez, Armin Wisthaler, Jack E. Dibb
Earth Sciences
Actinic flux, as well as aerosol chemical and optical properties, were measured aboard the NASA DC-8 aircraft during the ARCTAS (Arctic Research of the Composition of the Troposphere from Aircraft and Satellites) mission in Spring and Summer 2008. These measurements were used in a radiative transfer code to retrieve spectral (350-550 nm) aerosol single scattering albedo (SSA) for biomass burning plumes encountered on 17 April and 29 June. Retrieved SSA values were subsequently used to calculate the absorption Angstrom exponent (AAE) over the 350-500 nm range. Both plumes exhibited enhanced spectral absorption with AAE values that exceeded 1 (6.78 ± …
Characteristics Of Tropospheric Ozone Depletion Events In The Arctic Spring: Analysis Of The Arctas, Arcpac, And Arcions Measurements And Satellite Bro Observations, T P. Kurosu, Yuhang Wang, T P. Kurosu, K Chance, A Rozanov, A Richter, S J. Oltmans, A M. Thompson, Jonathan Hair, Marta Fenn, Andrew Weinheimer, Thomas B. Ryerson, S Solberg, L Gregory Huey, J Liao, Jack E. Dibb, J A. Neuman, J Nowak, B Pierce, M Natarajan, J Al-Saadi
Characteristics Of Tropospheric Ozone Depletion Events In The Arctic Spring: Analysis Of The Arctas, Arcpac, And Arcions Measurements And Satellite Bro Observations, T P. Kurosu, Yuhang Wang, T P. Kurosu, K Chance, A Rozanov, A Richter, S J. Oltmans, A M. Thompson, Jonathan Hair, Marta Fenn, Andrew Weinheimer, Thomas B. Ryerson, S Solberg, L Gregory Huey, J Liao, Jack E. Dibb, J A. Neuman, J Nowak, B Pierce, M Natarajan, J Al-Saadi
Earth Sciences
Arctic ozone depletion events (ODEs) are caused by halogen catalyzed ozone loss. In situ chemistry, advection of ozone-poor air mass, and vertical mixing in the lower troposphere are important factors affecting ODEs. To better characterize the ODEs, we analyze the combined set of surface, ozonesonde, and aircraft in situ measurements of ozone and bromine compounds during the Arctic Research of the Composition of the Troposphere from Aircraft and Satellites (ARCTAS), the Aerosol, Radiation, and Cloud Processes affecting Arctic Climate (ARCPAC), and the Arctic Intensive Ozonesonde Network Study (ARCIONS) experiments (April 2008). Tropospheric BrO columns retrieved from satellite measurements and back …
An Analysis Of Fast Photochemistry Over High Northern Latitudes During Spring And Summer Using In-Situ Observations From Arctas And Topse, J R. Olson, J H. Crawford, William H. Brune, J Mao, Xinrong Ren, A Fried, B Anderson, E C. Apel, M Beaver, D R. Blake, G Chen, John D. Crounse, Jack E. Dibb, Glenn Diskin, S R. Hall, L Gregory Huey, D Knapp, D Richter, D Riemer, J St. Clair, Kirk Ullman, J Walega, P Weibring, Andrew Weinheimer, Paul Wennberg, Armin Wisthaler
An Analysis Of Fast Photochemistry Over High Northern Latitudes During Spring And Summer Using In-Situ Observations From Arctas And Topse, J R. Olson, J H. Crawford, William H. Brune, J Mao, Xinrong Ren, A Fried, B Anderson, E C. Apel, M Beaver, D R. Blake, G Chen, John D. Crounse, Jack E. Dibb, Glenn Diskin, S R. Hall, L Gregory Huey, D Knapp, D Richter, D Riemer, J St. Clair, Kirk Ullman, J Walega, P Weibring, Andrew Weinheimer, Paul Wennberg, Armin Wisthaler
Earth Sciences
Observations of chemical constituents and meteorological quantities obtained during the two Arctic phases of the airborne campaign ARCTAS (Arctic Research of the Composition of the Troposphere from Aircraft and Satellites) are analyzed using an observationally constrained steady state box model. Measurements of OH and HO2 from the Penn State ATHOS instrument are compared to model predictions. Forty percent of OH measurements below 2 km are at the limit of detection during the spring phase (ARCTAS-A). While the median observed-to-calculated ratio is near one, both the scatter of observations and the model uncertainty for OH are at the magnitude of …
