Physical Sciences and Mathematics Commons^™

Gas-Particle Partitioning Of Atmospheric Hg(Ii) And Its Effect On Global Mercury Deposition, H M. Amos, D J. Jacob, C D. Holmes, Jenny A. Fisher, Q Wang, R M. Yantosca, E S. Corbitt, E Galarneau, A P. Rutter, M S. Gustin, A Steffen, J J. Schauer, J A. Graydon, V L. St Louis, R W. Talbot, E S. Edgerton, Y Zhang, E N. Sunderland

Faculty of Science - Papers (Archive)

Atmospheric deposition represents a major input of mercury to surface environments. The phase of mercury (gas or particle) has important implications for its removal from the atmosphere. We use long-term observations of reactive gaseous mercury (RGM), particle-bound mercury (PBM), fine particulate matter (PM_2.5), and temperature at five sites in North America to derive an empirical gas-particle partitioning relationship log₁₀(K^-1) = (10 ± 1) − (2500 ± 300)/T where K = (PBM/PM_2.5)/RGM with PBM and RGM in common mixing ratio units, PM_2.5 in μg m⁻³, and T in …