Physical Sciences and Mathematics Commons^™

Landscape/Atmosphere Interactions And Carbon-Dioxide Dynamics In The Great Onyx Groundwater Basin, Mammoth Cave National Park, Kentucky, Meghan Raines

Masters Theses & Specialist Projects

An increase in atmospheric CO2 since the Industrial Revolution has altered rates of global climate change and has motivated a need to better quantify the flux of carbon between Earth’s reservoirs. Attempts to quantify the exchange of atmospheric carbon between sources and sinks have led to an increasing interest in the terrestrial landscape, including the continental carbon sink associated with carbonate-mineral dissolution. This research sought to better inform an understanding of karst landscapes and their relationship with global climate change through carbon cycling. The study utilized high-resolution data collection of pH, temperature, and specific conductance of waters in the Cascade …

Exploring, Exploiting And Evolving Diversity Of Aquatic Ecosystem Models: A Community Perspective, Annette B.G. Janssen, George B. Arhonditsis, Arthur Beusen, Karsten Bolding, Louise Bruce, Jorn Bruggeman, Raoul-Marie Couture, Andrea S. Downing, J. Alex Elliott, Marieke A. Frassl, Gideon Gal, Daan J. Gerla, Matthew R. Hipsey, Fenjuan Hu, Stephen C. Ives, Jan H. Janse, Erik Jeppesen, Klaus D. Jöhnk, David Kneis, Xiangzhen Kong, Jan J. Kuiper, Moritz K. Lehmann, Carsten Lemmen, Deniz Özkundakci, Thomas Petzoldt, Karsten Rinke, Barbara J. Robson, René Sachse, Sebastiaan A. Schep, Martin Schmid, Huub Scholten, Sven Teurlincx, Dennis Trolle, Tineke A. Troost, Anne A. Van Dam, Luuk P.A. Van Gerven, Mariska Weijerman, Scott A. Wells, Wolf M. Mooij

Civil and Environmental Engineering Faculty Publications and Presentations

Here, we present a community perspective on how to explore, exploit and evolve the diversity in aquatic ecosystem models. These models play an important role in understanding the functioning of aquatic ecosystems, filling in observation gaps and developing effective strategies for water quality management. In this spirit, numerous models have been developed since the 1970s. We set off to explore model diversity by making an inventory among 42 aquatic ecosystem modellers, by categorizing the resulting set of models and by analysing them for diversity. We then focus on how to exploit model diversity by comparing and combining different aspects of …

8000 Years Of Environmental Evolution Of Barrier–Lagoon Systems Emplaced In Coastal Embayments (Nw Iberia), Rita González-Villanueva, Marta Pérez-Arlucea, Susana Costas, Roberto Bao, Xose L. Otero, Ronald J. Goble

Department of Earth and Atmospheric Sciences: Faculty Publications

The rocky and indented coast of NW Iberia is characterized by the presence of highly valuable and vulnerable, small and shallow barrier– lagoon systems structurally controlled. The case study was selected to analyse barrier–lagoon evolution based on detailed sedimentary architecture, chronology, geochemical and biological proxies. The main objective is to test the hypothesis of structural control and the significance at regional scale of any highenergy event recorded. This work is also aimed at identifying general patterns and conceptualizing the formation and evolution of this type of coastal systems. The results allowed us to establish a conceptual model of Holocene evolution …

Hydrologic Controls Of Coastal Groundwater Discharge In Southern Taylor Slough, Everglades National Park, Florida, Edward Linden

FIU Electronic Theses and Dissertations

This project empirically determined the controls of groundwater discharge potential and surface water chemistry in southern Taylor Slough, Everglades National Park, Florida. Potential for groundwater discharge was calculated as the difference in equivalent freshwater stage between groundwater and surface water on a daily basis for two sites (upland and coastal) along southern Taylor Slough. Upstream water stages were shown to vary most similarly to the timing of groundwater discharge potential in coastal Taylor Slough. Surface water major ion chemistry did not apparently change as a result of groundwater discharge potential. Surface water major ion chemistry at the coastal site was …

