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Double-Hinged Di-1,2,4-Triazoles For Synthesis Of Breathing Mofs, Christopher Ray Murdock

Doctoral Dissertations

Employing semi-rigid di-1,2,4-triazoles as ligands has led to the formation of a plethora of Metal-Organic Framework (MOF) architectures. The ability for the ligands to exhibit multiple conformations through a “hinge” effect allows for the formation of a multitude of MOF topologies and dimensionalities. Employment of a di-triazole containing a central trans-butene moiety was initially studied and led to the formation of two three-dimensional copper MOFs. The frameworks can be synthesized independently, but a reaction occurs in water wherein the kinetic product is used as a reagent to synthesize the topologically distinct thermodynamic product.

Additional testing of reaction conditions with …