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Full-Text Articles in Physical Sciences and Mathematics

Measurements Of Trace Gas Emissions From Australian Forest Fires And Correlations With Coincident Measurements Of Aerosol Optical Depth, Clare Paton-Walsh, N. B. Jones, Stephen R. Wilson, V Haverd, A. Meier, D. W. Griffith Dec 2005

Measurements Of Trace Gas Emissions From Australian Forest Fires And Correlations With Coincident Measurements Of Aerosol Optical Depth, Clare Paton-Walsh, N. B. Jones, Stephen R. Wilson, V Haverd, A. Meier, D. W. Griffith

Faculty of Science - Papers (Archive)

We present vertically integrated measurements of C2H2, C2H4, C2H6, HCOOH, CO, H2CO, HCN and NH3 through smoke plumes from Australian forest fires measured by ground-based solar absorption spectroscopy. The column amounts of these gases are highly correlated with simultaneous, co-located measurements of aerosol optical depth, providing a potential method of mapping biomass-burning emissions using satellite measurements of aerosol optical depth. We have calculated emission ratios relative to CO for the trace gases using aerosol optical depth as a proxy for CO and converted to emission factors by using an average emission factor for CO from literature measurements of extra-tropical forest …


Living With Trees – Perspectives From The Suburbs, Lesley M. Head, Pat Muir Dec 2005

Living With Trees – Perspectives From The Suburbs, Lesley M. Head, Pat Muir

Faculty of Science - Papers (Archive)

A study of suburban backyards and backyarders in Sydney and Wollongong revealed evidence of attitudes and behaviours in relation to trees. Attitudes are characterised under themes that indicate conditions of tolerance and belonging. They include attachment/risk, order/freedom and nativeness/alienness. While love is common, high levels of suspicion and intolerance towards trees in the suburban context are more common. Our findings confirm and throw further light on previous work indicating that many Australians have very partitioned views of the world in relationto where humans and nonhuman lifeforms belong. This partitioning must be understood in conceptual as well as spatial terms.


Regioselective Synthesis Of Novel E-Edge-[60]Fullerenylmethanodihydropyrroles And 1,2-Dihydromethano[60]Fullerenes, Leila Chaker, Graham E. Ball, James R. Williams, Glenn A. Burley, Bill C. Hawkins, Paul A. Keller, Stephen G. Pyne Dec 2005

Regioselective Synthesis Of Novel E-Edge-[60]Fullerenylmethanodihydropyrroles And 1,2-Dihydromethano[60]Fullerenes, Leila Chaker, Graham E. Ball, James R. Williams, Glenn A. Burley, Bill C. Hawkins, Paul A. Keller, Stephen G. Pyne

Faculty of Science - Papers (Archive)

Treatment of a tethered N-(diphenylmethylene)glycinate-malonate derivative with [60]fullerene under Bingel conditions yielded an e-edge-[60]fullerenylmethanodihydropyrrole adduct in a regioselective manner. The regiochemical outcome was independent of the order of addition of either the N-(diphenylmethylene)glycinate or the malonate moieties. This new bis-adduct was also prepared in 13C enriched form allowing for its unequivocal structural characterization by 2D INADEQUATE NMR experiments. Ring-opening of the dihydropyrrole functionality of the bisadducts under reductive conditions gave exclusively novel dihydromethano[60]fullerene derivatives.


