Physical Sciences and Mathematics Commons^™

Hydrologic Modeling With Remote Sensing For The Estimation Of Groundwater Resources Within The Sand River Catchment, South Africa, Sophia Bakar

Electronic Theses and Dissertations

The Sand River Catchment is an important tributary of the transboundary Limpopo River in South Africa, which spans Botswana, Mozambique, South Africa, and Mozambique. Groundwater is a critical resource in the region, especially in the context of population growth and climate change. Data are needed for proper management of these water resources. In regions where groundwater data are sparse in time, space, or both, the most promising solutions come from satellites and hydrologic models. Regional literature suggests that the Soutpansberg Mountains, located within the Sand Catchment, are high-elevation water towers with uncertain groundwater resources. Improved understanding of groundwater resources in …

Anthropogenic Effects On Tidal Distortion In A Tidal River, Matthew D. Fischer

Electronic Theses and Dissertations

Tidal rivers are landward portions of estuarine systems constituting the union between coastal, tidally controlled settings and rivers, where fluvial processes dominate. In these reaches, river discharge (mean flow) and tides are the two most important mechanisms in controlling geophysical flows. The processes governing water levels and current amplitudes in tidal rivers are highly nonlinear and modulated by external forcings- thus requiring sophisticated techniques for accurate prediction and forecasting. Physical oceanographers and estuarine physicists tend to limit their study area to the maximum extent of the horizontal tide (salinity intrusion), not the most landward point influenced by tidal water levels. …

Geochemical And Climatic Controls On The Sulfur Cycle In Volcanic Settings: Implications For The Origin Of Sulfur-Rich Deposits Investigated By The Spirit And Opportunity Rovers On Mars, Rhianna D. Moore

Doctoral Dissertations

On Earth, volcanic activity with elevated sulfur (S) degassing in the presence of water leads to the formation of hydrothermal deposits enriched in S-bearing minerals. Similar processes may have been an important source of S on Mars. The landing sites of Gusev crater and Meridiani Planum investigated by the Spirit and Opportunity rovers, respectively, showed elevated SO₄^2- [sulfate] concentrations, suggesting high- and low-temperature aqueous processes. However, the SO₄^2- contribution from subsequent aqueous weathering of hydrothermal S deposits has been poorly constrained, thus its importance to regional S cycling in the landing sites is unclear. In this …

Quantifying A 21-Year Surface Water And Groundwater Interaction In A Ridge And Valley Lake Environment Using A Highly Constrained Modeling Approach, Richard T. Bowers Jr.

USF Tampa Graduate Theses and Dissertations

Karst lakes are ubiquitous in ridge terrain settings in limestone aquifer coastal plain environments. In west-central Florida, these lakes are frequently connected to the Upper Floridan aquifer and have unique aquifer recharge characteristics. They have been selectively studied because they commonly have no or very limited surface water discharge and limited drainage areas, have appreciable surface water and groundwater interaction and leak to the deep aquifer. An innovative modeling approach was developed to collectively understand and more precisely quantify this vertical leakage, both from a lake-specific and regional water budget standpoint, for a 21-year study period (2000-2020). A unique, calibrated …

Hydrogeologic Investigation Of A Covered Karst Terrain, Joseph Peter Honings

LSU Doctoral Dissertations

Increasing demand for water for agricultural use within the Dougherty Plain of the Southeastern United States has depleted surface water bodies. In karstic landscapes, such as the Dougherty Plain in southwest Georgia where the linkages between surface and ground waters are close, there is a need to understand the physical characteristics of the subsurface that allow these close linkages. Having a better understanding of the subsurface characteristics will aid numerical modeling efforts that underpin policy decisions and economic analyses. Two common features on this karstic landscape are draws and geographically isolated wetlands. Using LiDAR, aerial imagery, and ground-penetrating radar, this …

Size, Timing, And Landscape Impacts Of Glacial Lake Outburst Floods In The Channeled Scabland Of Eastern Washington, Usa, Karin E. Lehnigk

Doctoral Dissertations

Extreme floods have dramatically altered landscapes on Earth and Mars through bedrock erosion, sediment deposition, and canyon formation. The Channeled Scabland of the Columbia Plateau in eastern Washington, USA, is perhaps the most striking example of such a landscape, where outburst floods from an ice-dammed glacial Lake Missoula eroded immense canyons and transported large volumes of sediment during the late Pleistocene. Despite advances in numerical modeling and geochemical exposure dating methods, it has remained a challenge to untangle the complex interactions between floodwater, bedrock, and glacial ice to link the size of a flood with its impact on the landscape. …