Hydroclimatic Shifts In Northeast Thailand During The Last Two Millennia — The Record Of Lake Pa Kho, Sakonvan Chawchai, Akkaneewut Chabangborn, Sherilyn C. Fritz, Minna Väliranta, Carl-Magnus Mörth, Maarten Blaauw, Paul J. Reimer, Paul J. Kusic, Ludvig Löwemark, Barbara Wohlfarth

Department of Earth and Atmospheric Sciences: Faculty Publications

The Southeast Asian mainland is located in the central path of the Asian summer monsoon, a region where paleoclimatic data are still sparse. Here we present a multi-proxy (TOC, C/N, δ13C, biogenic silica, and XRF elemental data) study of a 1.5 m sediment/peat sequence from Lake Pa Kho, northeast Thailand, which is supported by 20 AMS 14C ages. Hydroclimatic reconstructions for Pa Kho suggest a strengthened summer monsoon between BC 170–AD 370, AD 800–960, and after AD 1450; and a weakening of the summer monsoon between AD 370–800, and AD 1300–1450. Increased run-off and a higher nutrient supply after AD …

Carbon Cycling Dynamics Inferred From Carbon Isotope Sourcing In A Mid-Latitude Karst-Influenced River, Kegan N. Mcclanahan

Masters Theses & Specialist Projects

As ever-increasing levels of carbon dioxide alter the chemistry of the Earth’s atmosphere, understanding the global carbon cycle becomes increasingly important. A particularly important component is the riverine carbon cycle, as rivers are the primary conduits for dissolved inorganic carbon from terrestrial watersheds to ocean basins. Stable carbon isotopes (13C/12C) were collected weekly and input into the mixing model IsoSource to delineate seasonal carbon sourcing along two nested basins in the upper Green River System, Kentucky. In the more siliciclastic upstream catchment, dissolved inorganic carbon (DIC) was primarily derived from soil respiration (34%). Groundwater dissolving carbonate bedrock and carbonate dissolution/precipitation …

Sources Of Co2 Controlling The Carbonate Chemistry Of The Logsdon River, Mammoth Cave, Kentucky, Bruce Elliott Hatcher

Masters Theses & Specialist Projects

Logsdon River is a major, base-level stream within the Turnhole Bend Drainage basin of the Mammoth Cave System. The Logsdon River system has provided a unique opportunity to examine the geochemical evolution of a stream flowing through a major karst conduit that can be traversed for 10 km. This study examines CO₂ inputs at the upstream portion of the river, which provide major control for the river’s hydrochemistry. Samples were collected from the upstream portion of Logsdon River at what is referred to as the S-188 sump and also nearby at Crowbar Dome over the course of 44 weeks …

Late Holocene Paleoenvironmental Reconstruction In Barbados, Gilman Reno Ouellette

Masters Theses & Specialist Projects

Barbados is the easternmost island in the Caribbean region, and is uniquely situated between the Atlantic Ocean and Caribbean Sea. Being an isolated island with a karstified aquifer providing the majority of the nation’s water resources, Barbados has found itself in water scarce situations in recent years. In order to better understand natural shifts in groundwater recharge (which is determined by shifts in precipitation), longer records of precipitation are needed than are available from modern measurements. This study presents a paleoclimate reconstruction for the late Holocene on Barbados using stable and radiogenic isotope ratios in speleothem lamina as proxies. In …

State Of The Antarctic And Southern Ocean Climate System, Paul Andrew Mayewski, M. P. Meredith, C. P. Summerhayes, J. Turner, A. Worby, P. J. Barrett, G. Casassa, Nancy Bertler, T. Bracegirdle, A. C. Naveira Garabato, D. Bromwich, H. Campbell, Gordon S. Hamilton, W. B. Lyons, Kirk A. Maasch, S. Aoki, C. Xiao, Tas Van Ommen