Culture As Concept And Influence In Environmental Research And Management, Lesley M. Head, D. Trigger, J. Mulcock Dec 2005

Culture As Concept And Influence In Environmental Research And Management, Lesley M. Head, D. Trigger, J. Mulcock

Faculty of Science - Papers (Archive)

Given that human activities have been implicated in the vast majority of contemporary environmental problems, it might be expected that research effort into those activities and the attitudes from which they stem would be both strongly supported by funding agencies, and of central interest to environmental scientists and land managers. In this paper we focus on an undervalued area of environmental humanities research—cultural analysis of the beliefs, practices and often unarticulated assumptions which underlie human–environmental relations. In discussing how cultural processes are central to environmental attitudes and behaviours, and how qualitative research methods can be used to understand them in …


Evidence Of Reduced Measurement Uncertainties From An Ftir Instrument Intercomparison At Kiruna, Sweden, A. Meier, Clare Paton-Walsh, C. Bell, T. Blumenstock, F. Hase, A. Goldman, A. Steen, R. Kift, P. Woods, Y. Kondo Nov 2005

Evidence Of Reduced Measurement Uncertainties From An Ftir Instrument Intercomparison At Kiruna, Sweden, A. Meier, Clare Paton-Walsh, C. Bell, T. Blumenstock, F. Hase, A. Goldman, A. Steen, R. Kift, P. Woods, Y. Kondo

Faculty of Science - Papers (Archive)

We report the results of an intercomparison of vertical column amounts of HCl, HF, N2O, HNO3, CH4, O3, CO2 and N2 derived from the spectra recorded by two ground-based FTIR spectrometers operated side-by-side using the sun as a source. The procedures used to record spectra and derive vertical column amounts followed the format of previous instrument intercomparisons organised by the Network for Detection of Stratospheric Change (NDSC), but the level of agreement achieved was significantly better than for previous intercomparisons. For most gases the differences were typically 1% or less, with at least one of the five datasets showing no …


Adaptation To Extreme Environments: Macromolecular Dynamics In Complex Systems, M. Tehei Aug 2005

Adaptation To Extreme Environments: Macromolecular Dynamics In Complex Systems, M. Tehei

Faculty of Science - Papers (Archive)

What we previously thought of as insurmountable physical and chemical barriers to life, we now see as yet another niche harbouring Fextremophiles_. Extremophiles and their macromolecules had to develop molecular mechanisms of adaptation to extreme physico–chemical conditions. Using neutron spectroscopy, we have demonstrated that molecular dynamics represents one of these molecular mechanisms of adaptation. To which extent do hyper-saline conditions and extreme temperatures influence molecular dynamics? First, molecular dynamics were analysed for halophilic malate dehydrogenase from Haloarcula marismortui (Hm MalDH) under different molar solvent salt concentration conditions influencing its stability. Secondly, mean macromolecular motions were measured in-vivo in psychrophile (Aquaspirillum …


Is Plasminogen Deployed As A Streptococcus Pyogenes Virulence Factor?, Mark J. Walker, Jason D. Mcarthur, F. Mckay, M. Ranson Jul 2005

Is Plasminogen Deployed As A Streptococcus Pyogenes Virulence Factor?, Mark J. Walker, Jason D. Mcarthur, F. Mckay, M. Ranson

Faculty of Science - Papers (Archive)

Streptococcus pyogenes (group A streptococcus) causes human skin and throat infections as well as highly invasive diseases including necrotising fasciitis. Group A streptococcal infections and invasive disease have made a resurgence in developed countries over the last two decades. S. pyogenes utilise multiple pathways for the acquisition and activation of human plasminogen, securing potent proteolytic activity on the bacterial cell surface. Recent experimental evidence using a humanised transgenic mouse model suggests a critical role for human plasminogen in the dissemination of S. pyogenes in vivo.


Tandem Mass Spectrometry Of Deprotonated Iodothyronines, A. M. Couldwell, M. C. Thomas, Todd Mitchell, A. Hulbert, Stephen J. Blanksby Jun 2005

Tandem Mass Spectrometry Of Deprotonated Iodothyronines, A. M. Couldwell, M. C. Thomas, Todd Mitchell, A. Hulbert, Stephen J. Blanksby

Faculty of Science - Papers (Archive)