Hydrologic Response Of Little Creek To The 2020 Czu Lightning Complex Fire At The Swanton Pacific Ranch, Kylie E. Dupuis

Master's Theses

In this study, stage, streamflow, and precipitation data was collected from small watersheds in the Swanton Pacific Ranch for the first two hydrologic years following the 2020 CZU Lightning Complex. The Little Creek watershed was setup for high-resolution data collection with four separate stage gauge sites (Main Stem, North Fork, South Fork, and Upper North Fork) and four rain gauge sites (Al Smith House, Ridgeline, Upper North Fork, and Landing 23). Stage gauge sites were also established at Queseria, Archibald, and Mill creeks. Preliminary post-fire rating curves were developed for the four sites of Little Creek. The Main Stem (MS) …

Spatial Analysis Of Burn Severity And Streamflow Response In The Western Conus, Will Brendan Long

Dissertations and Theses

Wildfire increases the magnitude of runoff in catchments, which can lead to the degradation of ecosystems, risk to infrastructure, and loss of life. The Labor Day Fires of 2020 provided an opportunity to compare multiple large and severe wildfires with the objective of determining potential changes to hydrologic processes in Oregon Cascades watersheds. Geographic information systems (GIS) were implemented to determine the total percentage burned and percentage of high burn severity class of six watersheds on the west-slope of the Oregon Cascade Range. In addition, two control watersheds were included to contrast the influence of climatic effects. Spatial arrangement of …

Post-Fire Erosional And Hydrological Processes Promoting Debris Flow Initiation In A Douglas Fir And Western Hemlock Forest In The Riverside Burn Area, Oregon, Morena Nicole Hammer

Dissertations and Theses

Post-fire debris flows initiated by overland flow in the Pacific Northwest (PNW) are largely undocumented. Instead, debris flows are typically initiated by shallow landslides that result in a mud slurry of water and sediments traveling downhill under the force of gravity. However, because of the Fall 2020 fires in Oregon, the typical initiation style and erosional patterns in burned catchments may have changed because of unusually high burn severity. Due to the intensity of these fires, we set out to determine how hydrologic processes and erosion occurred, when they occurred, and what process was primarily responsible for the erosion that …

Characterization Of Municipal Water Sources For The Mexico-Lerma-Cutzamala Basin Region, Ian F. Hirons

International Development, Community and Environment (IDCE)

The Mexico and Toluca Valleys in central Mexico are part of one of the most heavily populated megalopolises in the western hemisphere where consistent access to safe, affordable, and quality water sources figures to be a decisive challenge in the era of climate change. This professional project report compiles a range of statistics and information about the vital liquid for 29 municipalities located in and around the Mexico City and Toluca areas. This contribution is derived from a broader team research endeavor that seeks to gauge the impacts and adaptive processes to climate change within those regions. By doing so, …

Application Of A 14c-Assay To Assess Methanotrophic Biodegradation Of Tce In Low Ph Groundwater, Evan Groome

All Theses

Current biological strategies for remediating trichloroethylene (TCE) in low pH aquifers (i.e., pH14C-TCE assay was developed to determine pseudo first-order rate constants for the degradation of TCE in microcosms containing soil and groundwater from the Boeing Michigan Aeronautical Research Center (BOMARC) superfund site, where the pH ranges from 4.1 to 4.9. The ¹⁴C-TCE assay was also adapted to calculate soil-normalized rate constants for data from this site, as well as data that Szwast²¹ collected from the Beltsville Agricultural Research Center (BARC). In addition to natural attenuation, biostimulation through amendments of methane and nutrients were also assessed. This treatment …

Water Sourcing Strategies Of Desert Vegetation In Varying Soil Textures With Vegetation Competition: A Stable Isotope Analysis, Martha Elizabeth Gardea

