Physical Sciences and Mathematics Commons^™

Towards Sociobiogeochemistry: Critical Perspectives On Anthropogenic Alterations To Soil Nitrogen Chemistry Via U.S. Urban And Suburban Development, Christopher D. Ryan

Dissertations, Theses, and Capstone Projects

The ecological impacts of changes to land use are relevant to concerns about climate change, eutrophication of waterbodies, and reductions in biodiversity. As a foundational component of ecosystem functioning, changes to soil biogeochemistry have significant effects on overall ecosystem health. With cities continuing to grow and develop in extent, the impacts of urbanization and suburbanization on soils are of particular concern. Despite a wide range of natural climatic and geologic conditions, several factors have driven similar patterns of land transformation and management across the United States. In particular, federal initiatives including the Home Owners Loan Corporation, the Federal Housing Administration, …

Short-Term Versus Long-Term Effects Of Nitrogen Addition And Warming On Ecosystem N Dynamics In A Grass-Dominated Temperate Old Field, Benjamin F. A. Souriol

Electronic Thesis and Dissertation Repository

Increased atmospheric nitrogen (N) deposition and climate warming are both anticipated to influence the ecosystem N dynamics of northern temperate ecosystems substantially over the next century. Nevertheless, in field experiments with N addition and warming treatments, temporal scale can play an important role in determining the extent of treatment effects on N dynamics, and it is unclear to what extent the results of short-term studies can be extrapolated to responses over longer time scales. I compared the short-term versus long-term effects of N addition and warming on net N mineralization, N leaching, and N retention in a grass-dominated old field. …

Investigating The Role Of Plant Traits And Interactions In Emergent Wetland Nutrient Removal, Andrew Ryan Sample

Theses and Dissertations

Increasing wetland restoration in the Lower Mississippi Alluvial Valley has been identified as a method to reduce nutrient loading in the Gulf of Mexico. Wetlands have historically been used to treat water through processes facilitated by wetland plants, and relatively few species and plant traits have been identified as important in carrying out these processes. This study focuses on some of those species and traits and aims to identify species differences and plant traits that may be important for wetland nutrient mitigation. Chapter I provides background information on nutrient pollution, wetland biogeochemical mechanisms for nutrient sequestration, and the focal species …

Nutrient Dynamics Of Freshwater Estuarine Sediments Disturbed By Dredging, Ryan Allan John Roekle

Theses and Dissertations

This study examined the nutrient environment of sediments in the Milwaukee River estuary and the dynamics of those nutrients during simulated disturbance experiments within the context of large-scale dredging remediation. Surface sediments were collected from throughout the Milwaukee estuary (including river, harbor, and nearshore stations) by PONAR, centrifuged to separate porewater (interstitial water) from solid material, and filtered to further isolate and stabilize dissolved material. Porewaters were analyzed for dissolved nutrients including ammoniacal nitrogen (AN), nitrate, nitrite, and soluble reactive phosphorus (SRP). Surface sediment porewaters within the estuary were often highly enriched in AN and SRP, which were often 10-2000x …

Diagnosing Excess Nitrogen In Rice Using Post-Season Tissue Samples, Kyle Hoegenauer

Graduate Theses and Dissertations

Proper nitrogen (N) management in rice production can be difficult to achieve without the aid of tools such as soil and tissue tests. There are no tests currently available to rice producers that determine whether N has been managed properly throughout the season or that detect instances of over fertilization. Rice stalk samples were collected from N response trials within 3 days of harvest from the primary Arkansas rice growing region in 2016-2018. Stalk samples were analyzed for N concentration through a KCl extraction and spectrofluorometric quantification. Samples analyzed with leaf material intact contained statistically different N concentrations than samples …

Assessment Of Nitrogen-Based Fertilizer Transport And Microbial Activities In Sandy Soil Profiles In South Texas, Gladys De La Rosa