In order to assist with the development of more selective and sensitive methods for thyroid hormone analysis the [M-H]– anions of the iodothyronines; T4, T3, rT3, (3,5)-T2 and the non-iodinated thyronine (T0) have been generated by negative ion electrospray mass spectrometry. Tandem mass spectra of these ions were recorded on a triple quadrupole mass spectrometer and show a strong analogy with the fragmentation pathways of the parent compound, tyrosine. All iodothyronines also show significant abundances of the iodide anion in their tandem mass spectra, which represents an attractive target for MRM analysis, given that iodothyronines are the only iodine bearing …


A Comparison Of The Gas Phase Acidities Of Phospholipid Headgroups:Experimental And Computational Studies, M. C. Thomas, Todd Mitchell, Stephen J. Blanksby Feb 2005

A Comparison Of The Gas Phase Acidities Of Phospholipid Headgroups:Experimental And Computational Studies, M. C. Thomas, Todd Mitchell, Stephen J. Blanksby

Faculty of Science - Papers (Archive)

Proton-bound dimers consisting of two glycerophospholipids with different headgroups were prepared using negative ion electrospray ionization and dissociated in a triple quadrupole mass spectrometer. Analysis of the tandem mass spectra of the dimers using the kinetic method provides, for the first time, an order of acidity for the phospholipid classes in the gas phase of PE < PA << PG < PS < PI. Hybrid density functional calculations on model phospholipids were used to predict the absolute deprotonation enthalpies of the phospholipid classes from isodesmic proton transfer reactions with phosphoric acid. The computational data largely support the experimental acidity trend, with the exception of the relative acidity ranking of the two most acidic phospholipid species. Possible causes of the discrepancy between experiment and theory are discussed and the experimental trend is recommended. The sequence of gas phase acidities for the phospholipid headgroups is found to; (i) have little correlation with the relative ionization efficiencies of the phospholipid classes observed in the negative ion electrospray process, and (ii) correlate well with fragmentation trends observed upon collisional activation of phospholipid [M-H]– anions.


Impact Of Changes In Natural Uv Radiation On Pigment Composition, Physiological And Morphological Characteristics Of The Antarctic Moss, Grimmia Antarctici., Sharon A. Robinson, J. D. Turnbull, C. E. Lovelock Feb 2005

Impact Of Changes In Natural Uv Radiation On Pigment Composition, Physiological And Morphological Characteristics Of The Antarctic Moss, Grimmia Antarctici., Sharon A. Robinson, J. D. Turnbull, C. E. Lovelock

Faculty of Science - Papers (Archive)

The impact of ambient UV-B radiation on the endemic bryophyte, Grimmia antarctici, was studied over 14 months in East Antarctica. Over recent decades, Antarctic plants have been exposed to the largest relative increase in UV-B exposure as a result of ozone depletion. We investigated the effect of reduced UV and visible radiation on the pigment concentrations, surface reflectance and physiological and morphological parameters of this moss. Plexiglass screens were used to provide both reduced UV levels (77%) and a 50% decrease in total radiation. The screen combinations were used to separate UV photoprotective from visible photoprotective strategies, since these bryophytes …


R120g Αb-Crystallin Promotes The Unfolding Of Reduced Α-Lactalbumin And Is Inherently Unstable., T. M. Treweek, A. Rekas, R. A. Lindner, Mark J. Walker, J. A. Aquilina, C. V. Robinson, J. Horwitz, M. Der Perng, R. A. Quinlan, J. A. Carver Feb 2005

R120g Αb-Crystallin Promotes The Unfolding Of Reduced Α-Lactalbumin And Is Inherently Unstable., T. M. Treweek, A. Rekas, R. A. Lindner, Mark J. Walker, J. A. Aquilina, C. V. Robinson, J. Horwitz, M. Der Perng, R. A. Quinlan, J. A. Carver

Faculty of Science - Papers (Archive)