Open Access Theses & Dissertations

Recent studies have suggested an ecohydrological separation of water exists in the northern Chihuahuan Desert, where vegetation types, rainfall regimes, and location in the terrain seem to determine the type of water (e.g. isotopically depleted or enriched in 18O and 2H) plants are able to source and use throughout their growing cycle. That work found evidence of creosote (Larrea tridentata) and mesquite (Prosopis glandulosa) using tightly bound soil water at both a site on an ephemeral channel and a site in higher elevated flat area because the isotopic signature of plant water at the beginning of the study did not …

Learning From Machines: Insights In Forest Transpiration Using Machine Learning Methods, Morgan Tholl

Dissertations and Theses

Machine learning has been used as a tool to model transpiration for individual sites, but few models are capable of generalizing to new locations without calibration to site data. Using the global SAPFLUXNET database, 95 tree sap flow data sites were grouped using three clustering strategies: by biome, by tree functional type, and through use of a k-means unsupervised clustering algorithm. Two supervised machine learning algorithms, a random forest algorithm and a neural network algorithm, were used to build machine learning models that predicted transpiration for each cluster. The performance and feature importance in each model were analyzed and compared …

Patterns Of Dissolved Methane In Groundwater And Its Contribution To Emissions Inventories, Amanda E. Campbell

Dissertations - ALL

The Marcellus Shale is the largest shale gas play in the U.S. production of natural gas using high-volume hydraulic fracturing (HVHF) and production is prevalent throughout the play except in New York (NY), where it is currently banned. High concentrations of methane, the main component of natural gas, in groundwater, as well as its presence in the atmosphere, can have negative consequences. In this dissertation, three aspects of this issue are explored: 1) how and why naturally-occurring methane concentrations vary through time; 2) how elevated naturally-occurring methane concentrations in domestic water wells can be predicted from commonly observed well characteristics; …

Remote Sensing Of High Latitude Rivers: Approaches, Insights, And Future Ramifications, Merritt E. Harlan

Doctoral Dissertations

High latitude rivers across the pan-Arctic domain are changing due to changes in climate and positive Arctic feedback loops. Understanding and contextualizing these changes is challenging due to a lack of data and methods for estimating and modeling river discharge, and mapping rivers. Remote sensing, and the availability of satellite imagery can provide ways to overcome these challenges. Through combining various forms of fieldwork, modeling, deep learning, and remote sensing, we contribute methodologies and knowledge to three key challenges associated with better understanding high latitude rivers. In the first chapter, we combine field data that can be rapidly deployed with …

Sewer System Infrastructure And Stressors On Water Quality In Streams Within The Alplaus Watershed In Upstate Ny, Camryn Ragland

Honors Theses

Healthy aquatic ecosystems require clean water, but many creeks and streams may be impaired by human activity. This study is focused on surface water quality of the Alplaus, and Indian Kill streams located within the Alplaus Watershed in Schenectady and Saratoga Counties (NY). The primary goal of this study is to understand the extent of water quality impairment within the Alplaus and Indian Kill using a range of indicators to understand the impacts of failing infrastructure and stressors to surface water. Sixty-five water samples were collected in the fall of 2021 from six locations in the Alplaus and Indian Kill …

Fluid Pathways In Magmatic Fluid-Dominated Hydrothermal System: Upper Resurgent Cone, Brothers Volcano, New Zealand, Esther G. Goita

Honors Theses

The Tonga-Kermadec Arc is an active volcanic arc located between New Zealand and Fiji. The arc expands over an approximate distance of 2530 km. The Kermadec Arc is currently host to over 30 volcanoes, the majority of which are submarine. The magmatic activity along the arc is characterized by the convergence between the Pacific and Australian plates. Brothers volcano is the most active hydrothermal system along the Kermadec arc and hosts two distinct hydrothermal systems, one magmatic fluid dominated, and the other seawater dominated, making the site perfect for studying nascent volcanogenic massive sulfide formation and fluid pathways. The International …

Groundwater Monitoring Analysis And Management Recommendations In California: Cuyama And Santa Cruz Mid-County, Kayla M. Souza

Master's Projects and Capstones

Groundwater is an essential water resource, accounting for about 40 percent of supply in California and 80 percent in the Central Coast hydrologic region, but significant monitoring data gaps have limited sustainable management efforts. Twenty-four basins within the Central Coast hydrologic region were identified as critically overdrafted in 2014. For this study, two basins were chosen based on differing sustainability concerns so that a comparative analysis could be performed on the groundwater monitoring methods. I obtained original groundwater elevation data reported (2000-2020) from the various groundwater monitoring organization wells to the California Department of Water Resources (DWR) within the Cuyama …

