Physical Sciences and Mathematics Commons^™

Editorial: Carbon Cycling In Aquatic Critical Zones, Peng Yao, Thomas S. Bianchi, David J. Burdige, Xiaojuan Feng, Peter A. Raymond

OES Faculty Publications

No abstract provided.

Lipid Markers And Compound-Specific Carbon Isotopes As Diet And Biosynthesis Reflectors In The Northern Neptune Whelk Neptunea Heros, H. Rodger Harvey, Rachel Mcmahon, Karen A. Taylor

OES Faculty Publications

A suite of lipid biomarkers plus compound-specific carbon isotopes of major sterols were determined in muscle tissues across increasing sizes of northern Neptune whelks Neptunea heros, developing eggs and potential diets to link trophic patterns, metabolism and carbon sources on the Chukchi Sea shelf. Analysis of primary prey included the northern clam Astarte borealis, water column particulate organic matter (POM) and surface sediments near the collection sites. Sterols specific to major algal groups along with algal-derived polyunsaturated fatty acids (C20:5n-3, C20:4n-3, C22:6n-3) in whelk muscle tissue reflected the importance of algal primary production to benthic consumers and its …

Associated Dataset: Relative Impacts Of Global Changes And Regional Watershed Changes On The Inorganic Carbon Balance Of The Chesapeake Bay, Pierre St-Laurent, Marjorie A.M. Friedrichs

Data

The dataset is a permanent archive of the results presented in the associated publication (St-Laurent et al. 2020, Biogeosciences).

This study used a biogeochemical module embedded in the Regional Ocean Modeling System (ROMS) to examine the relative impacts of global changes and regional watershed changes on the inorganic carbon balance of the Chesapeake Bay over the past century. The numerical experiments contrast the periods 1900-1914 and 2000-2014 and the results are fully described in the associated publication.

Seasonal Variability Of The Co2 System In A Large Coastal Plain Estuary, Jaclyn R. Friedman, Elizabeth H. Shadwick, Marjorie A.M. Friedrichs, Raymond G. Najjar, Olivia A. De Meo, Fei Da, Juliette L. Smith

VIMS Articles

The Chesapeake Bay, a large coastal plain estuary, has been studied extensively in terms of its water quality, and yet, comparatively less is known about its carbonate system. Here we present discrete observations of dissolved inorganic carbon (DIC) and total alkalinity from four seasonal cruises in 2016–2017. These new observations are used to characterize the regional CO₂ system and to construct a DIC budget of the mainstem. In all seasons, elevated DIC concentrations were observed at the mouth of the bay associated with inflowing Atlantic Ocean waters, while minimum concentrations of DIC were associated with fresher waters at the …

Expected Limits On The Ocean Acidification Buffering Potential Of A Temperate Seagrass Meadow, David A. Koweek, R. C. Zimmerman, Kathryn M. Hewett, Brian Gaylord, Sarah N. Giddings, Kerry J. Nickols, Jennifer L. Ruesink, John J. Stachowicz, Yuichiro Takeshita, Ken Caldeira

OES Faculty Publications

Ocean acidification threatens many marine organisms, especially marine calcifiers. The only global‐scale solution to ocean acidification remains rapid reduction in CO₂ emissions. Nevertheless, interest in localized mitigation strategies has grown rapidly because of the recognized threat ocean acidification imposes on natural communities, including ones important to humans. Protection of seagrass meadows has been considered as a possible approach for localized mitigation of ocean acidification due to their large standing stocks of organic carbon and high productivity. Yet much work remains to constrain the magnitudes and timescales of potential buffering effects from seagrasses. We developed a biogeochemical box model to …

Open-Ocean Carbon Monoxide Photoproduction, Aron Stubbins, Günther Uher, Cliff S. Law, Kenneth Mopper, Carol Robinson, Robert C. Upstill-Goddard

Chemistry & Biochemistry Faculty Publications

Sunlight-initiated photolysis of chromophoric dissolved organic matter (CDOM) is the dominant source of carbon monoxide (CO) in the open-ocean. A modelling study was conducted to constrain this source. Spectral solar irradiance was obtained from two models (GCSOLAR and SMARTS2). Water-column CDOM and total light absorption were modelled using spectra collected along a Meridional transect of the Atlantic ocean using a 200-cm pathlength liquid waveguide UV-visible spectrophotometer. Apparent quantum yields for the production of CO (AQY_CO) from CDOM were obtained from a parameterisation describing the relationship between CDOM light absorption coefficient and AQY_CO and the CDOM spectra collected. …

The Role Of Benthic Fluxes Of Dissolved Organic Carbon In Oceanic And Sedimentary Carbon Cycling, Davd J. Burdige, Marc J. Alperin, Juliana Homstead, Christopher S. Martens

OES Faculty Publications

Benthic fluxes (sediment-water exchange) of dissolved organic carbon (DOC) represent a poorly quantified component of sedimentary and oceanic carbon cycling. In this paper we use pore water DOC data and direct DOC benthic flux measurements to begin to quantitatively examine this problem. These results suggest that marine sediments represent a significant source of DOC to the oceans, as a lower limit of the globally-integrated benthic DOC flux is comparable in magnitude to riverine inputs of organic carbon to the oceans. Benthic fluxes of DOC also appear to be similar in magnitude to other sedimentary processes such as organic carbon oxidation …