Modeling Chemistry In And Above Snow At Summit, Greenland – Part 2: Impact Of Snowpack Chemistry On The Oxidation Capacity Of The Boundary Layer, J L. Thomas, Jack E. Dibb, L Gregory Huey, J Liao, D Tanner, Barry Lefer, R Von Glasow, J Stutz
Modeling Chemistry In And Above Snow At Summit, Greenland – Part 2: Impact Of Snowpack Chemistry On The Oxidation Capacity Of The Boundary Layer, J L. Thomas, Jack E. Dibb, L Gregory Huey, J Liao, D Tanner, Barry Lefer, R Von Glasow, J Stutz
Earth Sciences
The chemical composition of the boundary layer in snow covered regions is impacted by chemistry in the snowpack via uptake, processing, and emission of atmospheric trace gases. We use the coupled one-dimensional (1-D) snow chemistry and atmospheric boundary layer model MISTRA-SNOW to study the impact of snowpack chemistry on the oxidation capacity of the boundary layer. The model includes gas phase photochemistry and chemical reactions both in the interstitial air and the atmosphere. While it is acknowledged that the chemistry occurring at ice surfaces may consist of a true quasi-liquid layer and/or a concentrated brine layer, lack of additional knowledge …
The Carrington Event Not Observed In Most Ice Core Nitrate Records, E W. Wolff, M Bigler, M. A. J. Curran, Jack E. Dibb, M M. Frey, M Legrand, J R. Mcconnell
The Carrington Event Not Observed In Most Ice Core Nitrate Records, E W. Wolff, M Bigler, M. A. J. Curran, Jack E. Dibb, M M. Frey, M Legrand, J R. Mcconnell
Earth Sciences
The Carrington Event of 1859 is considered to be among the largest space weather events of the last 150 years. We show that only one out of 14 well-resolved ice core records from Greenland and Antarctica has a nitrate spike dated to 1859. No sharp spikes are observed in the Antarctic cores studied here. In Greenland numerous spikes are observed in the 40 years surrounding 1859, but where other chemistry was measured, all large spikes have the unequivocal signal, including co-located spikes in ammonium, formate, black carbon and vanillic acid, of biomass burning plumes. It seems certain that most spikes …
Analysis Of Satellite-Derived Arctic Tropospheric Bro Columns In Conjunction With Aircraft Measurements During Arctas And Arcpac, S Choi, Yuhang Wang, R J. Salawitch, T Canty, J Joiner, T Zeng, T P. Kurosu, K Chance, A Richter, L Gregory Huey, J Liao, J A. Neuman, J Nowak, Jack E. Dibb, Andrew Weinheimer, Glenn Diskin, Thomas B. Ryerson, Arlindo Da Silva, J Curry, D Kinnison, S Tilmes, P F. Levelt
Analysis Of Satellite-Derived Arctic Tropospheric Bro Columns In Conjunction With Aircraft Measurements During Arctas And Arcpac, S Choi, Yuhang Wang, R J. Salawitch, T Canty, J Joiner, T Zeng, T P. Kurosu, K Chance, A Richter, L Gregory Huey, J Liao, J A. Neuman, J Nowak, Jack E. Dibb, Andrew Weinheimer, Glenn Diskin, Thomas B. Ryerson, Arlindo Da Silva, J Curry, D Kinnison, S Tilmes, P F. Levelt
Earth Sciences
We derive tropospheric column BrO during the ARCTAS and ARCPAC field campaigns in spring 2008 using retrievals of total column BrO from the satellite UV nadir sensors OMI and GOME-2 using a radiative transfer model and stratospheric column BrO from a photochemical simulation. We conduct a comprehensive comparison of satellite-derived tropospheric BrO column to aircraft in-situ observations of BrO and related species. The aircraft profiles reveal that tropospheric BrO, when present during April 2008, was distributed over a broad range of altitudes rather than being confined to the planetary boundary layer (PBL). Perturbations to the total column resulting from tropospheric …