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Full-Text Articles in Physical Sciences and Mathematics

Characterization Of Β-Lactam Resistant Pandemic Serotypes Of Vibrio Cholerae Isolated From Ships' Ballast Tanks And Coastal Waters, Amanda Lynn Goodrich Oct 2006

Characterization Of Β-Lactam Resistant Pandemic Serotypes Of Vibrio Cholerae Isolated From Ships' Ballast Tanks And Coastal Waters, Amanda Lynn Goodrich

OES Theses and Dissertations

Vibrio cholerae serotypes 01 and 0139 are responsible for world-wide epidemics of cholera. These pandemic causing strains must possess genes that encode for the cholera toxin (CTX) and toxin co-regulated pili (TCP) in order to infect their hosts. In this study, 284 isolates of Vibrio cholerae from ballast and coastal waters were serotyped, with 11 % testing positive for serotype 01 and 21 % testing positive for serotype 0139. PCR assays were used to detect the presence of ctxA and tcpA genes in all positive isolates, none of which contained ctxA while 2% of the isolates contained tcpA. The 01 …


Exchange Hydrodynamics Between A Subestuary And Its Adjacent Estuary, Diego A. Narváez Oct 2006

Exchange Hydrodynamics Between A Subestuary And Its Adjacent Estuary, Diego A. Narváez

OES Theses and Dissertations

Four oceanographic surveys and two periods of moored data were analyzed to describe the subtidal exchange hydrodynamics between a subestuary (Nansemond River) and its adjacent estuary (James River) in the lower Chesapeake Bay. The surveys were carried out during two semidiurnal periods (~25 hrs), which included two spring and two neap tides. Velocity profiles and hydrographic data were recorded over an area ~4 km long and ~1 km wide allowing a spatial resolution rarely obtained with observational data. The results obtained in the surveys were extended with instruments deployed at the entrance to the subestuary during winter and summer time …


Circulation, Vol. 13, No. 2, Center For Coastal Physical Oceanography, Old Dominion University, Michael Ott Jul 2006

Circulation, Vol. 13, No. 2, Center For Coastal Physical Oceanography, Old Dominion University, Michael Ott

CCPO Circulation

Summer 2006 issue of CCPO Circulation featuring article "Chesapeake Bay Mouth Monitoring Program" by Dr. Michael Ott


Marine And Freshwater Cyanophages In A Laurentian Great Lake: Evidence From Infectivity Assays And Molecular Analyses Of G20 Genes, Steven W. Wilhelm, Matthew J. Carberry, Melanie L. Eldridge, Leo Poorvin, Matthew A. Saxton, Martina A. Doblin Jul 2006

Marine And Freshwater Cyanophages In A Laurentian Great Lake: Evidence From Infectivity Assays And Molecular Analyses Of G20 Genes, Steven W. Wilhelm, Matthew J. Carberry, Melanie L. Eldridge, Leo Poorvin, Matthew A. Saxton, Martina A. Doblin

OES Faculty Publications

While it is well established that viruses play an important role in the structure of marine microbial food webs, few studies have directly addressed their role in large lake systems. As part of an ongoing study of the microbial ecology of Lake Erie, we have examined the distribution and diversity of viruses in this system. One surprising result has been the pervasive distribution of cyanophages that infect the marine cyanobacterial isolate Synechococcus sp. strain WH7803. Viruses that lytically infect this cyanobacterium were identified throughout the western basin of Lake Erie, as well as in locations within the central and eastern …


Tidally Induced Variability At The Chesapeake Bay Entrance, María Andrea Piñones Jul 2006

Tidally Induced Variability At The Chesapeake Bay Entrance, María Andrea Piñones

OES Theses and Dissertations

Time series of current velocity from 6 stations at the Chesapeake Bay entrance were used to study the variability of tidal currents. Particular emphasis was placed on the semidiurnal tidal currents, which explains ~ 70% of the variability of tidal currents. Four different deployments that spanned more than one year showed that the vertical structure of the semidiurnal tidal currents vary seasonally in response to changes in water column stratification. Under destratified conditions favored by wind forcing, the semidiurnal tidal currents rotated cyclonically throughout the water column, thus emulating a Kelvin wave. In contrast, during stratified conditions the tidal currents …


