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Oceanography and Atmospheric Sciences and Meteorology

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University of South Carolina

Molecular

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Full-Text Articles in Physical Sciences and Mathematics

Molecular Properties Are A Primary Control On The Microbial Utilization Of Dissolved Organic Matter In The Ocean, Yuan Shen, Ronald Benner May 2020

Molecular Properties Are A Primary Control On The Microbial Utilization Of Dissolved Organic Matter In The Ocean, Yuan Shen, Ronald Benner

Faculty Publications

The global ocean sequesters a large amount of reduced carbon in dissolved organic molecules that can persist for centuries to millennia. The persistence of dissolved organic carbon (DOC) in the deep ocean has been attributed to inherently refractory molecules and to low concentrations of molecules, but the relative roles of molecular properties and molecular concentrations remain uncertain. We investigate both of these possibilities using bioas-say experiments with unfiltered seawater collected from five depths (50–1500 m) at the Bermuda Atlantic Time-Series Study site. The microbial utilization of compositionally distinct forms of seawater DOC at in situ and elevated concentrations was determined. …


A Molecular Perspective On The Ageing Of Marine Dissolved Organic Matter, R. Flerus, O. J. Lechtenfeld, B. P. Koch, S. L. Mccallister, P. Schmitt-Kopplin, Ronald Benner, G. Kattner Jan 2012

A Molecular Perspective On The Ageing Of Marine Dissolved Organic Matter, R. Flerus, O. J. Lechtenfeld, B. P. Koch, S. L. Mccallister, P. Schmitt-Kopplin, Ronald Benner, G. Kattner

Faculty Publications

Dissolved organic matter (DOM) was extracted by solid-phase extraction (SPE) from 137 water samples from different climate zones and different depths along an eastern Atlantic Ocean transect. The extracts were analyzed with Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) with electrospray ionization (ESI). Δ14C analyses were performed on subsamples of the SPE-DOM. In addition, the amount of dissolved organic carbon was determined for all water and SPE-DOM samples as well as the yield of amino sugars for selected samples. Linear correlations were observed between the magnitudes of 43 % of the FT-ICR mass peaks and the extract Δ14C …