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Materials Chemistry

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Binding Enhancement Factor

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Iron Oxide Nanomagnets In Polymer Matrices – Synthesis And Characterization, Shenjie Qiu Sep 2018

Iron Oxide Nanomagnets In Polymer Matrices – Synthesis And Characterization, Shenjie Qiu

Dissertations, Theses, and Capstone Projects

Magneto-responsive polymer-iron oxide materials have been fabricated by coating various polymers on iron oxide nanoparticles (NPs). The stability of magneto-responsive polymer-iron oxide materials relies on the selection of appropriate coating anchors, such as catechols and silanes. This dissertation describes two robust polymer coating systems on iron oxide NPs. One system focuses on thermo-responsive nitrated catechol-N-isopropylacrylamide polymers with binding enhancement factors (EnF) of ~40 and ~20 towards iron oxide NPs and a boronic acid compared to the polymers without the nitro group. The second system involves coating of poly(vinyl alcohol) (PVA) on iron oxide NPs via a silane anchor …