Fortnightly Variability At The Transition Between Two Sub-Estuaries, Mayra Lorena Riveron Enzastiga Jul 2006

Fortnightly Variability At The Transition Between Two Sub-Estuaries, Mayra Lorena Riveron Enzastiga

OES Theses and Dissertations

Profiles of current velocity from an Acoustic Doppler Current Profiler (ADCP) and of water salinity, temperature and density from a Conductivity-Temperature-Depth (CTD) recorder, were combined with surface salinity, temperature and density from a Conductivity-Temperature (CT) recorder to elucidate the fortnightly variability at the Lafayette River entrance. The Lafayette River connects at its mouth with the Elizabeth River, which is a tributary to the James River in the Chesapeake Bay. Data were collected in four experiments during consecutive spring and neap tides in the autumn of 2000, and in the spring of 2001. Each experiment was carried out for -25 hours …


Continuously Stratified Flow Dynamics Over A Hollow, David Salas-Monreal Jul 2006

Continuously Stratified Flow Dynamics Over A Hollow, David Salas-Monreal

OES Theses and Dissertations

Acoustic Doppler current profiles (ADCP) and density profiles were measured over three lower Chesapeake Bay bathymetric depressions (hollows) in order to determine the effects of a hollow on a continuously stratified flow. Measurements showed an acceleration of the near-bottom flow as it moved toward the deepest part of the hollows, in contrast to the deceleration expected from two-dimensional Bernoulli-type dynamics. The acceleration was attributed to lateral water intrusions that were most apparent during floods. The presence of lateral water intrusions was corroborated by observations in a transverse section that crossed the deepest part of the hollows. The observed deceleration of …


Substituting Otoliths For Chemical Analyses: Does Sagitta = Lapillus?, Nathan G. Smith, Cynthia M. Jones May 2006

Substituting Otoliths For Chemical Analyses: Does Sagitta = Lapillus?, Nathan G. Smith, Cynthia M. Jones

OES Faculty Publications

Chemical analysis of fish otoliths has become an important technique in fisheries science with widespread applications. Most research up to this point has focused predominantly on sagittal otoliths, but the underlying assumptions may also apply to lapilli. The goal of this study was to determine whether lapilli and sagittae have the same otolith chemistry and whether one can be substituted for the other for solution-based chemical analysis in wild-captured fish. We compared the stable isotope chemistry (δ13C and δ18O) of paired sagittae and lapilli of juvenile spotted seatrout Cynoscion nebulosus collected from Chesapeake Bay seagrass beds in 2002. …


Biogeochemistry Of Arsenic And Antimony In The North Pacific Ocean, Gregory A. Cutter, Lynda S. Cutter May 2006

Biogeochemistry Of Arsenic And Antimony In The North Pacific Ocean, Gregory A. Cutter, Lynda S. Cutter

OES Faculty Publications

The biogeochemical cycles of the metalloid elements arsenic and antimony were examined along a 15,000 km surface water transect and at 9 vertical profile stations in the western North Pacific Ocean as part of the 2002 IOC Contaminant Baseline Survey. Results show that the speciation of dissolved arsenic (As III, As V, and methylated As) was subtly controlled by the arsenate (AsV)/phosphate ratio. An additional fraction of presumed organic arsenic previously reported in coastal waters was also present (~15% of the total As) in oceanic surface waters. Dissolved inorganic antimony displayed mildly scavenged behavior that was confirmed by correlations with …


Thermometric Measurements Of The Molecular Sublayer At The Air-Water Interface, B. Ward Apr 2006

Thermometric Measurements Of The Molecular Sublayer At The Air-Water Interface, B. Ward

OES Faculty Publications

[1] A series of measurements was conducted in the AirSea Interaction Saltwater Tank (ASIST) to study the response of the air-water interfacial molecular sublayer under various heat flux and wind speed conditions. In-situ gradients were measured with a platinum-plated tungsten wire microthermometer, which resolved the temperature of the thermally conductive sublayer. Air-sea heat flux was controlled by changing the air-water temperature difference (ΔTAW) and the wind speed, and measurements were made for three ΔTAW regimes over a range of wind speeds. A function was fitted to the measured temperature profiles as a way of extracting the boundary …


