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Full-Text Articles in Physical Sciences and Mathematics
Estimated Total Emissions Of Trace Gases From The Canberra Wildfires Of 2003: A New Method Using Satellite Measurements Of Aerosol Optical Depth & The Mozart Chemical Transport Model, Clare Paton-Walsh, L Emmons, Stephen R. Wilson
Estimated Total Emissions Of Trace Gases From The Canberra Wildfires Of 2003: A New Method Using Satellite Measurements Of Aerosol Optical Depth & The Mozart Chemical Transport Model, Clare Paton-Walsh, L Emmons, Stephen R. Wilson
Faculty of Science - Papers (Archive)
In this paper we describe a new method for estimating trace gas emissions from large vegetation fires using satellite measurements of aerosol optical depth (AOD) at 550 nm, combined with an atmospheric chemical transport model. The method uses a threshold value to screen out normal levels of AOD that may be caused by raised dust, sea salt aerosols or diffuse smoke transported from distant fires. Using this method we infer an estimated total emission of 15±5 Tg of carbon monoxide, 0.05±0.02 Tg of hydrogen cyanide, 0.11±0.03 Tg of ammonia, 0.25±0.07 Tg of formaldehyde, 0.03±0.01 of acetylene, 0.10±0.03 Tg of ethylene, …
Average Mass Scan Of The Total Ion Chromatogram Versus Percentage Chemical Composition In Multivariate Statistical Comparison Of Complex Volatile Mixtures, Niko Radulovic, Polina Blagojevic, Danielle Skropeta
Average Mass Scan Of The Total Ion Chromatogram Versus Percentage Chemical Composition In Multivariate Statistical Comparison Of Complex Volatile Mixtures, Niko Radulovic, Polina Blagojevic, Danielle Skropeta
Faculty of Science - Papers (Archive)
The analysis of complex volatile mixtures by gas chromatography-mass spectrometry (GC-MS) is a time-consuming process. It involves separation and identification of the components based on their retention times and fragmentation patterns, followed by determination of their relative percentages from integration of their peak areas. Herein we show that multivariate statistical analysis of the relative abundances of the m/z values obtained from the average mass scans (AMS) of the complex mixture is a faster and potentially more reliable method of assessing these mixtures. To achieve this, 15 model complex mixtures, were prepared comprising varying amounts of 10 different constituents. The AMS …
Total Synthesis Of Uniflorine A, Casuarine, Australine, 3-Epi-Australine, And 3,7-Di-Epi-Australine From A Common Precursor, Thunwadee Ritthiwigrom, Anthony C. Willis, Stephen G. Pyne
Total Synthesis Of Uniflorine A, Casuarine, Australine, 3-Epi-Australine, And 3,7-Di-Epi-Australine From A Common Precursor, Thunwadee Ritthiwigrom, Anthony C. Willis, Stephen G. Pyne
Faculty of Science - Papers (Archive)
A flexible method for the diastereoselective total synthesis of the pyrrolizidine alkaloids Uniflorine A, casuarine, australine, and 3-epi-australine and the unnatural epimer 3,7-di-epi-australine from a common chiral 2,5-dihydropyrrole precursor is described.
Validation Of Five Years (2003-2007) Of Sciamachy Co Total Column Measurements Using Ground-Based Spectrometer Observations, A T. J De Laat, A M. S Gloudemans, H Schrijver, I Aben, Y Nagahama, K Suzuki, E Mahieu, N B. Jones, Clare Paton-Walsh, N M. Deutscher, D W. T Griffith, M De Maziere, R L. Mittermeier, H Fast, J Notholt, M Palm, T Hawat, T Blumenstock, F Hase, M Schneider, C Rinsland, A V. Dzhola, E I. Grechko, A M. Poberovskii, M V. Makarova, J Mellqvist, A Strandberg, R Sussmann, T Borsdorff, M Rettinger
Validation Of Five Years (2003-2007) Of Sciamachy Co Total Column Measurements Using Ground-Based Spectrometer Observations, A T. J De Laat, A M. S Gloudemans, H Schrijver, I Aben, Y Nagahama, K Suzuki, E Mahieu, N B. Jones, Clare Paton-Walsh, N M. Deutscher, D W. T Griffith, M De Maziere, R L. Mittermeier, H Fast, J Notholt, M Palm, T Hawat, T Blumenstock, F Hase, M Schneider, C Rinsland, A V. Dzhola, E I. Grechko, A M. Poberovskii, M V. Makarova, J Mellqvist, A Strandberg, R Sussmann, T Borsdorff, M Rettinger
Faculty of Science - Papers (Archive)
Abstract. This paper presents a validation study of SCanning Imaging Absorption spectroMeter for Atmospheric CHartographY (SCIAMACHY) carbon monoxide (CO) total column measurements from the Iterative Maximum Likelihood Method (IMLM) algorithm using ground-based spectrometer observations from twenty surface stations for the five year time period of 2003–2007. Overall we find a good agreement between SCIAMACHY and ground-based observations for both mean values as well as seasonal variations. For high-latitude Northern Hemisphere stations absolute differences between SCIAMACHY and ground-based measurements are close to or fall within the SCIAMACHY CO 2 precision of 0.2×1018 molecules/cm2 (10%) indicating that SCIAMACHY can observe CO accurately …
Calibration Of The Total Carbon Column Observing Network Using Aircraft Profile Data, Debra Wunch, G C Toon, Paul O. Wennberg, Steven C. Wofsy, Robert S. Stephens, M K.R. Fischer, O Uchino, J Abshire, P Bernath, S C Biraud, J-F Blavier, C Boone, K P. Bowman, E V. Browell, T Campos, B Connor, Bruce C. Daube, Nicholas M. Deutscher, M Diao, J W. Elkins, Christoph Gerbig, E Gottlieb, David W. Griffith, D F. Hurst, Rodrigo Jimenez, Gretchen Keppel-Aleks, E A. Kort, Ronald Macatangay, T Machidda, H Matsueda, F Moore, I Morino, S Park, J Robinson, C M. Roehl, Y Sawa, V Sherlock, C Sweeney, T Tanaka, M A. Zondlo
Calibration Of The Total Carbon Column Observing Network Using Aircraft Profile Data, Debra Wunch, G C Toon, Paul O. Wennberg, Steven C. Wofsy, Robert S. Stephens, M K.R. Fischer, O Uchino, J Abshire, P Bernath, S C Biraud, J-F Blavier, C Boone, K P. Bowman, E V. Browell, T Campos, B Connor, Bruce C. Daube, Nicholas M. Deutscher, M Diao, J W. Elkins, Christoph Gerbig, E Gottlieb, David W. Griffith, D F. Hurst, Rodrigo Jimenez, Gretchen Keppel-Aleks, E A. Kort, Ronald Macatangay, T Machidda, H Matsueda, F Moore, I Morino, S Park, J Robinson, C M. Roehl, Y Sawa, V Sherlock, C Sweeney, T Tanaka, M A. Zondlo
Faculty of Science - Papers (Archive)
The Total Carbon Column Observing Network (TCCON) produces precise measurements of the column average dry-air mole fractions of CO2, CO, CH4, N2O and H2O at a variety of sites worldwide. These observations rely on spectroscopic parameters that are not known with sufficient accuracy to compute total columns that can be used in combination with in situ measurements. The TCCON must therefore be calibrated to World Meteorological Orga-nization (WMO) in situ trace gas measurement scales. We present a calibration of TCCON data using WMO-scale instrumentation aboard aircraft that measured profiles over four TCCON stations during 2008 and 2009. These calibrations are …