Earth Science Faculty Scholarship

This paper reviews developments in our understanding of the state of the Antarctic and Southern Ocean climate and its relation to the global climate system over the last few millennia. Climate over this and earlier periods has not been stable, as evidenced by the occurrence of abrupt changes in atmospheric circulation and temperature recorded in Antarctic ice core proxies for past climate. Two of the most prominent abrupt climate change events are characterized by intensification of the circumpolar westerlies (also known as the Southern Annular Mode) between ∼6000 and 5000 years ago and since 1200–1000 years ago. Following the last …

Ice Core Record Of Rising Lead Pollution In The North Pacific Atmosphere, E. Osterberg, Paul Andrew Mayewski, Karl J. Kreutz, D. Fisher, Michael Handley, Sharon Sneed, C. Zdanowicz, J. Zheng, M. Demuth, M. Waskiewicz, J. Bourgeois

Earth Science Faculty Scholarship

A high-resolution, 8000 year-long ice core record from the Mt. Logan summit plateau (5300 m asl) reveals the initiation of trans-Pacific lead (Pb) pollution by ca. 1730, and a >10-fold increase in Pb concentration (1981–1998 mean = 68.9 ng/l) above natural background (5.6 ng/l) attributed to rising anthropogenic Pb emissions from Asia. The largest rise in North Pacific Pb pollution from 1970–1998 (end of record) is contemporaneous with a decrease in Eurasian and North American Pb pollution as documented in ice core records from Greenland, Devon Island, and the European Alps. The distinct Pb pollution history in the North Pacific …

Snow Chemistry Across Antarctica, Nancy Bertler, Paul Andrew Mayewski, Alberto Aristarain, P. Barrett, S. Becagli, Ronaldo Torma Bernardo, Xiao Cunde, M. Curran, Qin Dahe, Daniel Dixon, Francisco Adolfo Ferron, H. Fischer, Markus Frey, M. Frezzotti, F. Fundel, Christophe Genthon, R. Gragani, Gordon Hamilton, M. Handley, Sungmin Hong, E. Isaksson, Ren Jiawen, Kokichi Kamiyama, Satoru Kanamori, Eija Karkas, L. Karlöf, S. Kaspari, K. Kreutz, A. Kurbatov, E. Meyerson, Hideaki Motoyama, R. Mulvaney, Zhang Mingjun, H. Oerter, E. Osterberg, M. Proposito, A. Pyne, U. Ruth, Jefferson Cardia Simoes, B. Smith, S. Sneed, Kimmo Teinila, F. Traufetter, R. Udisti, Aki Virkkula, Okitsugu Watanabe, B. Williamson, E. Wolff, Li Zhongqin

Earth Science Faculty Scholarship

An updated compilation of published and new data of major-ion (Ca, Cl, K, Mg, Na, NO₃, SO₄) and methylsulfonate (MS) concentrations in snow from 520 Antarctic sites is provided by the national ITASE (International Trans-Antarctic Scientific Expedition) programmes of Australia, Brazil, China, Germany, Italy, Japan, Korea, New Zealand, Norway, the United Kingdom, the United States and the national Antarctic programme of Finland. The comparison shows that snow chemistry concentrations vary by up to four orders of magnitude across Antarctica and exhibit distinct geographical patterns. The Antarctic-wide comparison of glaciochemical records provides a unique opportunity to improve …

The International Trans-Arctic Scientific Expedition (Itase): An Overview, Paul Andrew Mayewski, Massimo Frezzotti, Nancy Bertler, Tas Van Ommen, Gordon S. Hamilton, Tim H. Jacka, Brian Welch, Markus Frey, Dahe Qin, Jiawen Ren, Jefferson Simões, Michel Fily, Hans Oerter, Fumihiko Nishio, Elisabeth Isaksson, Robert Mulvaney, Per Holmund, Volodya Lipenkov, Ian Goodwin