Correlating Late Pleistocene Deposits On The Coastal Plain Of Virginia With The Glacial-Eustatic Sea-Level Curve, Timothy Wullschleger Scott Apr 2006

Correlating Late Pleistocene Deposits On The Coastal Plain Of Virginia With The Glacial-Eustatic Sea-Level Curve, Timothy Wullschleger Scott

OES Theses and Dissertations

Late Pleistocene sediments mapped along Virginia's southeastern coastal plain record deposition by high-frequency cycles during isotope stages 5 to 1. Correlations between several geologic units both south (S) and east (E) of the Chesapeake Bay have proven difficult due to insufficient dating methods. To improve these regional correlations, two members of the Tabb Formation on Virginia's southside and two formations on the southern Delmarva Peninsula were selected for stratigraphic analyses. Ground penetrating radar provided geologic details in areas where samples were collected for optically stimulated luminescence (OSL) dating. The stratigraphically older units, Sedgefield Member of the Tabb Formation (S) and …


Hydrographic Observations During The 2002 Ioc Contaminant Baseline Survey In The Western Pacific Ocean, C. I. Measures, Greg A. Cutter, W. M. Landing, R. T. Powell Mar 2006

Hydrographic Observations During The 2002 Ioc Contaminant Baseline Survey In The Western Pacific Ocean, C. I. Measures, Greg A. Cutter, W. M. Landing, R. T. Powell

OES Faculty Publications

The 2002 IOC Contaminant Baseline Survey in the western Pacific Ocean was the fourth in a series of cruises intended to establish the contemporary concentrations of trace elements and other materials in the major water masses of the ocean and to illuminate the pathways by which materials delivered to the surface ocean are incorporated in the subsurface waters. The expedition occupied 9 vertical profile stations encompassing the subtropical and subarctic gyre of the western North Pacific. In addition, underway surface water samples were collected during transits between the stations. This paper uses the temperature, salinity, nutrient, oxygen, and chlorophyll data …


A Temporal Approximate Deconvolution Model For Large-Eddy Simulation, C. D. Pruett, B. C. Thomas, C. E. Grosch, T. B. Gatski Feb 2006

A Temporal Approximate Deconvolution Model For Large-Eddy Simulation, C. D. Pruett, B. C. Thomas, C. E. Grosch, T. B. Gatski

CCPO Publications

A temporal approximate deconvolution model (TADM) is developed for large-eddy simulation and is demonstrated for plane-channel flow at Re-tau=590. The TADM combines explicit causal time-domain filtering with linear deconvolution (defiltering) to approximate unfiltered fields and residual stress to arbitrarily high order. The TADM methodology appears to lead to a robust family of residual-stress models that should provide a viable alternative to conventional (spatial) filtering for applications in which spatial filtering is problematic, e.g., for problems requiring unstructured or highly stretched grids. (c) 2006 American Institute of Physics.


Loop Current Warming By Hurricane Wilma, Lie-Yauw Oey, Tal Ezer, Dong-Ping Wang, S. J. Fan, Xun-Qiang Yin Jan 2006

Loop Current Warming By Hurricane Wilma, Lie-Yauw Oey, Tal Ezer, Dong-Ping Wang, S. J. Fan, Xun-Qiang Yin

CCPO Publications

Hurricanes mix and cool the upper ocean, as shown here in observations and modeling of the Caribbean Sea and the Gulf of Mexico during the passage of hurricane Wilma. Curiously, the upper ocean around the Loop Current warmed prior to Wilma's entrance into the Gulf. The major cause was increased volume and heat transports through the Yucatan Channel produced by storm-induced convergences in the northwestern Caribbean Sea. Such oceanic variability may have important impacts on hurricane predictions.


