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Stable isotopes

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Full-Text Articles in Physical Sciences and Mathematics

Determining Spatial Controls On Snow Isotopic Signature And Tracing The Snowmelt Pulse As It Moves Through Two Montane Catchments, Jenna K. Rolle Jan 2022

Determining Spatial Controls On Snow Isotopic Signature And Tracing The Snowmelt Pulse As It Moves Through Two Montane Catchments, Jenna K. Rolle

Graduate Student Theses, Dissertations, & Professional Papers

In this study, we investigate the spatial and temporal distribution of stable isotopes of oxygen and hydrogen in water across two mountainous catchments in west-central Montana to trace the input of snow to local soil, bedrock aquifers, and streams. Snowpack and snowmelt samples were collected throughout the winter season at ten sites selected to encompass a range of elevation, aspect, slope angle and hillslope position. Soil and bedrock wells at five of the ten sites were sampled after the initial snowmelt pulse and stream samples were collected weekly at the outlets of both catchments to trace the timing and partitioning …


Spatiotemporal Variability Of Soil Water Δ18o And Δ2h Reveals Hydrological Processes In Two Floodplain Soils, Amanda Ceming-Barbato Sep 2021

Spatiotemporal Variability Of Soil Water Δ18o And Δ2h Reveals Hydrological Processes In Two Floodplain Soils, Amanda Ceming-Barbato

LSU Master's Theses

The movement of water through soil is preferential and heterogeneous. Subsurface interactions between mobile flows and the soil matrix are not uniform and are therefore difficult to predict through time and space. The use of stable isotopes of hydrogen (2H) and oxygen (18O) as conservative tracers of water movement is improving understanding of soil hydrological processes, yet field-scale observations of isotopic variability remain scarce despite implications for identifying dominant hydrologic processes. We sampled two adjacent soils at a ridge-swale topography floodplain forest to determine soil water isotopic variability at a 20 cm depth resolution in soils …


A Study Of Stable Isotopes In Snow On Mt. Hood, Oregon, Maya Felix Jun 2021

A Study Of Stable Isotopes In Snow On Mt. Hood, Oregon, Maya Felix

University Honors Theses

Over the 2020-2021 Winter, event-based and end-of-season snow samples were collected on Mt. Hood near Government Camp, OR and analyzed for their stable isotopic compositions of 18O and 2H. It was found that surficial snow collected through the winter had higher variation in isotopic values than samples from a snow pit collected in spring. This suggests homogenization occurred in the snowpack over the season from snow metamorphism, sublimation, and/or melting. Homogenization of the snowpack will likely become more pronounced as temperatures increase and rain falls more often than snow due to climate change. Research that utilizes the snowpack …


Stable Isotopes Of Water Reveal Differences In Plant – Soil Water Relationships Across Northern Environments, Matthew J. Kohn, James P. Mcnamara Jan 2021

Stable Isotopes Of Water Reveal Differences In Plant – Soil Water Relationships Across Northern Environments, Matthew J. Kohn, James P. Mcnamara

Geosciences Faculty Publications and Presentations

We compared stable isotopes of water in plant stem (xylem) water and soil collected over a complete growing season from five well‐known long‐term study sites in northern/cold regions. These spanned a decreasing temperature gradient from Bruntland Burn (Scotland), Dorset (Canadian Shield), Dry Creek (USA), Krycklan (Sweden), to Wolf Creek (northern Canada). Xylem water was isotopically depleted compared to soil waters, most notably for deuterium. The degree to which potential soil water sources could explain the isotopic composition of xylem water was assessed quantitatively using overlapping polygons to enclose respective data sets when plotted in dual isotope space. At most sites …


Agricultural Irrigation Induced Evaporation In A Temperate Study Area: A Stable Isotope Approach, Lincoln Grevengoed Dec 2020

Agricultural Irrigation Induced Evaporation In A Temperate Study Area: A Stable Isotope Approach, Lincoln Grevengoed