Earth Science Faculty Scholarship

From its original formulation in 1990 the International Trans-Antarctic Scientific Expedition (ITASE) has had as its primary aim the collection and interpretation of a continent-wide array of environmental parameters assembled through the coordinated efforts of scientists from several nations. ITASE offers the ground-based opportunities of traditional-style traverse travel coupled with the modern technology of GPS, crevasse detecting radar, satellite communications and multidisciplinary research. By operating predominantly in the mode of an oversnow traverse, ITASE offers scientists the opportunity to experience the dynamic range of the Antarctic environment. ITASE also offers an important interactive venue for research similar to that afforded …

Variability In Accumulation Rates From Gpr Profiling On The West Antarctic Plateau, Vandy B. Spikes, Gordon S. Hamilton, Steven A. Arcone, Susan Kaspari, Paul Andrew Mayewski

Earth Science Faculty Scholarship

Isochronal layers in firn detected with ground-penetrating radar (GPR) and dated using results from ice-core analyses are used to calculate accumulation rates along a 100 km across-flow profile in West Antarctica. Accumulation rates are shown to be highly variable over short distances. Elevation measurements from global positioning system surveys show that accumulation rates derived from shallow horizons correlate well with surface undulations, which implies that wind redistribution of snow is the leading cause of this variability. Temporal changes in accumulation rate over 25-185 year intervals are smoothed to along-track length scales comparable to surface undulations in order to identify trends …

Antarctic Oversnow Traverse-Based Southern Hemisphere Climate Reconstruction, Paul Andrew Mayewski

Earth Science Faculty Scholarship

On 2 January 2003, the U.S. component of the International Trans Antarctic Scientific Expedition (U.S. ITASE) (Figure 1) arrived at the South Pole after completing more than 5000 km of oversnow traverses that included much of west Antarctica and a portion of east Antarctica (Figure 2). During the traverses, which were performed from 1999 through 2003, U.S. ITASE focused on collecting data that will allow the reconstruction of sub-annual scale climate variability and changes in the chemistry of the atmosphere over the last 200+ years.

ITASE is a multi-disciplinary research program supported by 19 nations and endorsed by the Scientific …

Chemical Composition Of Fresh Snow On Xixabangma Peak, Central Himalaya, During The Summer Monsoon Season, Shichang Kang, Dahe Qin, Paul Andrew Mayewski, Sharon B. Sneed

Earth Science Faculty Scholarship

The physical and chemical analysis of ice cores recovered from glaciers in the Himalaya provide some of the best records of past climate change in the region (e.g. Qin and others, 2000; Thompson and others, 2000; Kang and others, 2001, 2002). In order to better understand the climatic and environmental records preserved in snow and ice, studies have investigated the precipitation chemistry in the high Himalaya, notably that the northern slopes of the central Himalaya (Mayewski and others, 1986; Jenkins and others 1987) and the southern slopes of the central Himalaya (Shrestha and others, 1997; Marinoni and others, 2001).

Methanesulfonate In The Firn Of King George Island, Antarctica, Jiankang Han, Zichu Xie, Xinping Zhang, Dongsheng Dai, Paul Andrew Mayewski, M. S. Twickler

Earth Science Faculty Scholarship

Methanesulfonate was investigated as a potential contributor to the sulfur budget, based on analysis of a firn core from Collins Ice Cap, King George Island, Antarctica (62°10' S, 58°50' W). The anion was found to be present at a mean concentration of 0.17 μeq L^-1, with a maximum of 0.73 μeq L^-1. Dating based on the δ¹⁸O profile suggests that the principal peaks of methanesulfonate are associated with snow deposited in summer and autumn. A careful examination of MSA, SO₄^2-and nssSO₄^2- profiles indicates that two of the three peaks …

High-Precision Dating Of Volcanic Events (A.D. 1301–1995) Using Ice Cores From Law Dome, Antarctica, Anne S. Palmer, Tas D. Van Ommen, Mark A. J. Curran, Vin Morgan, Joe M. Souney, Paul Andrew Mayewski