Theses and Dissertations

Conventional farming is a common practice in Lower Rio Grande Valley (LRGV) and the application of nitrogen fertilizer is essential for plant growth and support. However, managing the rate of nitrogen that is applied can benefit farmers financially and reduce nitrate leaching that can have an adverse effect on the local environment and aquatic systems, e.g., rivers and estuaries. Sandy soils are more vulnerable to water infiltration due to the large proportion of macropores. This study aims to (i) assess how nitrate from a variety of fertilizers (i.e., synthetic and organic) distributes on the top 60 cm layer of a …

Analysis Of Indianapolis Waterways For Evidence Of Eutrophication And Contamination Induced By Urban Pollution, Kiley Grace Wardwell

Undergraduate Honors Thesis Collection

The focus of my research will be largely focused on the water quality of the White River throughout Indianapolis. I will be testing water samples from five different points along the White River to analyze three of its contents, assessing the differing levels of pollution along different points progressing down the river and through the city. The locations I have chosen to test coincide with water gauge sites along the White River and are as follows: Logan Street in Noblesville, 82nd Street, Broad Ripple Dam, Michigan Road and Raymond Street. The surface water at these five locations will be tested …

Quantifying The Leaching Of Nutrients And Metals In A Pasture Soil As Affected By Excreta Of Ruminants Fed Alternative Diets, Ian Kennedy

Graduate Theses and Dissertations

The leaching of nitrate through the soil profile and into adjacent water systems has been a leading cause of water pollution and results in the loss of a valuable nutrient from animal production systems. Forage-based animal production systems may be improved through manipulation of animal diets that incorporate tannins and total polyphenolic compounds with feed, increasing the amount of nitrogen (N) retained by an animal/decreasing rates of digestion and altering the N-containing compounds that are excreted and deposited onto soil. Incorporating the forage legumes sericea lespedeza (Lespedeza cuneate [Dumont de Courset] G. Don) and lablab (Lablab purpurues L.) into the …

Long Term Nutrient And Chlorophyll A Dynamics Across Long Island Sound And Impacts On Dissolved Oxygen Conditions Within The Western Sound (1991-2019), Sherry Perreira

Dissertations and Theses

Nitrogen overload, eutrophication, and hypoxia have been challenging and persistent water quality problems in Long Island Sound (LIS) over the past decades with major impacts on commercial industries, ecology, and recreational activities in the region. Recognizing these problems, the EPA enforced three phases of the Clean Water Act (CWA) to reduce nitrogen loads in an effort to improve this important estuary. This study examines how nitrogen (NH₃, NO_x & TDN), chlorophyll a (CHLA), and dissolved oxygen (DO) concentrations changed in LIS over the past 30 years, in response to water quality regulations as well as changes in …

Nitrogen Dynamics And Transport Along Flowpaths In A Rural Wetland-Stream Complex, Colton Kyro

Graduate Student Theses, Dissertations, & Professional Papers

Human activities have doubled the rate of nitrogen inputs onto the landscape resulting in elevated nitrogen concentrations in our streams. Anthropogenically applied nitrogen is largely transported to stream networks via groundwater movement. Groundwater discharge occurs in distinct points along a stream but whose influences can often persist far beyond that area due to insufficient biogeochemical removal of imported nitrogen potentially causing alterations in community structure and precipitating large algae blooms. To understand the factors governing nitrogen abundance in a historical polluted stream, I used a mass-balance approach to quantify groundwater-surface water interaction and the magnitude of groundwater nitrogen input and …

In The Margins: Reconsidering The Range And Contribution Of Diazotrophs In Nearshore Environments, Corday R. Selden

OES Theses and Dissertations

Dinitrogen (N₂) fixation enables primary production and, consequently, carbon dioxide drawdown in nitrogen (N) limited marine systems, exerting a powerful influence over the coupled carbon and N cycles. Our understanding of the environmental factors regulating its distribution and magnitude are largely based on the range and sensitivity of one genus, Trichodesmium. However, recent work suggests that the niche preferences of distinct diazotrophic (N₂ fixing) clades differ due to their metabolic and ecological diversity, hampering efforts to close the N budget and model N₂ fixation accurately. Here, I explore the range of N₂ fixation …