Topographic Influence On Overflow Dynamics: Idealized Numerical Simulations And The Faroe Bank Channel Overflow, Tal Ezer Jan 2006

Topographic Influence On Overflow Dynamics: Idealized Numerical Simulations And The Faroe Bank Channel Overflow, Tal Ezer

CCPO Publications

Properties of the North Atlantic Deep Water (NADW) depend on mixing that occurs in the Denmark Strait (DS) and the Faroe Bank Channel (FBC) overflow regions. How the sill's topography in those regions may affect mixing processes and downstream variability is thus investigated using a high-resolution terrain-following ocean model. Model results agree with observations that show enhanced mixing and entrainment downstream from the sill; however, mixing seems to occur over a longer distance downstream from the FBC sill and more abruptly downstream from the DS sill. Sensitivity experiments with various FBC sill widths demonstrate that the narrow sill is responsible …


Circulation, Vol. 13, No. 1, Center For Coastal Physical Oceanography, Old Dominion University, John M. Klinck Jan 2006

Circulation, Vol. 13, No. 1, Center For Coastal Physical Oceanography, Old Dominion University, John M. Klinck

CCPO Circulation

Winter 2006 issue of CCPO Circulation featuring article "Biological Processes in Bivalves as Revealed by Numerical Models" by Dr. John Klinck


A Comparison Of Global Estimates Of Marine Primary Production From Ocean Color, Mary-Elena Carr, Marjorie A. M. Friedrichs, Marjorie Schmeltz, Maki Noguchi Aita, David Antoine, Kevin R. Arrigo, Ichio Asanuma, Oliver Aumont, Richard Barber, Michael Behrenfeld Jan 2006

A Comparison Of Global Estimates Of Marine Primary Production From Ocean Color, Mary-Elena Carr, Marjorie A. M. Friedrichs, Marjorie Schmeltz, Maki Noguchi Aita, David Antoine, Kevin R. Arrigo, Ichio Asanuma, Oliver Aumont, Richard Barber, Michael Behrenfeld

CCPO Publications

The third primary production algorithm round robin (PPARR3) compares output from 24 models that estimate depth-integrated primary production from satellite measurements of ocean color, as well as seven general circulation models (GCMs) coupled with ecosystem or biogeochemical models. Here we compare the global primary production fields corresponding to eight months of 1998 and 1999 as estimated from common input fields of photosynthetically-available radiation (PAR), sea-surface temperature (SST), mixed-layer depth, and chlorophyll concentration. We also quantify the sensitivity of the ocean-color-based models to perturbations in their input variables. The pair-wise correlation between ocean-color models was used to cluster them into groups …


Transport Of Antarctic Krill (Euphausia Superba) Across The Scotia Sea. Part Ii: Krill Growth And Survival, Bettina A. Fach, Eileen E. Hofmann, Eugene J. Murphy Jan 2006

Transport Of Antarctic Krill (Euphausia Superba) Across The Scotia Sea. Part Ii: Krill Growth And Survival, Bettina A. Fach, Eileen E. Hofmann, Eugene J. Murphy

CCPO Publications

A time-dependent, size-structured, physiologically based krill growth model was used in conjunction with a circulation model to test the hypothesis that Antarctic krill (Euphausia superba) populations at South Georgia are sustained by import of individuals from upstream regions. Surface phytoplankton concentrations along the simulated drifter trajectories were extracted from historical Coastal Zone Color Scanner (CZCS) measurements and sea ice biota concentrations were calculated from sea ice concentration and extent extracted along drifter trajectories from Special Sensor Microwave/ Imager measurements. As additional food sources, a time series of heterotrophic food was constructed from historical data, and time series of …


Pelagic Functional Group Modeling: Progress, Challenges And Prospects, Raleigh R. Hood, Edward A. Laws, Robert A. Armstrong, Nicholas R. Bates, Christopher W. Brown, Craig A. Carlson, Fei Chai, Scott C. Doney, Paul G. Falkowski, Richard A. Feely, Marjorie A. M. Friedrichs Jan 2006

Pelagic Functional Group Modeling: Progress, Challenges And Prospects, Raleigh R. Hood, Edward A. Laws, Robert A. Armstrong, Nicholas R. Bates, Christopher W. Brown, Craig A. Carlson, Fei Chai, Scott C. Doney, Paul G. Falkowski, Richard A. Feely, Marjorie A. M. Friedrichs

CCPO Publications

In this paper, we review the state of the art and major challenges in current efforts to incorporate biogeochemical functional groups into models that can be applied on basin-wide and global scales, with an emphasis on models that might ultimately be used to predict how biogeochemical cycles in the ocean will respond to global warming. We define the term "biogeochemical functional group" to refer to groups of organisms that mediate specific chemical reactions in the ocean. Thus, according to this definition, "functional groups" have no phylogenetic meaning-these are composed of many different species with common biogeochemical functions.

