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Full-Text Articles in Physical Sciences and Mathematics

From Waste To Energy: The Electrochemical Reduction Of Co2 Using Recycled Nanostructured Catalysts, Ibrahim Badawy Jul 2023

From Waste To Energy: The Electrochemical Reduction Of Co2 Using Recycled Nanostructured Catalysts, Ibrahim Badawy

Theses and Dissertations

The reduction of carbon dioxide (CO2RR) using electrochemistry is a promising solution for the burgeoning global energy crisis. The overall vision of its implementation relies on renewable energy sources to power the reaction creating carbon neutral products and effectively closing the carbon cycle. Research in this field has come a long way since its inception in the mid-1900s. However, there remain significant hurdles and important considerations to overcome in order to reach full commercialization. Most electrocatalysts tested for CO2RR have been designed solely for maximum performance while ignoring the environmental consequences if such a material were …


Carbon Dioxide Capture Potential Of Chitosan-Nanocrystalline Cellulose Aerogel Composite Materials: Synthesis, Functionalization, And Characterization, Victor Oghenekohwo Jan 2023

Carbon Dioxide Capture Potential Of Chitosan-Nanocrystalline Cellulose Aerogel Composite Materials: Synthesis, Functionalization, And Characterization, Victor Oghenekohwo

Theses and Dissertations

The carbon dioxide capture technology has been established as an invaluable player in the current global efforts to allay the warming of the planet and climate change. In this connection, the study centers on the valorization of waste organic materials for the application described herein. The sorbents, sourced from a combination of by-products of food processing and agricultural residue waste products, viz. seafood waste and sugarcane bagasse, showed prospects for selective carbon dioxide capture, adsorbing up to 5.78 mg/g of the gas at 273 K and 2.82 mg/g at 298 K, as observed on the Micromeritic ASAP 2020 surface area …


Atomistic Simulation Of Na+ And Cl- Ions Binding Mechanisms To Tobermorite 14Å As A Model For Alkali Activated Cements, Ahmed Abdelkawy Jan 2022

Atomistic Simulation Of Na+ And Cl- Ions Binding Mechanisms To Tobermorite 14Å As A Model For Alkali Activated Cements, Ahmed Abdelkawy

Theses and Dissertations

The production of ordinary Portland cement (OPC) is responsible for ~8% of all man-made CO2 emissions. Unfortunately, due to the continuous increase in the number of construction projects, and since virtually all projects depend on hardened cement from the hydration of OPC as the main binding material, the production of OPC is not expected to decrease. Alkali-activated cement produced from the alkaline activation of byproducts of industries, such as iron and coal industries, or processed clays represents a potential substitute for OPC. However, the interaction of the reaction products of AAC with corrosive ions from the environment, such as Cl-, …


Design And Fabrication Of Nanostructured Electrodes For Complementary Electrochemical And Photoelectrochemical Water Splitting, Kholoud El Sayed Abousalem Jan 2022

Design And Fabrication Of Nanostructured Electrodes For Complementary Electrochemical And Photoelectrochemical Water Splitting, Kholoud El Sayed Abousalem

Theses and Dissertations

Designing highly active, durable, and nonprecious electrodes for overall water splitting is of urgent scientific importance to realize sustainable hydrogen production. Accordingly, the need to search efficient energy production systems is of crucial necessity. In this thesis, two various systems for sustainable hydrogen production have been reported using electrochemical and photoelectrochemical pathways. In the first part of the thesis, electrochemical water splitting involving both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) has been established. To this end, an innovative approach is demonstrated to synthesize flower-like 3D homogenous trimetallic Mn, Ni, Co phosphide catalysts directly on nickel foam via …


Transition Metal Phosphides For High Performance Electrochemical Energy Storage Devices, Amina Saleh Jan 2022

Transition Metal Phosphides For High Performance Electrochemical Energy Storage Devices, Amina Saleh

Theses and Dissertations

Electrochemical energy storage technologies are nowadays playing a leading role in the global effort to address the energy challenges. A lot of attention has been devoted to designing hybrid devices known as supercapatteries which combine the merits of supercapacitors (high power density) and rechargeable batteries (high energy density). Transition metal phosphides (TMP) are a rising star for supercapattery anode materials thanks to their high conductivity, metalloid characteristics, and kinetic favorability for fast electron transport. Herein, new TMP-based materials were synthesized for use as supercapattery positive electrodes, via a multifaceted approach to yield devices enjoying concurrently high power and energy densities. …