Spatial And Temporal Variation Of Nutrients In The Great Lakes-St. Lawrence Basin: Implications For Primary Production In Stream Ecosystems, Nolan Pearce

Electronic Thesis and Dissertation Repository

Growing human populations and associated land use activities has increased the amount of nutrients delivered to surface waters. Eutrophication from the over-enrichment of nitrogen and phosphorus has degraded ecosystem conditions in streams, lakes, and coastal areas worldwide. Thus, the management of anthropogenic nutrient loading is a global concern. This thesis employed a combination of field and experimental research to provide watershed managers with information on the spatial and temporal patterns in stream nutrient enrichment, and the associated ecological effects of anthropogenic nutrient loading in the Great Lakes-St. Lawrence basin. Four studies were completed to address this research goal. First, I …

In Situ Plant Uptake Of Excess Nutrients And Consequential Alteration Of Rhizosphere Dynamics, Srusti Maddala

Crop, Soil and Environmental Sciences Undergraduate Honors Theses

The use of phytoremediation in ecological remediation projects has numerous benefits including soil stabilization and nutrient uptake. Recently, microdialysis, a diffusion-based sampling technique commonly used in biomedical research, has been recognized as a candidate for monitoring chemical changes in the rhizosphere. The real-time, in situ data it provides about nutrient diffusion may improve the management and success of restoration projects. Therefore, the objective of this study was to employ the technique of microdialysis in the novel application of quantifying the diffusive flux of inorganic nitrogen compounds in the rhizosphere of native plants of Arkansas. The microdialysis technique was first optimized …

The Environmental Microbiome In A Changing World: Microbial Processes And Biogeochemistry, Stephanie Juice

Graduate College Dissertations and Theses

Climate change can alter ecosystem processes and organismal phenology through both long-term, gradual changes and alteration of disturbance regimes. Because microbes mediate decomposition, and therefore the initial stages of nutrient cycling, soil biogeochemical responses to climate change will be driven by microbial responses to changes in temperature, precipitation, and pulsed climatic events. Improving projections of soil ecological and biogeochemical responses to climate change effects therefore requires greater knowledge of microbial contributions to decomposition. This dissertation examines soil microbial and biogeochemical responses to the long-term and punctuated effects of climate change, as well as improvement to decomposition models following addition of …

Viability Of Wetland Crops For Use In Treatment Wetlands: Nitrogen Removal From Water And Production Of Food, Andrew Denson Corder

Theses and Dissertations

Treatment wetlands are used to treat wastewater from a variety of sources, but their functionality depends on the macrophytes present therein. To better understand the viability of wetland macrophytes both as sources of food and as agents of nitrogen removal from wastewater, this study quantified plant growth, food production, and nitrogen removal capacity of three common wetland crops as well as three locally dominant graminoid species in a variety of relevant ecological contexts. All six plant species and a control were grown over a ten-week period in three related experiments: (1) under three moisture regimes, (2) with or without competition …

Strategies To Improve Forage Utilization By Sheep Offered Forage Mixtures, Valens Niyigena

