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Full-Text Articles in Physical Sciences and Mathematics
Insertion Of Benzylisocyanide Into A Zr-P Bond And Rearrangement. Atom-Economical Synthesis Of A Phosphaalkene, Samantha N. Macmillian, Joseph M. Tanski, Rory Waterman
Insertion Of Benzylisocyanide Into A Zr-P Bond And Rearrangement. Atom-Economical Synthesis Of A Phosphaalkene, Samantha N. Macmillian, Joseph M. Tanski, Rory Waterman
College of Arts and Sciences Faculty Publications
Reaction of (N3N)ZrPHPh (1, N3N = N(CH2CH2NSiMe3)33−) with PhCH2NC affords the 1,1-insertion product (N3N)Zr[C(PHPh)NCH2Ph] (2), which thermally rearranges to the phosphaalkene-containing complex, (N3N)Zr[N(CH2Ph)C(H)PPh] (3).