α-Crystallin is the principal lens protein which, in addition to its structural role, also acts as a molecular chaperone, to prevent aggregation and precipitation of other lens proteins. One of its two subunits, αB-crystallin, is also expressed in many non-lenticular tissues, and a natural missense mutation, R120G, has been associated with cataract and desminrelated myopathy, a disorder of skeletal muscles (Vicart et al., 1998, Nature Genet. 20:92-95). In the present study, real-time 1H NMR spectroscopy showed that the ability of R120G αB-crystallin to stabilize the partially folded, molten globule state of α- lactalbumin was significantly reduced in comparison with wild …


Environmental Effects Of Ozone Depletion And Its Interactions With Climate Change: Progress Report, 2004, A Andrady, P Aucamp, A Bais, C. Ballare, L Bjorn, J R. Bornman, M Caldwell, T Callaghan, A P. Cullen, D J. Erickson, F R. De Gruijl, D P. Hader, Mohammad Ilyas, G Kulandaivelu, H D. Kumar, J Longstreth, Richard L. Mckenzie, M Norval, H Redhwi, R C. Smith, Keith R. Solomon, B Sulzberger, Y Takizawa, Xiaoyan Tang, A H. Teramura, A Torikai, J C. Van Der Leun, Stephen R. Wilson, R C. Worrest, R. G. Zepp Jan 2005

Environmental Effects Of Ozone Depletion And Its Interactions With Climate Change: Progress Report, 2004, A Andrady, P Aucamp, A Bais, C. Ballare, L Bjorn, J R. Bornman, M Caldwell, T Callaghan, A P. Cullen, D J. Erickson, F R. De Gruijl, D P. Hader, Mohammad Ilyas, G Kulandaivelu, H D. Kumar, J Longstreth, Richard L. Mckenzie, M Norval, H Redhwi, R C. Smith, Keith R. Solomon, B Sulzberger, Y Takizawa, Xiaoyan Tang, A H. Teramura, A Torikai, J C. Van Der Leun, Stephen R. Wilson, R C. Worrest, R. G. Zepp

Faculty of Science - Papers (Archive)

The complexity of the linkages between ozone depletion, UV-B radiation and climate change has become more apparent.


Radiocarbon In Corals From The Cocos (Keeling) Islands And Implications For Indian Ocean Circulation, Q Hua, Colin D. Woodroffe, Scott Smithers, M Barbetti, David Fink Jan 2005

Radiocarbon In Corals From The Cocos (Keeling) Islands And Implications For Indian Ocean Circulation, Q Hua, Colin D. Woodroffe, Scott Smithers, M Barbetti, David Fink

Faculty of Science - Papers (Archive)

Annual bands of a Porites coral from the Cocos (Keeling) Islands, eastern Indian Ocean, were analysed by radiocarbon for 1955–1985 AD. A rapid oceanic response of the site to bomb 14C is found, with a maximum D14C value of 132% in 1975. This value is considerably higher than those for the northwestern Indian Ocean, suggesting that surface waters reaching Cocos are not derived from the Arabian Sea. Instead, D14C values for Cocos and those for Watamu (Kenya) agree well over most of the study interval, suggesting that the South Equatorial Current carries 14C-elevated water rather than 14C-depleted water westward across …


Seasonal Variations Of Co And Hcn In The Troposphere Measured By Solar Absorption Spectroscopy Over Poker Flat, Alaska, Y Kasai, A. Kagawa, Nicholas B. Jones, A. Fujiwara, K. Seki, Y. Murayama, F Murcray Jan 2005

Seasonal Variations Of Co And Hcn In The Troposphere Measured By Solar Absorption Spectroscopy Over Poker Flat, Alaska, Y Kasai, A. Kagawa, Nicholas B. Jones, A. Fujiwara, K. Seki, Y. Murayama, F Murcray

Faculty of Science - Papers (Archive)

Tropospheric partial column abundances of CO and HCN have been retrieved from infrared solar spectra observed with a ground-based spectrometer at Poker Flat Alaska (65°N, 147°W) over the time period from 2000 to 2004. From these data we report the transpacific transport induced inter-annual variability of tropospheric CO over Poker Flat. This is the first report of solar infrared data from the Poker Flat station, where the geographical location of the site means that remote sensing measurements are sampling the transport of transpacific air parcels going to Northern America from Eastern Siberia and Asia. The five year time-span of the …