Masters Theses

In regions where groundwater is used for irrigation, significant water losses take place due to evaporation. Previous studies demonstrated the utility of stable oxygen and hydrogen isotopes in estimating evaporative water loss experienced during return flow back to an aquifer. Unlike arid regions where the other studies took place, this study examined the region around Kalamazoo, Michigan, the United States, which experiences a more temperate climate. Irrigation in the Kalamazoo area primarily uses center-pivot systems supplied by wells, unlike flood irrigation in previous study areas. Water samples were taken periodically from wells close to center-pivot irrigation systems. Water losses due …


Characterization Of Shallow Subsurface Hydrology In Large Fine-Grained Floodplains, Mary Grace Lemon Jul 2020

Characterization Of Shallow Subsurface Hydrology In Large Fine-Grained Floodplains, Mary Grace Lemon

LSU Doctoral Dissertations

Floodplains are hydrologically dynamic, receiving water from overbank events, hyporheic flows, local precipitation, and regional groundwater sources. These sources are variously important contributors to the heterogeneous floodplain water pool that includes matrix water in soil micropores, mobile water in soil macropores, groundwater below the rooting zone, ephemeral to seasonal surface storage, and permanent surface water features such as oxbow lakes, sloughs, and other secondary channels. All sources may be ecologically relevant for floodplain vegetation, but the exact roles of each source in both controlling soil water and shallow groundwater recharge and in controlling floodplain water drainage are not well understood, …


An Investigation And Comparison Of Stable Isotopes In Meteoric Waters And Groundwaters From Southern Washington, Emily E. Smoot Jun 2020

An Investigation And Comparison Of Stable Isotopes In Meteoric Waters And Groundwaters From Southern Washington, Emily E. Smoot

University Honors Theses

A main source of freshwater in the Pacific Northwest is the Columbia River Basalt Group aquifer system. The semi-arid region of eastern Washington has undergone heavy groundwater depletion in recent decades due to increasing population and expanding agricultural use. Aggressive mining has resulted in drawdowns of up to 30 meters. By using stable isotopes oxygen-eighteen (18O) and deuterium (D), this study confines the timing of groundwater precipitation and proposes an explanation for why drawdowns are so significant. The isotopic composition of meteoric water is compared to groundwaters from southeast Washington. The two populations are statistically different (p < 0.001, alpha = 0.05). The isotopic composition of groundwaters from the deepest wells (< -150 m msl) are isotopically lighter than meteoric waters and not achievable by recharge under the current climate. These deep groundwaters are interpreted to have precipitated during the Last Glacial Maximum in the late Pleistocene and finished precipitating roughly 5 ka. Thus, replenishment of the aquifer cannot be expected to keep pace with extraction. Additionally, this research examines the elevation response in the stable isotope signature of meteoric water along the 47° N latitude by computing three lapse rates for 18 …


Water Sourcing Strategies Of Highly Resilient Vegetation In Desert Soils: Stable Isotope Analysis Of A Northern Chihuahuan Desert Ecosystem, Hayden Eleanor Thompson Jan 2020

Water Sourcing Strategies Of Highly Resilient Vegetation In Desert Soils: Stable Isotope Analysis Of A Northern Chihuahuan Desert Ecosystem, Hayden Eleanor Thompson

Open Access Theses & Dissertations

Plant water use strategies and water transport dynamics are important for understanding ecosystem productivity and soil-vegetation-atmosphere interactions within an environment (Li et al., 2007). Recent research using stable isotope analysis in wet and humid climates has found that vegetation uses tightly particle-bound water stored in the soil that does not participate in translatory flow (Brooks et al., 2010; Goldsmith et al., 2011; McDonnell 2014). In arid and semi-arid deserts of the United States, highly resilient vegetation, such as the Honey Mesquite (Prosopis glandulosa) and the Creosote shrub (Larrea tridentata), exhibit some degree of activity year-round despite limited water availability during …


Age-Specific And Species-Specific Tree Response To Seasonal Drought In Tropical Dry Forests, Emily A. Santos Jan 2020