Fullerene And Tungsten Oxide Nanostructures-Based Electrocatalysts For All-Vanadium Redox Flow Batteries, Farah Ahmed El Diwany Jun 2021

Fullerene And Tungsten Oxide Nanostructures-Based Electrocatalysts For All-Vanadium Redox Flow Batteries, Farah Ahmed El Diwany

Theses and Dissertations

The vanadium redox flow battery (VRFB) is one of the most promising long-term energy storage solutions mainly due to its long service life and the independence of its energy capacity on power rating and vice versa. However, its relatively high capital cost limits its widespread deployment. Economic analysis reveals that a high-power density VRFB with decreased cell stack size can dramatically reduce the cost. The energy efficiency of a VRFB primarily depends on the kinetics of vanadium redox reactions that take place in the stack. Therefore, studying the effect of surface chemistry of electrodes on the kinetics of each …


Experimental And Computational Design Of Nanostructured Materials For High Performance Supercapacitor Devices, Basant A. Ali Feb 2021

Experimental And Computational Design Of Nanostructured Materials For High Performance Supercapacitor Devices, Basant A. Ali

Theses and Dissertations

Both energy conversion and storage technologies need to be developed hand-to-hand simultaneously to overcome the energy crises. To this end, supercapacitors (SCs) have the potential to be the energy storage platform due to their fast charging capability and long cycling stability. However, their low energy is the bottleneck towards their wide implementation compared to batteries. Also, current research is based on guess and check methods to modify electrode materials with limited properties prediction. In this thesis, density functional theory (DFT) has been employed as a tool to identify potential SC electrode materials. Then, the gained knowledge was used to develop …


Nanoengineered Materials For Energy Conversion & Storage Applications: A Density Functional Theory Study, Ahmed Biby Jan 2021

Nanoengineered Materials For Energy Conversion & Storage Applications: A Density Functional Theory Study, Ahmed Biby

Theses and Dissertations

The conventional approach for the development of novel materials has become long relative to the desired product development cycle. Thus, the sluggish pace of the development of materials within the conventional approach hinders the rapid transformation of the scientific outcomes into useful technological products. To this end, the field of hierarchical materials informatics evolved to bridge this gap. In this field, the multiscale material internal structure is considered the starting point and the core of this approach. This being said, the density functional theory (DFT) was used to generate useful materials data for the advancement of the hierarchical materials data-bases …


Investigation Of Auni5 Films Deposited By Laser Ablation For Rf Mems Switches, Noha Sameh Ahmed Farghal Feb 2007

Investigation Of Auni5 Films Deposited By Laser Ablation For Rf Mems Switches, Noha Sameh Ahmed Farghal

Archived Theses and Dissertations

No abstract provided.


Properties And Structure Of Some Chalcogenide Glasses, Amin Ismail Amin Abdel-Latif Jan 1968

Properties And Structure Of Some Chalcogenide Glasses, Amin Ismail Amin Abdel-Latif

Archived Theses and Dissertations

No abstract provided.


Active Magnesium Oxide Prepared From Magnesium Oxalate Dihydrate, Jehane Nour El Dine Ragai Jan 1968

Active Magnesium Oxide Prepared From Magnesium Oxalate Dihydrate, Jehane Nour El Dine Ragai

Archived Theses and Dissertations

No abstract provided.


The Electrical Resistivity Of Different Types Of Glasses, Fadel Youssef Iskandar Assabghy Jan 1966

The Electrical Resistivity Of Different Types Of Glasses, Fadel Youssef Iskandar Assabghy

Archived Theses and Dissertations

No abstract provided.


Some Properties Of Cerium Borate And Phosphate Glasses In Relation To Structure, M Osama El-Bayoumi Jan 1966

Some Properties Of Cerium Borate And Phosphate Glasses In Relation To Structure, M Osama El-Bayoumi

Archived Theses and Dissertations

No abstract provided.


A Study Of Some Properties Of As2S3 Glass And The Test Of A New Theory Of Glass Formation, Edward Nashed Bolous Jan 1966

A Study Of Some Properties Of As2S3 Glass And The Test Of A New Theory Of Glass Formation, Edward Nashed Bolous

Archived Theses and Dissertations

No abstract provided.