Physical Sciences and Mathematics Commons^™

A New Interpretation Of Total Column Bro During Arctic Spring, R J. Salawitch, T Canty, T P. Kurosu, K Chance, Q Liang, Arlindo Da Silva, S Pawson, J E. Neilsen, J. V. Rodriguez, P K. Bhartia, X Liu, L Gregory Huey, J Liao, R E. Stickel, D Tanner, Jack E. Dibb, W R. Simpson, D Donohue, Andrew Weinheimer, F Flocke, D Knapp, D Montzka, J A. Neuman, J Nowak, Thomas B. Ryerson, S J. Oltmans, D R. Blake, E L. Atlas, D Kinnison, S Tilmes, L L. Pan, F Hendrick, R Bradley Pierce, M Van Roozendael, K Kreher, P V. Johnston, R S. Gao, B Johnson, T P. Bui, G Chen, R B. Pierce, J H. Crawford, D J. Jacob

Earth Sciences

Emission of bromine from sea-salt aerosol, frost flowers, ice leads, and snow results in the nearly complete removal of surface ozone during Arctic spring. Regions of enhanced total column BrO observed by satellites have traditionally been associated with these emissions. However, airborne measurements of BrO and O₃ within the convective boundary layer (CBL) during the ARCTAS and ARCPAC field campaigns at times bear little relation to enhanced column BrO. We show that the locations of numerous satellite BrO “hotspots” during Arctic spring are consistent with observations of total column ozone and tropopause height, suggesting a stratospheric origin to these …