Impact Of Climate Oscillations/Indices On Hydrological Variables In The Mississippi River Valley Alluvial Aquifer., Meena Raju

Theses and Dissertations

The Mississippi River Valley Alluvial Aquifer (MRVAA) is one of the most productive agricultural regions in the United States. The main objectives of this research are to identify long term trends and change points in hydrological variables (streamflow and rainfall), to assess the relationship between hydrological variables, and to evaluate the influence of global climate indices on hydrological variables. Non-parametric tests, MMK and Pettitt’s tests were used to analyze trend and change points. PCC and Streamflow elasticity analysis were used to analyze the relationship between streamflow and rainfall and the sensitivity of streamflow to rainfall changes. PCC and MLR analysis …

Characterization Of Quaternary Stratigraphy In The Mississippi Sound To Evaluate The Influence Of Geologic Heterogeneity On Submarine Groundwater Transport And Discharge, Zachary Peoples

Theses and Dissertations

Submarine Groundwater Discharge (SGD) through seafloor sediments is gaining recognition as an important component of coastal water quality. Stratigraphic features creating geologic heterogeneity, such as incised paleochannels, may influence preferential pathways for SGD. The central Mississippi Sound is underlain by paleochannels that were incised into Pleistocene sediments while the area was subaerially exposed during the last glacial maximum and are now buried by transgressive Holocene deposits. In this thesis, newly collected chirp, previously published seismic reflection, and sediment core data are used to characterize the three-dimensional structure of the Holocene-Pleistocene contact. Results indicate that Pleistocene paleochannels cross-cut the study area, …

Development And Evaluation Of Seasonal, Continental-Scale Streamflow Forecasts, Elissa Marie Yeates

Theses and Dissertations

Methods of forecasting streamflow using atmospheric ensembles and hydrologic routing have greatly improved over the past decades. These forecasts anticipate the timing and magnitude of streamflow peaks, enabling early warning of floods. Recent advances in atmospheric modeling have enabled production of forecasts months ahead, which are less precise but give a useful sense of trends.

The purpose of this study is to produce and evaluate a seasonal streamflow forecast model using a Muskingum routing hydrologic model coupled with runoff from a land surface model, and atmospheric input from a medium-term atmospheric and precipitation model. To evaluate the skill of the …

Overlapping Scales Of Place Based Indigenous Knowledge And Hydroclimate In Australia, Rachel L. Coleman

Electronic Theses and Dissertations

Indigenous Peoples have been monitoring and adapting to uncertainty and change in their local regions for millennia, resulting in a holistic view of the interlinkages within the occupied complex socio-environmental systems. This research consists of investigating the overlapping scales of knowledge within Indigenous Australian seasonal calendars and colonial methods of hydroclimate assessment for improving adaptability to climate change impacts.

The analyses began with a sample of 25 Indigenous seasonal calendars providing a glimpse into interlinkages among biota, environment, and meteorology of the localised regions. Across the calendars, five themes of information and multiple categories within these themes became apparent and …

Giving Form To Flow: Modeling The Paleohydrological Context For Human Settlement And Water Use In The North-Central Coast Of Peru, Elizabeth Leclerc

Electronic Theses and Dissertations

Within coastal Andean archaeology there is a growing emphasis on the roles of hydrology and hydrological knowledge in Andean strategies for water management, settlement, and land use. Hydrological methods can not only help reconstruct past water environments but also illuminate the influence of changing climates and conditions in the Andean highlands on coastal water flows. Through a case study of the Supe River basin in north-central coastal Peru, focusing on the period from 5000 to 3000 calibrated radiocarbon years before present (cal. BP), I review several hydrological methods useful for archaeological study. I then combine these to develop a paleohydrological …

Characterization Of Water Flow And Solute Transport Driven By Preferential Flow In Soil Vadose Zone, Abdullah Al Mamun

All Dissertations

The vadose zone acts as a buffer zone between the ground surface and the aquifers underneath and controls the transmission of infiltrating water and contaminants, for example, pesticides and chemical spills. Therefore, understanding the flow and transport processes that dominate the vadose zone is important. Macropores are ubiquitous and particularly found in abundance in the vadose zone. These macropores facilitate preferential flow, through which water travels rapidly deep into the soil, bypassing most of the porous matrix. Preferential flow and transport have environmental significance as their processes impact hydrology, ecology, agriculture, subsurface contamination, and waste management sectors. Thus, the overall …