Rnai-Mediated Knocking-Down Of Rlpk2 Gene Retarded Soybean Leaf Senescence, Xiaoping Li, Yuanyuan Ma, Pengli Li, Liwen Zhang, Yong Wang, Ren Zhang, Ningning Wang Jan 2005

Rnai-Mediated Knocking-Down Of Rlpk2 Gene Retarded Soybean Leaf Senescence, Xiaoping Li, Yuanyuan Ma, Pengli Li, Liwen Zhang, Yong Wang, Ren Zhang, Ningning Wang

Faculty of Science - Papers (Archive)

Leaf senescence that occurs in the last stage of leaf development is a genetically programmed process. It is very significant to elucidate the molecular mechanisms that control the initiation and progression of leaf senescence and the way the senescence signal is transduced. In a previous study on artificially induced soybean leaf senescence, we cloned a novel gene designatedrlpk2 (Genbank Accession No. AY687391) that encodes a leucine-rich repeat (LRR) receptor like protein kinase. The expression level ofrlpk2 gene was shown to be strongly up-regulated during both the natural leaf senescence process in this report and the artificially induced primary-leaf-senescence …


Macrochannels And Their Significance For Flood-Risk Minimisation, West Dapto, New South Wales, E. L. Roper, Ivars Reinfelds, Gerald C. Nanson Jan 2005

Macrochannels And Their Significance For Flood-Risk Minimisation, West Dapto, New South Wales, E. L. Roper, Ivars Reinfelds, Gerald C. Nanson

Faculty of Science - Papers (Archive)

A prominent characteristic of streams draining catchments in West Dapto, New South Wales, are well developed macrochannels that have formed within alluvial terraces in mid-catchment zones. A detailed hydraulic modelling study using HEC-RAS, HEC-GeoRAS and Arcview GIS indicates that these macrochannels are scaled to accommodate high magnitude floods. They offer a significant degree of natural protection from flood events up to and in excess of 100 years recurrence interval, essentially by operating as 'bankfull' channels during such events. Macrochannel landforms can be clearly distinguished and mapped on fine-scale digital elevation models (DEMs) and other GIS data sources such as rectified …


Palaeovolcanic Forcing Of Short-Term Dendroisotopic Depletion: The Effect Of Decreased Solar Intensity On Irish Oak, N. Ogle, Christian Turney, R.M. Kalin, L. O'Donnell, C.J. Butler Jan 2005

Palaeovolcanic Forcing Of Short-Term Dendroisotopic Depletion: The Effect Of Decreased Solar Intensity On Irish Oak, N. Ogle, Christian Turney, R.M. Kalin, L. O'Donnell, C.J. Butler

Faculty of Science - Papers (Archive)

The climatic effects of historical volcanic eruptions are well documented in the literature. What are less certain however, are the effects of eruptions on more distant environments, particularly vegetation. Here we present sub-annual δ13C records from two high-resolution Irish oak (Quercus spp.) chronologies that span the Laki (Grímsvötn) 1783–84 and Tambora 1815 eruptions. In both instances, a significant depletion in δ13C is recorded within the trees following the eruption (∼1.8‰). Historical meteorological datasets from observatories near to the trees sampled demonstrate that the shifts in carbon isotopic content cannot be accounted for by changes in …


Structural Re-Assignment Of The Mono- And Bis-Addition Products From The Addition Reactions Of N-(Diphenylmethylene)Glycinate Esters To [60]Fullerene Under Bingel Conditions, Graham E Ball, Glenn Ashley Burley, Leila Chaker, William Hawkins, James Williams, Paul A. Keller, Stephen G. Pyne Jan 2005