Earth Science Faculty Scholarship

A record of volcanic activity over the period A.D. 1301–1995 has been extracted from three Law Dome ice cores (East Antarctica). The record dating is unambiguous at the annual level from A.D. 1807 to 1995 and has an uncertainty of ±1 year at A.D. 1301. Signals from 20 eruptions are preserved in the record, including those of two unknown eruptions with acid deposition beginning in A.D. 1810.8 and A.D. 1685.8. The beginning of the ice core signal from the A.D. 1815 Tambora eruption is observed in the austral summer of A.D. 1816/1817. The mean observed stratospheric transport and deposition time …

The Effect Of Spatial And Temporal Accumulation Rate Variability In West Antarctica On Soluble Ion Deposition, K. J. Kreutz, Paul Andrew Mayewski, L. D. Meeker, M. S. Twickler, S. I. Whitlow

Earth Science Faculty Scholarship

Annually‐dated snowpit and ice core records from two areas of West Antarctica are used to investigate spatial accumulation patterns and to evaluate temporal accumulation rate/glaciochemical concentration and flux relationships. Mean accumulation rate gradients in Marie Byrd Land (11–23 gcm⁻²yr⁻¹ over 150 km, decreasing to the south) and Siple Dome (10–18 gcm⁻²yr⁻¹ over 60 km, decreasing to the south) are consistent for at least the last several decades, and demonstrate the influence of the offshore quasi‐permanent Amundsen Sea low pressure system on moisture flux into the region. Local and regional‐scale topography in both regions appears …

Sea Level Pressure Variability In The Amundsen Sea Region Inferred From A West Antarctic Glaciochemical Record, K. J. Kreutz, Paul Andrew Mayewski, I. I. Pittalwala, L. D. Meeker, M. S. Twickler, S. I. Whitlow

Earth Science Faculty Scholarship

Using European Center for Medium-Range Weather Forecasts (ECMWF) numerical operational analyses, sea ice extent records, and station pressure data, we investigate the influence of sea level pressure variability in the Amundsen Sea region on a West Antarctic (Siple Dome) glaciochemical record. Empirical orthogonal function analysis of the high-resolution Siple Dome multivariate ice core chemical time series record (SDEOF1) documents lower tropospheric transport of sea-salt aerosols to the site. During 1985–1994 the SDEOF1 record of high (low) aerosol transport corresponds to anomalously low (high) sea level pressure (SLP) in the Amundsen Sea region. Spatial correlation patterns between ECMWF monthly SLP fields …

Monsoon And Dust Signals Recorded In Dasuopu Glacier, Tibetan Plateau, Kang Shichang, Cameron P. Wake, Qin Dahe, Paul Andrew Mayewski, Yao Tandong

Earth Science Faculty Scholarship

During summer 1997, a 15m firn core was recovered from Dasuopu glacier (28°23'N, 85° 44' E; 7000 m a.s.l.) on the northwest margin of Xixabangma Feng in the central Himalaya. Oxygen isotope values and concentrations of Ca²⁺, Mg²⁺, NH₄⁺, SO₄^2- and NO₃^- were measured over the 10 years of snow accumulation captured in the firn core. The seasonal variations of δ¹⁸O values and major-ion concentrations in the Dasuopu core indicated that summer monsoon and dust signals are clearly recorded in Dasuopu glacier. Annual variations in the δ …

Maximum Temperature Trends In The Himalaya And Its Vicinity: An Analysis Based On Temperature Records From Nepal For The Period 1971-94, Arun B. Shrestha, Camerson P. Wake, Paul Andrew Mayewski, Jack E. Dibb

Earth Science Faculty Scholarship

Analyses of maximum temperature data from 49 stations in Nepal for the period 1971-94 reveal warming trends after 1977 ranging from 0.06° to 0.12°C yr¹ in most of the Middle Mountain and Himalayan regions, while the Siwalik and Terai (southern plains) regions show warming trends less than 0.03°C yr¹. The subset of records (14 stations) extending back to the early 1960s suggests that the recent warming trends were preceded by similar widespread cooling trends. Distributions of seasonal and annual temperature trends show high rates of warming in the high-elevation regions of the country (Middle Mountains and Himalaya), …

Antarctic's Role Pursued In Global Climate Change, Paul Andrew Mayewski, I. Goodwin

Earth Science Faculty Scholarship

The impact of Antarctica on global climate change and the impact of global climate change on Antarctica are the focal points of a current series of expeditions there, and an international, interdisciplinary array of researchers met this past spring to go over the expeditions' progress. Advances were reported in describing the impact of the seasonal cycle, semiannual oscillation, and the El Niño-Southern Oscillation (ENSO) cycle on Antarctic accumulation in recent decades.