Substantial progress has …


Western Caribbean Sea Surface Temperatures During The Late Quaternary, Matthew W. Schmidt, Maryline J. Vautravers, Howard J. Spero Jan 2006

Western Caribbean Sea Surface Temperatures During The Late Quaternary, Matthew W. Schmidt, Maryline J. Vautravers, Howard J. Spero

OES Faculty Publications

[1] Mg/Ca ratios in the planktonic foraminifera Globigerinoides ruber from Colombian Basin core ODP 999A suggest that Caribbean sea surface temperatures ( SSTs) were from 2.1 to 2.7°C colder than the present during the last three glacial maximums. In comparison, faunal derived SSTs ( SIMMAX method) show that August SSTs in the Caribbean varied < 2° over the past 360 kyr, whereas February SSTs varied between 21.0°C and 26.5°C. Changes in the Mg/Ca-SST record contain a strong 23 kyr periodicity, suggesting the Mg/Ca-SST record reflects a warm season weighted SST average rather than an annual mean SST. Combining several dissolution indices, we identify brief periods of decreased carbonate preservation in our record and show that MIS 11 stands out as the most intensive dissolution cycle in the Caribbean over the last 460 kyr. Comparison of Caribbean SST change with a similar estimate of tropical SST variability in the western Pacific over the past 360 kyr reveals shifts in the east-west tropical SST gradient that are coeval with glacial-interglacial climate change and consistent both with a southward migration of the glacial ITCZ and with a glacial El Niño-like mode of tropical circulation.


Red And Black Tides: Quantitative Analysis Of Water-Leaving Radiance And Perceived Color For Phytoplankton, Colored Dissolved Organic Matter, And Suspended Sediments, Heidi M. Dierssen, Raphael M. Kudela, John P. Ryan, Richard C. Zimmerman Jan 2006

Red And Black Tides: Quantitative Analysis Of Water-Leaving Radiance And Perceived Color For Phytoplankton, Colored Dissolved Organic Matter, And Suspended Sediments, Heidi M. Dierssen, Raphael M. Kudela, John P. Ryan, Richard C. Zimmerman

OES Faculty Publications

Using field measurements and quantitative modeling, we demonstrate that red coloration of the sea surface is not associated with any particular group of phytoplankton and is strongly dependent on the physiology of the human visual system. Red or brown surface waters can be produced by high concentrations of most types of algae, colored dissolved organic matter, or suspended sediment. Even though light reflected by red tides commonly peaks in the yellow spectral region (570–580 nm), human color perception requires consideration of the entire spectrum of light relative to receptors within the human eye. The color shift from green to red …


Ocean Warming And Freshening In The Northern Gulf Of Alaska, Thomas C. Royer, Chester E. Grosch Jan 2006

Ocean Warming And Freshening In The Northern Gulf Of Alaska, Thomas C. Royer, Chester E. Grosch

CCPO Publications

Water column temperatures on the shelf in the northern Gulf of Alaska have increased more than 0.8 degrees C and vertical density stratification has increased since 1970 near Seward, Alaska throughout the 250 m depth. This high latitude marine system has low water temperatures, high rates of precipitation, glacial melting, high wind speeds and high rates of biological productivity. A more than 300 km alongshore shift ( locally westward) of isotherms is suggested. The observations are consistent with a conceptual ocean-atmosphere circulation model that employs coastal freshwater discharge, glacial ablation and wind forcing. Positive regional feedback mechanisms accelerate the discharge …


Inter-Annual Sea Level Variability In The Southern Gulf Of Mexico (1966-1976), David Alberto Salas-De-León, Maria Adela Monreal-Gómez, David Salas-Monreal, Mayra Lorena Riveron-Enzastiga, Norma Leticia Sánchez-Santillan Jan 2006