Graduate Theses and Dissertations

In the first experiment, alfalfa and novel endophyte-infected tall fescue (NE+) forages were harvested after a killing frost, then mixed to formulate 4 different treatments; alfalfa alone, 67% alfalfa +33% fescue, 33% alfalfa + 67% fescue, or 100% fescue. After 3 months of storage as silage, Dorper ewe lambs (n = 20; mean BW = 34.7 ± 6.65 kg) were fed silage for ad libitum consumption, using 5 animals per treatment. Increasing the proportion of NE+ tall fescue improved (P < 0.05) silage total acids and lactic acid concentrations and decreased silage ammonia concentration. Digestible dry matter and organic matter intake and nitrogen utilization parameters decreased with increasing inclusion of NE+ in diet. In the second experiment, 16 Dorper ewe lambs (41.8 ± 4.61 kg BW) were assigned to 4 different treatments; alfalfa silage alone (0 g/kg; CONT) or alfalfa silage mixed with chopped sericea lespedeza (SL) hay to provide 90 (LOW), 180 (MED), or 270 g/kg SL (HIGH) on a dry matter basis in a randomized complete block design experiment with 2 period to provide 4 observations per treatment for each experimental period. Increasing the proportion of sericea lespedeza in the diet decreased dry matter and organic matter digestibility but did not affect feed intake. Fecal nitrogen (g/kg N intake) increased linearly (P < 0.01) while urinary N (g/ day and g/ kg of N intake) tended to decreased linearly and quadratically (P ≤ 0.1) with increasing the proportion of SL in diet. In the third experiments, 16 gestating Dorper ewe lambs (49.1 ± 4.61 kg BW) were allocated to 4 treatments; alfalfa silage alone (0% g/kg; CONT) or alfalfa silage mixed with lablab purpureus(LP) hay to provide 90 (LOW), 180 (MED), or 270 g/kg LP (HIGH) on a dry matter (DM) basis, in a randomized complete block design experiment with a total 8 replication per treatment. Supplementation of LP in diet increased quadratically (P ≤ 0.04) forage dry matter, organic matter intake, digestible dry matter and digestible organic matter intake (P < 0.05). Nitrogen apparently absorbed and urinary N both decreased linearly (P < 0.01) with adding more LP hay in diet. Harvesting and mixing alfalfa and fescue after a killing frost improved silage fermentation characteristics and supplementation of tannins from SL and polyphenol from LP altered N excretion.

Key words: lablab, sericea lespedeza, alfalfa silage, nitrogen, sheep.

Evaluation Of Soybean Maturity Group And Planting Date In A Soybean-Rice Rotation On Overall Crop Productivity, Carrie Ortel

Graduate Theses and Dissertations

Little is known about the effects of soybean (Glycine max L.) management techniques on soil-nitrogen (N) credit development and its impact on the subsequent rice (Oryza sativa L.) crop’s success. This study was conducted to determine how soybean maturity group (MG) and planting date effect overall soybean productivity and its influence on the following rice crop. Various soybean planting dates (optimum and late) and MGs (3.5, 4.7, 5.4, and 5.6) were grown and followed in rotation with a rice crop. Six rates of pre-flood fertilizer-N (0, 44, 89, 134, 179, 224 kg N ha-1) were applied to the rice crop. …

Ulva Spp. Bloom Dynamics In A Hyper-Eutrophic Estuary: Jamaica Bay, New York, Annesia Lamb

Dissertations, Theses, and Capstone Projects

In this dissertation, I present three studies that further our understanding of macroalgae identity, growth, and proliferation. Eutrophication is prevalent in shallow coastal ecosystems world-wide. One of the ecosystem consequences is the development of a bloom forming green marine macroalgae, Ulva spp. Ulva can have negative effects such as Zostera spp. degradation, fish, and shellfish declines. I performed assessments of (1) identity of the bloom-forming Ulva and other macroalgae assemblage, (2) physical, chemical, and biological drivers of Ulva bloom growth and proliferation, and (3) optimal irradiance and temperature requirements for early growth stages in Ulva linza.

The first study …

Effects Of Enhanced Efficiency Nitrogen Fertilizers On Agronomic Parameters And Loss Pathways In The Subtropical Mississippi Delta Region, Scott Michael Pensky

LSU Master's Theses

Minimizing nitrogen (N) loss is critical for improving N use efficiency (NUE) in crop production and reducing its effects on the environment. Management practices such as seasonal application timing of N fertilizers and the addition of enhanced efficiency N fertilizers (EENFs) were investigated for the high N requirement of the two most common cereal crops globally, corn (Zea mays L.) and wheat (Triticum aestivum L.), in the subtropical climate of Louisiana. Field research was established during the 2016 and 2017 seasons at the LSU Agricultural Center’s Dean Lee and Central research stations to examine the effect of different EENFs and …

Evaluation Of Controlled-Release Nitrogen And Potassium Fertilizer In Louisiana Sugarcane Production, Samuel Kwakye

