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Unexpected Synthesis Of 1,3,5-Triarly-1,5-Diketones From Aryl Ketones Via Di-Enamine Mechanism, Bin Liu, Junfeng Wang, Yi Pang, Zemei Ge, Runtao Li
Unexpected Synthesis Of 1,3,5-Triarly-1,5-Diketones From Aryl Ketones Via Di-Enamine Mechanism, Bin Liu, Junfeng Wang, Yi Pang, Zemei Ge, Runtao Li
Yi Pang
An unexpected reaction of aryl ketone with acetohydrazone of aromatic aldehyde via 1,2-di-enamine/diiminium mechanism was discovered, leading to efficient synthesis of 1,3,5-triaryl-1,5-diketones in good to excellent yields. (C) 2014 Elsevier Ltd. All rights reserved.