Structural Re-Assignment Of The Mono- And Bis-Addition Products From The Addition Reactions Of N-(Diphenylmethylene)Glycinate Esters To [60]Fullerene Under Bingel Conditions, Graham E Ball, Glenn Ashley Burley, Leila Chaker, William Hawkins, James Williams, Paul A. Keller, Stephen G. Pyne

Faculty of Science - Papers (Archive)

The addition of N-(diphenylmethylene)glycinate esters (Ph2C=NCH2CO2R) to [60]fullerene under Bingel conditions gives [60]fullerenyldihydropyrroles and not methano[60]fullerenyl iminoesters [C60C(CO2R)(N=CPh2)] as previously reported. Unequivocal evidence for the structure of C60C(CO2Et)(N=CPh2) was provided by INADEQUATE NMR studies on 13C enriched material. New mechanistic details are proposed to account for the formation of [60]fullerenyldihydropyrroles and their reductive ring-opening reactions.


Comparisons Between Sciamachy And Ground-Based Ftir Data For Total Columns Of Co, Ch4, Co2 And N2o, B Dils, M De Maziere, T Blumenstock, M Buchwitz, R De Beek, Nicholas B. Jones, David W. Griffith, P Demoulin, A G Frankenberg, H Duchatelet, Hans Fast Jan 2005

Comparisons Between Sciamachy And Ground-Based Ftir Data For Total Columns Of Co, Ch4, Co2 And N2o, B Dils, M De Maziere, T Blumenstock, M Buchwitz, R De Beek, Nicholas B. Jones, David W. Griffith, P Demoulin, A G Frankenberg, H Duchatelet, Hans Fast

Faculty of Science - Papers (Archive)

Total column amounts of CO, CH4, CO2 and N2O retrieved from SCIAMACHY nadir observations in its near-infrared channels have been compared to data from a ground-based quasi-global network of Fourier-transform infrared (FTIR) spectrometers. The SCIAMACHY data considered 5 here have been produced by three different retrieval algorithms, WFM-DOAS (version 0.4, 0.41 for CH4), IMAP-DOAS (version 0.9) and IMLM (version 5.5) and cover the January to December 2003 time period. Comparisons have been made for individual data, as well as for monthly averages. To maximize the number of reliable coincidences that satisfy the temporal and spatial collocation criteria, the 10 SCIAMACHY …


Spatial Ecology Of Slatey-Grey Snakes (Stegonotus Cucullatus, Colubridae) On A Tropical Australian Floodplain, Gregory P. Brown, Richard Shine, Thomas Madsen Jan 2005

Spatial Ecology Of Slatey-Grey Snakes (Stegonotus Cucullatus, Colubridae) On A Tropical Australian Floodplain, Gregory P. Brown, Richard Shine, Thomas Madsen

Faculty of Science - Papers (Archive)

The extent, sequence, synchrony and correlates of diel displacements by animals can provide powerful insights into the ecological and social factors that shape an organism's day-to-day activities, but detailed data on spatial ecology are available for very few tropical taxa. Radiotelemetric monitoring of 25 slatey-grey snakes (Stegonotus cucullatus) on a floodplain in the Australian wet-dry tropics for periods of 40 to 355 d (mean=195 d, 136 locations per snake) provided extensive information on habitat use, movement patterns and home range size of these large slender-bodied colubrids. All radio-tracked animals were nocturnal, sheltering by day in soil cracks and …


Prodromus Of Vertebrate Paleontology And Geochronology Of Bermuda, Storrs L. Olson, David B. Wingate, Paul J. Hearty, Frederick V. Grady Jan 2005

Prodromus Of Vertebrate Paleontology And Geochronology Of Bermuda, Storrs L. Olson, David B. Wingate, Paul J. Hearty, Frederick V. Grady

Faculty of Science - Papers (Archive)