LSU Master's Theses

Sugarcane (Saccharum spp) production is an integral part of Louisiana's economy. Proper fertilizer management, particularly nitrogen (N) and potassium (K), optimizes sugarcane production. An experiment was established in 2015 at the LSU AgCenter Sugar Research Station in St. Gabriel, Louisiana to: (1) assess the effect of N and K fertilizer sources on sugarcane yield and quality parameters, and (2) monitor the changes in inorganic N and K levels in the soil at different sugarcane growth stages. The experiment was arranged in a randomized complete block design on a Sharkey clay soil and complete randomized design on a Commerce …

The Effect Of Preflood Nitrogen And Flood Establishment Timing On Rice Development, Nitrogen Uptake And Grain Yield, Tyler Richmond

Graduate Theses and Dissertations

Urea-N fertilizer is typically applied at the 5-leaf stage to rice (Oryza sativa L.) grown in a dry-seeded, delayed-flood production system. How long the preflood-N can be delayed without adverse effects on yield potential is poorly understood. The research objective was to determine the effects of preflood-N application and flood establishment timing on aboveground-N content, 50% heading, yield components, and grain yield. Trials were established on silt loam soils at the Pine Tree Research Station (PTRS) and Rice Research and Extension Center (RREC) during 2015 and 2016. Urea-N was applied at 0, 45, 90, 135, and 180 kg N ha-1 …

Decomposition Of Black Mangrove (Avicennia Germinans ) Leaf Litter: Calibrating Estuarine Indicators Of Functional Recovery, Leticia Martinez Contreras

Theses and Dissertations

Decomposition of plant material produced by mangroves and other macrophytes in estuaries occurs in both sediments and the water column. Early and intense processing could be more common in the water. In a previous study, in situ decomposition rates of Black Mangrove (Avicennia germinans ) leaf litter suspended in the water column differed among three estuaries in south Texas with moderate differences in salinity, water temperature, available nitrogen (N), and tidal flow. A series of microcosm experiments were conducted to determine the influence, within observed ranges in the estuaries, of these water variables on mass loss of Black Mangrove …

Effects Of Silvopasture Establishment On Aqueous And Gaseous Soil N Losses At The University Of New Hampshire Organic Dairy Research Farm, Kathryn Ann Slebodnik

Honors Theses and Capstones

The expansion of local agriculture in the New England region is putting increased pressure on farmers to expand their arable land base. While clear-cutting is a traditional method of converting forested land to agriculture, it is known for having adverse ecological impacts. To minimize these impacts, farmers can create a silvopasture which incorporates a portion of the original forest canopy into pastures or crop fields. This study evaluates the impact of land-use changes for agriculture on soil nitrogen (N) retention. In particular, this study investigates the differences in soil N turnover, gaseous loss, and aqueous loss among an established forest, …

Residual Effects Of Nitrogen Fertilization On Soil Nitrogen Pools And Corn Growth, Meghan E. Moser

Open Access Theses

Given the dynamic nature of soil nitrogen (N), inorganic N fertilization to corn (Zea mays L.) has potential to alter N pool balance by creating an accumulation or depletion of soil N. Current corn N recommendations in the common corn-soybean rotation of Indiana strive to find the best N rate that maximizes producer profit. Increasing our understanding of soil N will inform producers if they should adjust fertilizer rates for corn to influence maintenance of organic N and Carbon. Our objective was to determine residual N effects from fertilized corn in a corn-soybean rotation by measuring (1) soil N …

Nutrient Runoff And Leachate After Land-Application Of Digestate In A Laboratory Study Using Rainfall Simulations, Min Xiao

Open Access Theses

There has been an increasing number of anaerobic digesters on livestock farms in the United States during the past two decades. Anaerobic digestion of manure allows production of renewable energy and generation of stabilized and nutrient-rich digestate that can be used as organic fertilizer. However, the majority of the existed studies using liquid digestate as fertilizer only focused on the effectiveness for crop yield, nutrient content and microorganism in soil. There is insufficient understanding in the environmental impact of digestate land-application. This laboratory study used six treatments including four different liquid digestate treatments, a chemical fertilizer treatment, and an unfertilized …