Wetland Uranium Transport Via Iron-Organic Matter Flocs And Hyporheic Exchange, Connor J. Parker

All Dissertations

Uranium (U) released from the M-Area at the Department of Energy Savannah River Site into Tims Branch, a seasonal wetland and braided stream system, is estimated to be 43,500 kg between 1965 and 1984. The motivation for this work is the uranium’s persistence in the wetland for decades, where it is estimated that 80% of the U currently remains in the Tims Branch wetland. U has begun to incorporate into wetland iron (Fe) and carbon cycles, associating with local Fe mineralogy and deposits of rich wetland organic matter (OM). The objective of this work is to characterize the chemical phases …

Fate And Transport Of Toxoplasma Gondii Oocysts In Saturated Porous Media: Effects Of Electrolytes And Natural Organic Matter, Christian Pullano

All Theses

Toxoplasma gondii is a pathogenic microorganism that is currently a threat to public health. Understanding the fate and transport of T. gondii through the soil and groundwater is vital in determining the risk it poses to water resources and human health. The physico-chemical interactions between the groundwater and the bio colloid within an aquifer will dictate its mobility and its ability to infect humans. This research examines how various naturally occurring groundwater chemistries containing organic compounds and monovalent and divalent salt solutions will alter the fate and transport of T. gondii. Solutions containing various concentrations of humic acid, fulvic …

Alkalinity Enhanced Mass Reduction Of Uranium Contaminated Sediment, Cullen Edward Meurer

Theses and Dissertations

Uranium is a toxic and radioactive metal that is naturally occurring in the Earth’s crust. The uranium mining boom of the 1950’s produced many contaminated aquifers throughout the United States. Monitoring of groundwater data suggests that uranium concentrations may take 100’s of years to naturally attenuate to below the maximum contamination limit. This project examines a potential and novel remediation technique of groundwater contaminated with uranium through alkalinity enhanced desorption from the solid phase. Alkalinity enhances the desorption of uranium by complexing uranyl (UO22+) with Ca and CO3 which allows for further desorption. Since remediation is time consuming and expensive, …

Mass Transport Of Uranium During Recharge Of Surface Water To Contaminated Groundwater, Kendyl Nicole Hoss

Theses and Dissertations

This study characterized the predominant mass transport mechanisms of uranium during river water recharge to contaminated groundwater to better characterize its mobility. It was hypothesized that the mass transfer of uranium from the solid phase to the aqueous phase was occurring during periods of river water to groundwater recharge via concentration-driven desorption. Sediment data confirmed the presence of uranium on the solid phase via nitric acid extraction. The recharge of river water to the saturated zone of a uranium-contaminated aquifer was simulated in a multi-well tracer test. The injection fluid was Little Wind River water and was traced with added …

Temporal Changes In Surface Water Availability: Patterns Of Seasonal Shift On Water Stress In The Conterminous Us Under A Changing Climate, Quinn Montana

Graduate Theses and Dissertations

The argument could be made that there is nothing more valuable on the planet than water. Our lives depend upon it. Climate change is already having an impact on the United States (US) and water stress will be one of the problems we increasingly face in coming decades. Regional research has shown that one or another part of the conterminous US (CONUS) is expected to experience an annual deficit or a surplus in runoff. Further studies have looked at changing patterns over the CONUS as a whole. Other research has focused on a particular season. This work addresses a gap …

The Effect Of Changing Land Use On Streamflow Statistics And Flood Flows Across Select Gages In Northwest Arkansas, Timothy Mcmullen

Civil Engineering Undergraduate Honors Theses

Since 1901, heavy rainfall events have increased in the United States in both intensity and frequency, and population in the United States has increased, resulting in significant land use changes. Both of these trends could explain an increase in observed flood magnitude and frequency. In order to determine if a relationship exists between land use/land cover and changing stream flows in northwest Arkansas, this study analyzed temporal changes in various flow statistics for fourteen stream gages and compared the rates of change in flow statistics from gages on streams with watersheds that have varying land uses, i.e. urban, agricultural, and …