Summary Pleistocene sea-level fluctuations were the primary determinant of geological deposition and biotic evolution on Bermuda. The island is composed of carbonate sand deposited on the eroded summit of a submarine volcano during ele- vated sea-levels of interglacial periods. A few vertebrate remains have been recovered directly from interglacial sandstones, mainly of mid-Pleistocene age. Glacial intervals are marked by red soils derived mainly from atmospheric dust. Vertebrate fossils of glacial age are not preserved at the surface and are known only from caves and fissure fills. Fossil faunas are known on Bermuda from the last two glacial episodes but none …


No Academic Borders?: Transdisciplinarity In University Teaching And Research, Alice W. Russell Jan 2005

No Academic Borders?: Transdisciplinarity In University Teaching And Research, Alice W. Russell

Faculty of Science - Papers (Archive)

Transdisciplinarity has been a veritable mantra, especially in the humanities and social sciences, for twenty years or more. Yet academic structures and research application requirements still struggle to come to grips with crossboundary research and teaching. Making universities more trans-discipline-friendly is a tricky task, however. As Wendy Russell explains, trans-disciplines require disciplines, and disciplinary boundaries, too.


Preliminary Results Of The Eip Project, Robert G. Bednarik, Giriraj Kumar, Alan Watchman, Richard G. Roberts Jan 2005

Preliminary Results Of The Eip Project, Robert G. Bednarik, Giriraj Kumar, Alan Watchman, Richard G. Roberts

Faculty of Science - Papers (Archive)

The primary rationale of the Early Indian Petroglyphs Project is to investigate claims of the occurrence of Lower Palaeolithic petroglyphs in central regions of India. Other purposes of this multifacetted research project are to provide new data for the chronology of the Middle and Late Pleistocene hominin history of India; to introduce scientific methods of rock art dating in this country; and to investigate its Lower Palaeolithic stone tool industries. This project, a collaboration of Indian and Australian researchers, was commenced in 2001. It involves archaeological excavations, a range of analytical studies and intensive field surveys, and it will continue …


Effects Of Javan Rusa Deer (Cervus Timorensis) On Native Plant Species In The Jibbon-Bundeena Area, Royal National Park, New South Wales, David Keith, Belinda Pellow Jan 2005

Effects Of Javan Rusa Deer (Cervus Timorensis) On Native Plant Species In The Jibbon-Bundeena Area, Royal National Park, New South Wales, David Keith, Belinda Pellow

Faculty of Science - Papers (Archive)

A reconnaissance survey and exclosure experiment were carried out to examine the effects of Javan rusa deer on native flora and vegetation in Royal National Park on the southern outskirts of Sydney, Australia. Of 78 native plant species examined during the survey, only nine showed no evidence of vertebrate herbivory or physical damage and the majority of these plants were ferns and sedges. The other 69 species showed effects that included defoliation (young and/or old leaves), removal of shoots, bark-stripping, stem breakages and destruction or consumption of reproductive material. These effects varied in severity between species and from place to …


Combined Effects Of Solar Radiation And Desiccation On The Mortality And Development Of Encapsulated Embryos Of Rocky Shore Gastropods, R. Przeslawski Jan 2005

Combined Effects Of Solar Radiation And Desiccation On The Mortality And Development Of Encapsulated Embryos Of Rocky Shore Gastropods, R. Przeslawski

Faculty of Science - Papers (Archive)

Intertidal encapsulated embryos may be synchronously exposed to many environmental stressors, but interactions between some of these factors remain poorly understood. Here, the effects of solar radiation and desiccation on embryonic mortality and developmental rates were assessed using laboratory and field experiments. Egg masses of 3 intertidal gastropod species were exposed for 72 h to combinations of spectral (full spectrum, UV-blocked, dark) and daily emersion treatments (control, 15, 30, 60 min). Siphonaria denticulata and Bembicium nanum embryos were expected to be tolerant to emersion and UVR as they are routinely deposited on exposed rock platforms. In contrast, Dolabrifera brazieri embryos …