Inter-Annual Sea Level Variability In The Southern Gulf Of Mexico (1966-1976), David Alberto Salas-De-León, Maria Adela Monreal-Gómez, David Salas-Monreal, Mayra Lorena Riveron-Enzastiga, Norma Leticia Sánchez-Santillan

CCPO Publications

Hourly time series at seven locations throughout the southern Gulf of Mexico were used to calculate the trend and the inter-annual sea level. The sea level series from January 1966 to December 1976 were filtered using a Lanczos low pass filter to remove oscillations with periods smaller than one year. The results revealed a sea level increment of about 1.4 mm yr(-1) from 1966 to 1976 in the southern Gulf of Mexico. The monthly sea level variability obtained after the trends were removed, presented a sea level setup during winter and a sea level depression in summer attributed to seasonal …


Dynamics Of Carbon Allocation In A Deep-Water Population Of The Deciduous Kelp Pleurophycus Gardeneri (Laminariales), Clare M. Dominik, Richard C. Zimmerman Jan 2006

Dynamics Of Carbon Allocation In A Deep-Water Population Of The Deciduous Kelp Pleurophycus Gardeneri (Laminariales), Clare M. Dominik, Richard C. Zimmerman

OES Faculty Publications

Pleurophycus gardneri (Laminariales) is common in the low intertidal of the Northeast Pacific, but dominates many deep (30 to 40 m) rocky reefs in central California. Seasonal dynamics of productivity and resource allocation of a deep-water population of this deciduous, stipitate kelp were studied to understand how blade abscission affects the annual carbon budget. Patterns of growth, metabolism, and carbon storage and mobilization were measured monthly for 1 yr relative to in situ light and temperature, and used to model the annual carbon budget. The resulting carbon budget was used to determine if blade abscission effectively reduced respiratory demand during …


Nitrogen Fixation And Release Of Fixed Nitrogen By Trichodesmium Spp. In The Gulf Of Mexico, Margaret R. Mulholland, Peter W. Bernhardt, Cynthia A. Heil, Deborah A. Bronk, Judith M. O'Neil Jan 2006

Nitrogen Fixation And Release Of Fixed Nitrogen By Trichodesmium Spp. In The Gulf Of Mexico, Margaret R. Mulholland, Peter W. Bernhardt, Cynthia A. Heil, Deborah A. Bronk, Judith M. O'Neil

OES Faculty Publications

During a 3-yr study in the Gulf of Mexico, we measured dinitrogen (N2) fixation and nitrogen (N) release by Trichodesmium and compared these rates with water column N demand and the estimated N necessary to support blooms of Karenia brevis, a toxic dinoflagellate that severely affects the West Florida shelf. Net and gross N2 fixation rates were compared in simultaneous incubations using 15N2 uptake and acetylene reduction, respectively. The difference between net and gross N2 fixation is assumed to be an approximation of the rate of N release. Results demonstrate that Trichodesmium in …


Evaluating The Biogeochemical Cycle Of Selenium In San Francisco Bay Through Modeling, Shannon L. Meseck, Gregory A. Cutter Jan 2006

Evaluating The Biogeochemical Cycle Of Selenium In San Francisco Bay Through Modeling, Shannon L. Meseck, Gregory A. Cutter

OES Faculty Publications

A biogeochemical model was developed to simulate salinity, total suspended material, phytoplankton biomass, dissolved selenium concentrations (selenite, selenate, and organic selenide), and particulate selenium concentrations (selenite + selenate, elemental selenium, and organic selenide) in the San Francisco Bay estuary. Model-generated estuarine profiles of total dissolved selenium reproduced observed estuarine profiles at a confidence interval of 91- 99% for 8 different years under various environmental conditions. The model accurately reproduced the observed dissolved speciation at confidence intervals of 81-98% for selenite, 72-91% for selenate, and 60-96% for organic selenide. For particulate selenium, model-simulated estuarine profiles duplicated the observed behavior of total …


Iron In Ice Cores From Law Dome: A Record Of Atmospheric Iron Deposition For Maritime East Antarctica During The Holocene And Last Glacial Maximum, Ross Edwards, Peter N. Sedwick, Vin Morgan, Claude Boutron Jan 2006