Available Nitrogen And Denitrification In Soil Altered By Ground Cover And Nutrient Source In An Organic Apple Orchard, Jade Nicole Ford

Graduate Theses and Dissertations

A shift in public demand towards more organic and locally produced fruit and vegetables has been occurring across the United States in recent years. A common practice in organic fruit production is the application of organic ground covers to supply nutrients while enhancing other soil properties. A need for research exists in the southern region of the U.S. examining the effects of regionally applicable ground cover and nutrient management on nitrogen availability and the microbial community to provide information to organic farmers in the region. Two studies were conducted to determine how 12 treatment combinations of four ground covers (compost, …

A Bat-Guano-Derived Δ15N And Δ13C Record Of Paleoenvironmental Change: Zidită Cave, Romania, Daniel Martin Cleary

USF Tampa Graduate Theses and Dissertations

Because nitrogen isotopes are fractionated along the soil-plant-insect-bat-guano pathway, it may be possible to reconstruct environmental and climatic changes reflected in the nitrogen isotopic composition of guano. A 1.5-m core of bat guano from Zidită Cave (western Romania) provides a record of climatic and anthropogenic influence on the regional nitrogen cycle and paleoenvironmental controls on nitrogen transforming processes. Increasing and decreasing trends of nitrogen isotopic composition (δ¹⁵N values) correspond well with changes in the influence of farming practices, deforestation, and forest expansion. These influences likely had a significant effect on the openness of the nitrogen cycle, resulting in …

Evidence Of Late Quaternary Fires From Charcoal And Siliceous Aggregates In Lake Sediments In The Eastern U.S.A., Joanne P. Ballard

Doctoral Dissertations

The late-glacial transition to the Holocene, 15,000–11,600 cal yr BP, is an enigmatic period of dynamic global changes and a major extinction event in North America. Fire is an agent of disturbance that transforms the environment physically and chemically, and affects plant community composition. To improve understanding of the linkages between fire, vegetation, and climate over the late glacial and Holocene in the eastern U.S., I analyzed lake-sediment cores for charcoal and indicators of wood ash, and compared results to existing pollen records. A new microscopic charcoal record from Anderson Pond, Tennessee revealed high fire activity from 23,000–15,000 cal yr …

Rice Grain Yield And Nitrogen Uptake And Ammonia Volatilization From Urea As Affected By Urea Amendment And Simulated Rainfall, Randy Dempsey

Graduate Theses and Dissertations

The effect of rainfall between urea application and flood establishment on N loss and grain yield of rice (Oryza sativa L.) has not been studied. The first research objective was to compare the effects of simulated rainfall amounts and N-(n-butyl) thiophosphoric triamide (NBPT) urease inhibitor rate on NH3 volatilization and rice growth. Three field experiments were conducted and NH3 volatilization was measured in two experiments for 11 days after urea application (DAU) in semi-open chambers. Urea or NBPT-treated urea (NBPT-Urea) was subjected to six simulated rainfall amounts (0-25 mm) applied 5 to 15 h after urea application and flooded 7 …

Biogeochemical Cycling In Lake Superior Tributaries: Seasonality, Quantity And Quality Of Export, Ashley Anne Coble

Dissertations, Master's Theses and Master's Reports - Open

Seasonal and spatial variability in environmental factors may affect dissolved organic matter composition and nutrient transformation and retention in streams. The objective of this research was to quantify and describe seasonality, quantity, and quality of nutrient processing and export of ammonium (NH₄), soluble reactive phosphate (SRP), and dissolved organic carbon (DOC) into Lake Superior through intensive study in a small 1st order watershed coupled with snapshot measurements across 12 tributaries that varied in size, location, and wetland coverage. Our results suggest biodegradable C is exported from a small headwater stream year-round and that DOC mineralization rates can be …