Difficulties still remain, however, in explaining fully the history and forcing of the Antarctic climate and the links between tropical forcing and high-latitude response. The difficulties arise largely because …

Spatial Variability Of Climate And Past Atmospheric Circulation Patterns From Central West Antarctic Glaciochemistry, David B. Reusch, Paul Andrew Mayewski, Sallie I. Whitlow, Iqbal I. Pittalawa, Mark S. Twickler

Earth Science Faculty Scholarship

Atmospheric circulation patterns and the spatial variability of atmospheric chemistry and moisture transport in central West Antarctica are investigated using new 40 year long (1954–1994 A.D.) glaciochemical and accumulation rate records developed from four firn cores from this region. The core sites lie on a 200 km traverse from 82° 22′ S, 119° 17′ W to 81° 22′ S, 107° 17′ W. The glaciochemical records represent the major ionic species present in Antarctic snow: Na⁺, K⁺, Mg²⁺, Ca²⁺, Cl⁻, NO₃⁻, and SO₄²⁻. High spatial …

The Weddell Sea Region: An Important Precipitation Channel To The Interior Of The Antarctic Ice Sheet As Revealed By Glaciochemical Investigation Of Surface Snow Along The Longest Trans-Antarctic Route, Qin Dahe, Paul Andrew Mayewski, Ren Jiawen, Xiao Cunde, Sun Junying

Earth Science Faculty Scholarship

Glaciochemical analysis of surface snow samples, collected along a profile crossing the Antarctic ice sheet from the Larsen Ice Shelf, Antarctic Peninsula, via the Antarctic Plateau through South Pole, Vostok and Komsomolskaya to Mirny station (at the east margin of East Antarctica), shows that the Weddell Sea region is an important channel for air masses to the high plateau of the Antarctic ice sheet (>2000 m a.s.l.). This opinion is supported by the following. (1) The fluxes of sea-salt ions such as Na⁺, Mg²⁺ and Cl⁻ display a decreasing trend from the west to the …

Seasonal Variations Of Glaciochemical, Isotopic And Stratigraphic Properties In Siple Dome (Antarctica) Surface Snow, K. J. Kreutz, Paul Andrew Mayewski, M. S. Twickler, S. I. Whitlow, J. W.C. White, C. A. Shuman, C. F. Raymond, H. Conway, J. R. Mcconnell

Earth Science Faculty Scholarship

Six snow-pit records recovered from Siple Dome, West Antarctica, during 1994 are used to study seasonal variations in chemical (major ion and H2O2), isotopic (deuterium) and physical stratigraphic properties during the 1988-94 period. Comparison of dD measurements and satellite-derived brightness temperature for the Siple Dome area suggests that most seasonal dD maxima occur within ±4 weeks of each 1 January. Several other chemical species (H2O2, non-sea-salt (nss) SO42-, methanesulfonic acid and NO3-) show coeval peaks with dD, together providing an accurate method for identifying summer accumulation. Sea-salt-derived species generally peak during winter/spring, but episodic input is noted throughout some years. …

Climatological Significance Of Δ18O In Precipitation And Ice Cores: A Case Study At The Head Of The Ürütnqi River, Tien Shan, China, Hou Shugui, Qin Dahe, Paul Andrew Mayewski, Yang Qinzhao, Ren Jiawen, Li Zhongqin, Xiao Cunde

