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Tellurorhodamine Photocatalysts In Aerobic Oxidation Reactions: Development Of Synthetic Methods And Reaction Mechanisms, Irving D. Rettig
Tellurorhodamine Photocatalysts In Aerobic Oxidation Reactions: Development Of Synthetic Methods And Reaction Mechanisms, Irving D. Rettig
Dissertations and Theses
Aerobic oxidation photocatalysis involves the use of oxygen as an oxidant species, coupled to a light driven catalyst to achieve useful chemical transformations. Catalytic aerobic oxidation reactions can be defined as either oxidase-like, in which O2 acts as an electron donor/acceptor but is not incorporated into the reaction products, or oxygenase-like where O2 acts as an electron donor/acceptor and is incorporated into the reaction products. A multitude of inorganic catalysts have been developed that can achieve a wide scope of oxidase-like or oxygenase-like reactivity, however, it is rare for a catalyst to be capable of both. We report …