Physical Sciences and Mathematics | Open Access Articles

A Lab-On-Chip Phosphate Analyzer For Long-Term In Situ Monitoring At Fixed Observatories: Optimization And Performance Evaluation In Estuarine And Oligotrophic Coastal Waters, Maxime Grand, Geraldine Clinton-Bailey, Alexander Beaton, Allison Schaap, Thomas Johengen, Mario Tamburri, Douglas Connelly, Matthew Mowlem, Eric Achterberg

Faculty Publications

The development of phosphate sensors suitable for long-term in situdeployments in natural waters, is essential to improve our understanding of the distribution, fluxes, and biogeochemical role of this key nutrient in a changing ocean. Here, we describe the optimization of the molybdenum blue method for in situ work using a lab-on-chip (LOC) analyzer and evaluate its performance in the laboratory and at two contrasting field sites. The in situ performance of the LOC sensor is evaluated using hourly time-series data from a 56-day trial in Southampton Water (UK), as well as a month-long deployment in the subtropical oligotrophic waters of …

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Alongcoast Structure And Interannual Variability Of Seasonal Midshelf Water Properties And Velocity In The Northern California Current System, B. Hickey, S. Geier, N. Kachel, S. Ramp, P. Kosro, Thomas Connolly

Faculty Publications

Moored sensors were maintained for ∼5 years on the northern California Current System (CCS) midshelf. The alongcoast sensor array spanned the area of influence of the plume from the Columbia River, several submarine canyons, as well as a coastal promontory where the equatorward coastal jet frequently separates from the shelf. Upwelling-favorable wind stress magnitude decreases poleward by more than a factor of three over the latitudinal range and shelf width varies by a factor of two. In spite of the alongcoast structure in setting, both seasonal and interannual patterns in subsurface layer water properties were remarkably similar at all sites. …

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Dust Deposition In The Eastern Indian Ocean: The Ocean Perspective From Antarctica To The Bay Of Bengal, Maxime Grand, Christopher Measures, Mariko Hatta, William Hiscock, Clifton Buck, William Landing

Faculty Publications

Atmospheric deposition is an important but still poorly constrained source of trace micronutrients to the open ocean because of the dearth of in situ measurements of total deposition (i.e., wet + dry deposition) in remote regions. In this work, we discuss the upper ocean distribution of dissolved Fe and Al in the eastern Indian Ocean along a 95°E meridional transect spanning the Antarctic margin to the Bay of Bengal. We use the mixed layer concentration of dissolved Al in conjunction with empirical data in a simple steady state model to produce 75 estimates of total dust deposition that we compare …

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Dissolved Fe And Al In The Upper 1000 M Of The Eastern Indian Ocean: A High‐Resolution Transect Along 95°E From The Antarctic Margin To The Bay Of Bengal, Maxime Grand, Christopher Measures, Mariko Hatta, William Hiscock, William Landing, Peter Morton, Clifton Buck, Pamela Barrett, Joseph Resing

Faculty Publications

A high‐resolution section of dissolved iron (dFe) and aluminum (dAl) was obtained along ~95°E in the upper 1000 m of the eastern Indian Ocean from the Antarctic margin (66°S) to the Bay of Bengal (18°N) during the U.S. Climate Variability and Predictability (CLIVAR) CO2 Repeat Hydrography I08S and I09N sections (February–April 2007). In the Southern Ocean, low concentrations of dAl (<1 n M) reflect the negligible dust inputs impacting the water masses subducted in the circumpolar domain. The low dAl concentrations characterizing the Southern Ocean terminate near 45°S, probably because of the advection of subtropical water masses that received dust and sedimentary inputs in their formation region. Our subsurface dFe data near the southern Kerguelen Plateau were significantly higher than historical observations in other Indian sectors of the Southern Ocean. We surmise that the offshore advection of dFe‐rich waters along the western flank of the southern Kerguelen plateau and enhanced vertical mixing could contribute to this elevated subsurface dFe inventory. Elevated subsurface particulate and dFe levels downstream of the northern Kerguelen Plateau may reflect long‐range lateral transport from the plateau's sediments and/or remineralization inputs. At the northern edge of the south Indian subtropical gyre, the deposition of Australian dust, possibly combined with the advection of dAl‐enriched waters from the Indonesian Throughflow, creates a region of elevated dAl in the upper 400 m but without a corresponding enrichment in dFe. In the northern Indian Ocean, the South Equatorial Current constitutes a remarkable biogeochemical front separating the oxygen‐rich and dFe‐poor subtropical gyre waters from the dFe‐rich and oxygen‐depleted waters of the northern Indian Ocean. By tracing the accumulation of macronutrients and dFe along the advective pathway of Indian Central Water, we show that the central waters of the northern Indian Ocean receive excess dFe in addition to that produced by remineralization inputs. The resuspension of shelf sediments and release of pore waters probably contribute to the elevated dFe and dAl levels observed below the highly stratified upper layers of the Bay of Bengal.

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Quantifying The Impact Of Atmospheric Deposition On The Biogeochemistry Of Fe And Al In The Upper Ocean: A Decade Of Collaboration With The Us Clivar-Co2 Repeat Hydrography Program, Maxime Grand, Clifton Buck, William Landing, Christopher Measures, Mariko Hatta, William Hiscock, Matthew Brown, Joseph Resing

Faculty Publications

The aerosol deposition of continental material and its partial dissolution in the surface ocean exerts an important control on the distribution of iron and other potentially limiting trace metal (TM) micronutrients in the open ocean. This dust deposition has implications for the regulation of global climate through the coupling of biolimiting TM cycles, marine productivity, and the global carbon cycle. Thus, it is important to determine the locations of dust deposition in the open ocean and to quantify the magnitude and subsequent dissolution of the dust. At present, there are too few dust deposition estimates and solubility measurements in the …

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Bioactive Trace Metal Distributions And Biogeochemical Controls In The Southern Ocean, Christopher Measures, Mariko Hatta, Maxime Grand

Faculty Publications

Extensive sampling in many regions of the Southern Ocean has demonstrated that surface water concentrations of dissolved Fe are low enough to limit phytoplankton growth. In contrast, there is currently no evidence that other bioactive elements (e.g., Mn, Zn, Co) are similarly limiting. Although atmospheric input of dissolved Fe to Southern Ocean surface waters appears to be low, resuspension of sediments from shallow regions around islands and the Antarctic coastline can inject significant amounts of Fe into the surrounding waters, stimulating primary production and providing a natural laboratory for studying the response of biological systems to natural Fe fertilization processes. …

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Faculty Publications

Alongcoast Structure And Interannual Variability Of Seasonal Midshelf Water Properties And Velocity In The Northern California Current System, B. Hickey, S. Geier, N. Kachel, S. Ramp, P. Kosro, Thomas Connolly

Faculty Publications

Dust Deposition In The Eastern Indian Ocean: The Ocean Perspective From Antarctica To The Bay Of Bengal, Maxime Grand, Christopher Measures, Mariko Hatta, William Hiscock, Clifton Buck, William Landing

Faculty Publications

Dissolved Fe And Al In The Upper 1000 M Of The Eastern Indian Ocean: A High‐Resolution Transect Along 95°E From The Antarctic Margin To The Bay Of Bengal, Maxime Grand, Christopher Measures, Mariko Hatta, William Hiscock, William Landing, Peter Morton, Clifton Buck, Pamela Barrett, Joseph Resing

Faculty Publications

Faculty Publications

Bioactive Trace Metal Distributions And Biogeochemical Controls In The Southern Ocean, Christopher Measures, Mariko Hatta, Maxime Grand

Faculty Publications