Earth Science Faculty Scholarship

Stable-oxygen-isotope ratios (δ¹⁸O) collected from the headwaters of the Ürümqi river, Tien Shan, China, were used to test the relationship between δ¹⁸O temporal relationship is found between δ¹⁸O monthly averages which remove synoptic-scale influences such as changes in condensation level, condensation temperature and moisture sources (Yao and others, 1996). Linear fits as high as 0.95‰°C^-1 for precipitation events and 1.23‰°C^-1 for monthly averages are found. Although the δ¹⁸O (∼2 km from the precipitation sampling site) decreased dramatically compared to the precipitation samples , the ice-core records of annually averaged δ …

Soluble Species In Aerosol And Snow And Their Relationship At Glacier 1, Tien Shan, China, Junying Sun, Dahe Qin, Paul Andrew Mayewski, Jack E. Dibb, Sallie Whitlow, Zhongqin Li, Qinzhao Yang

Earth Science Faculty Scholarship

Simultaneous sampling of aerosol (n = 20) and snow (n = 114) was made at Glacier 1, Tien Shan, between May 19 and June 29, 1996. Similar temporal patterns of some major ion (calcium, magnesium, potassium, sodium, chloride, and sulfate) concentrations between snow and aerosol show that snow chemistry basically reflects changes in the chemistry of the atmosphere. This gives us confidence in the reconstruction of past atmospheric change using some snow data. There are no significant correlations between aerosol and snow samples for ammonium and nitrate. This suggests that postdepositional and/or postcollection processes may alter ammonium and …

Limited Migration Of Soluble Ionic Species In A Siple Dome, Antarctica, Ice Core, Karl J. Kreutz, Paul Andrew Mayewski, Sallie I. Whitlow, Mark S. Twickler

Earth Science Faculty Scholarship

High-resolution (>10 samples a ^-1) glaciochemical analyses covering the last 110 years from a Siple Dome, Antarctica, ice core reveal limited migration of certain soluble ionic species (methane sulfonic acid, NO₃ and Mg²⁺). Th e observed chemical migration m ay be due in part to seasonal alternation between less acidic winter (from high sea-salt concentrations) and m ore acidic summer (from high marine biogenic acid concentrations) layers, common at coastal sites such as Siple Dome. Exact mechanisms to explain the migration are unclear, although simple diffusion and gravitational movement are unlikely since new peaks are …

Spatial Variability Of Snow Chemistry In Western Dronning Maud Land, Antarctica, Malin Stenberg, Elisabeth Isaksson, Margareta Hansson, Wibjörn Karlén, Paul Andrew Mayewski, Mark S. Twickler, Sallie I. Whitlow, Niels Gundestrup

Earth Science Faculty Scholarship

During the austral summer of 1993-94 a number of 1-2 m deep snow pits were sampled in connection with firn-coring in western Dronning Maud Land, Antarctica. The traverse went from 800 to about 3000 m a.s.l. upon the high-altitude plateau. Profiles of cations (Na⁺, K⁺, Mg²⁺, Ca²⁺), anions (CI^-, NO^3-, SO₄^2-, CH₃SO₃^-) and stable oxygen isotopes (δ¹⁸O) from II snow pits are presented here. Close to the coast 2 m of snow accumulates in about 2-3 years, whilst …

Assessment Of The Record Of The 1982 El Chichón Eruption As Preserved In Greenland Snow, Gregory A. Zielinski, Jack E. Dibb, Qinzhao Yang, Paul Andrew Mayewski, Sallie Whitlow, Mark S. Twickler, Mark S. Germani

Earth Science Faculty Scholarship

Variability in the SO 4 2 - and Cl⁻ time series for the 1980s from 12 shallow snow pits across the Greenland ice sheet is used to evaluate the record of the 1982 El Chichón eruption and the potential for recording a moderate northern equatorial eruption in a single Greenland ice core. Composition of volcanic glass found in spring 1983 snow in one of the pits in the Summit region matches that from El Chichón glass, thereby verifying the deposition of material from the eruption. High Na⁺ and Cl⁻ concentrations in this same layer probably represent deposition …