Confirmation Of The Structure Of Oxystemokerrin By Single Crystal X-Ray Structural Analysis And A Proposed Biosynthesis, Pitchaya Mungkornasawakul, Hayden Matthews, Alison T. Ung, Stephen G. Pyne, Araya Jatisatienr, Wilford Lie, Brian W. Skelton, Allan H. White Jan 2005

Confirmation Of The Structure Of Oxystemokerrin By Single Crystal X-Ray Structural Analysis And A Proposed Biosynthesis, Pitchaya Mungkornasawakul, Hayden Matthews, Alison T. Ung, Stephen G. Pyne, Araya Jatisatienr, Wilford Lie, Brian W. Skelton, Allan H. White

Faculty of Science - Papers (Archive)

The crystal structure of the pentacyclic Stemona alkaloid oxystemokerrin (2), isolated from the roots of Stemona kerrii, is reported, confirming the structure proposed for this compound in a contemporaneous spectroscopic study. This compound is a diastereomer of stemocurtisinol (3), whose structure we have recently reported from S. curtisii, also confirmed by a single-crystal X-ray study. These alkaloids have opposite configurations at C-4 and C-19. A possible biosynthetic pathway for the biosynthesis of 2 and 3 is proposed.


Mechanisms Of Climate Variability, Edward A. Bryant Jan 2005

Mechanisms Of Climate Variability, Edward A. Bryant

Faculty of Science - Papers (Archive)

Climatic hazards originate with the processes that move air across the Earth's surface due to differential heating and cooling. Surprisingly, examination of these processes has focused upon heating at the tropics and downplayed the role of cold air masses moving out of polar regions due to deficits in the radiation balance in these latter regions. Fluctuations – in the intensity of pulses of cold air moving out of polar regions or of heating at the equator – and the location of the interaction between these cold and warm air masses, are crucial factors in determining the magnitude, frequency, and location …


Walking With Hobbits: An Insider's View Of The Discovery At Liang Bua, Kira E. Westaway Jan 2005

Walking With Hobbits: An Insider's View Of The Discovery At Liang Bua, Kira E. Westaway

Faculty of Science - Papers (Archive)

Startling archaeological and palaeoanthropological discoveries tend to generate a wealth of responses from different social and professional groups. The recent discovery of a 'hobbit' generated a response from academic institutions, the media and the general public that was unexpected, but at the same time very indicative of how human beings perceive themselves. By reviewing how this find has impacted on these three groups, a mixture of emotions is revealed: disbelief, horror, intrigue and fascination. But can science, especially science in Indonesia, benefit from this period of intense scrutiny and interest brought about by the most important, albeit disputed, find of …


Doing Discourse Analysis, Gordon R. Waitt Jan 2005

Doing Discourse Analysis, Gordon R. Waitt

Faculty of Science - Papers (Archive)

My hope in writing this chapter is to generate enthusiasm for geographical research employing discourse analysis. My intention is to provide some advice on doing discourse analysis to facilitale the design of research. I first outline why some geographers have been inspired by this approach. I suggest how Foucauldian discourse analysis is a break from other critical methods applied to textual analysis, including content analysis, semiology, and iconography. The theoretical underpinnings of the method provided by Michel Foucault, a French poststructuralist philosopher, is a key source of difference. I therefore condense Michel Foucault's contribution to discourse analysis by sketching out …


Catalytic Transesterification Of Beta-Ketoesters With Zeolite H-Fer Under Solvent Free Conditions, Sudhir R. Shengule, K Pasupathy, Subhash P. Chavan, Vikas Shinde, R Anand Jan 2005

Catalytic Transesterification Of Beta-Ketoesters With Zeolite H-Fer Under Solvent Free Conditions, Sudhir R. Shengule, K Pasupathy, Subhash P. Chavan, Vikas Shinde, R Anand

Faculty of Science - Papers (Archive)

Zeolite H-FER catalyzes the transesterification of ??-ketoesters with variety of alcohols under solvent-less condition in excellent yields. The catalyst can be reused without any loss of activity. ?? ARKAT.