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Full-Text Articles in Physical Sciences and Mathematics
Steady-State Aerosol Distributions In The Extra-Tropical, Lower Stratosphere And The Processes That Maintain Them, J. Wilson, Shan-Hu Lee, J. Reeves, C. Brock, H. Jonsson, B. Lafleur, M. Loewenstein, J. Podolske, E. Atlas, K. Boering, G. Toon, D. Fahey, T. Bui, G. Diskin, F. Moore
Steady-State Aerosol Distributions In The Extra-Tropical, Lower Stratosphere And The Processes That Maintain Them, J. Wilson, Shan-Hu Lee, J. Reeves, C. Brock, H. Jonsson, B. Lafleur, M. Loewenstein, J. Podolske, E. Atlas, K. Boering, G. Toon, D. Fahey, T. Bui, G. Diskin, F. Moore
Shan-Hu Lee
Measurements of aerosol, N2O and OCS made in the Northern Hemisphere below 21 km altitude following the eruption of Pinatubo are presented and analyzed. After September 1999, the oxidation of OCS and sedimentation of particles in the extra-tropical overworld north of 45 N are found to maintain the aerosol in a steady state. This analysis empirically links precursor gas to aerosol abundance throughout this region. These processes are tracked with age-of-air which offers advantages over tracking as a function of latitude and altitude. In the extra-tropical, lowermost stratosphere, normalized volume distributions appear constant in time after the fall of 1999. …
Ternary Homogeneous Nucleation Of H2so4, Nh3, And H2o Under Conditions Relevant To The Lower Troposphere, D. Benson, J. Yu, A. Markovich, Shan-Hu Lee
Ternary Homogeneous Nucleation Of H2so4, Nh3, And H2o Under Conditions Relevant To The Lower Troposphere, D. Benson, J. Yu, A. Markovich, Shan-Hu Lee
Shan-Hu Lee
Ternary homogeneous nucleation (THN) of H2SO4, NH3 and H2O has been used to explain new particle formation in various atmospheric regions, yet laboratory measurements of THN have failed to reproduce atmospheric observations. Here, we report first laboratory observations of THN made under conditions relevant to the lower troposphere ([H2SO4] of 106–107 cm−3, [NH3] of 0.08–20 ppbv, and a temperature of 288 K). Our observations show that NH3 can enhance atmospheric H2SO4aerosol nucleation and the enhancement factor (EF) in nucleation rate (J) due to NH3 (the ratio of Jmeasured with vs. without NH3) increases linearly with increasing [NH3] and increases with …