Iron In Ice Cores From Law Dome: A Record Of Atmospheric Iron Deposition For Maritime East Antarctica During The Holocene And Last Glacial Maximum, Ross Edwards, Peter N. Sedwick, Vin Morgan, Claude Boutron

OES Faculty Publications

Total dissolvable iron (TDFe) was measured in sections of ice cores recovered from Law Dome on the coast of Wilkes Land, East Antarctica. These samples include ice dating from the Last Glacial Maximum (LGM), the Last Deglaciation, and the early and mid Holocene as well as samples from the Anthropocene that have been dated with seasonal to annual resolution. Combining our TDFe concentration data with estimates of the ice accumulation rate, we estimate the atmospheric iron deposition for Law Dome and the adjacent Southern Ocean during these periods. Our results indicate that the atmospheric iron deposition flux to this region …


Effects Of Salinity Changes On The Photodegradation And Ultraviolet-Visible Absorbance Of Terrestrial Dissolved Organic Matter, E. C. Minor, J. Pothen, B. J. Dalzell, H. Abdulla, K. Mopper Jan 2006

Effects Of Salinity Changes On The Photodegradation And Ultraviolet-Visible Absorbance Of Terrestrial Dissolved Organic Matter, E. C. Minor, J. Pothen, B. J. Dalzell, H. Abdulla, K. Mopper

Chemistry & Biochemistry Faculty Publications

We performed laboratory studies to determine the effects of salinity on the photodegradation of dissolved organic matter (DOM) from the Great Dismal Swamp, Virginia, an important source of terrestrial DOM to the lower Chesapeake Bay. Samples were created by mixing Great Dismal Swamp water (ionic strength approximate to 0 mol L-1) with modified artificial seawater solutions of differing salinities while keeping the final dissolved organic carbon (DOC) concentration constant. These samples were then irradiated for 24 h in a light box providing ultraviolet (UV) light similar to that of natural sunlight. Light absorbance and DOC concentrations decreased after …


Open-Ocean Carbon Monoxide Photoproduction, Aron Stubbins, Günther Uher, Cliff S. Law, Kenneth Mopper, Carol Robinson, Robert C. Upstill-Goddard Jan 2006

Open-Ocean Carbon Monoxide Photoproduction, Aron Stubbins, Günther Uher, Cliff S. Law, Kenneth Mopper, Carol Robinson, Robert C. Upstill-Goddard

Chemistry & Biochemistry Faculty Publications

Sunlight-initiated photolysis of chromophoric dissolved organic matter (CDOM) is the dominant source of carbon monoxide (CO) in the open-ocean. A modelling study was conducted to constrain this source. Spectral solar irradiance was obtained from two models (GCSOLAR and SMARTS2). Water-column CDOM and total light absorption were modelled using spectra collected along a Meridional transect of the Atlantic ocean using a 200-cm pathlength liquid waveguide UV-visible spectrophotometer. Apparent quantum yields for the production of CO (AQYCO) from CDOM were obtained from a parameterisation describing the relationship between CDOM light absorption coefficient and AQYCO and the CDOM spectra collected. …


The Role Of Lipids During Embryonic Development Of The Euphausiids Euphausia Pacifica And Thysanoessa Spinifera, Se-Jong Ju, H. Rodger Harvey, Jaime Gómez-Gutiérrez, William T. Peterson Jan 2006

The Role Of Lipids During Embryonic Development Of The Euphausiids Euphausia Pacifica And Thysanoessa Spinifera, Se-Jong Ju, H. Rodger Harvey, Jaime Gómez-Gutiérrez, William T. Peterson

OES Faculty Publications

To understand the role of lipids during early embryogenesis, major lipid classes together with individual fatty acid and sterol composition were determined in embryos from multiple developmental stages of the euphausiids Euphausia pacifica and Thysanoessa spinifera. Average lipid content in embryos of E. pacifica and T. spiniferafrom the earliest stage (multicell) were 4.45 and 3.69 µg embryo-1,respectively. During development, the lipid content decreased at similar rates in the embryos of both species. In contrast to many crustacean eggs, phospholipids were the dominant lipid class in all embryonic stages, with decreasing concentrations seen during development. Individual …