Age-Specific And Species-Specific Tree Response To Seasonal Drought In Tropical Dry Forests, Emily A. Santos

Cal Poly Humboldt theses and projects

Millions of people live in or depend on ecoregions dominated by Tropical Dry Forests (TDFs), but due to their high accessibility, convenient topography and mild climate conditions their distribution is fragmented with less than 10% of their original extent remaining in many countries. Despite the vast ecosystem services provided by TDFs, including vital water resources in water limited environments, ecohydrological research in this biome has been limited to a small number of short-term investigations. Similar to worldwide trends, the TDF surrounding Bahía de Caráquez (Bahía), Ecuador, has been severely deforested over the past 400 years. The land use history in …


Spatial And Temporal Mapping Of Distributed Precipitation, Surface And Groundwater Stable Isotopes Enables Insights Into Hydrologic Processes Operating At A Catchment Scale, Alison Cole Oct 2019

Spatial And Temporal Mapping Of Distributed Precipitation, Surface And Groundwater Stable Isotopes Enables Insights Into Hydrologic Processes Operating At A Catchment Scale, Alison Cole

Masters Theses

Isotopic analyses of d18O and d2H of water through the hydrologic cycle have allowed hydrologists to make better interpretations related to climate and relationships between precipitation, surface water, and groundwater. In this study 394 precipitation samples 1917 surface water samples and 1405 groundwater samples across Massachusetts was used to create an isoscape for each respective water. All samples have been collected by volunteers throughout Massachusetts. A state meteoric water line: d2H = 7.7*d18O + 9.8, surface water line: d2H = 5.7*d18O – 4.2, and groundwater line: d2 …


Estimating Watershed Residence Times In Artificially-Drained Landscapes And Relation To Nutrient Concentrations, Emma Beck, Lisa Welp, Alexandra L. Meyer Aug 2018

Estimating Watershed Residence Times In Artificially-Drained Landscapes And Relation To Nutrient Concentrations, Emma Beck, Lisa Welp, Alexandra L. Meyer

The Summer Undergraduate Research Fellowship (SURF) Symposium

Nutrient runoff from agricultural lands feeds harmful algae blooms that create a variety of problems in freshwater ecosystems. In order to reduce the effects of this nutrient runoff, Best Management Practices (BMPs) are being put in place in agricultural lands. Most of these BMPs focus on slowing down the flow of water through the watershed to give nutrient concentrations time to deplete before the water flows to the stream or river. However, the effectiveness of these BMPs are highly unknown and the process of monitoring nutrient runoff is often complex and costly. The data in this study consists of 7 …


The Role Of Logmat Biofilm In The Spirit Lake Ecosystem After The Eruption Of Mt. St. Helens, Emma Sevier Jan 2018

The Role Of Logmat Biofilm In The Spirit Lake Ecosystem After The Eruption Of Mt. St. Helens, Emma Sevier

Summer Research

Spirit Lake, on the flanks of Mount St. Helens, was dramatically altered as a result of the eruption in 1980, and over the past 37 years the lake ecosystem has recovered in a rapidly evolving volcanic landscape. While Spirit Lake is similar in many ways to other alpine oligotrophic lakes, it is unique because approximately 20% of the lake’s surface remains covered with floating log mats from trees felled during the eruption. The undersides of the logs provide a substrate for biofilm (periphyton) that is primarily comprised of algae, diatoms, and cyanobacteria. Due to the sheer amount of log-based surface …


Hydrologic And Chemical Interaction Between Waste Dumps And A Flooded Mine Pool At The Combination Mine, Philipsburg District, Montana, Corey Swisher Apr 2017

Hydrologic And Chemical Interaction Between Waste Dumps And A Flooded Mine Pool At The Combination Mine, Philipsburg District, Montana, Corey Swisher

Graduate Theses & Non-Theses

The Combination Mine, located approximately 12 miles northwest of Philipsburg Montana, was intermittently mined for silver, gold, and copper from 1885 until the 1990s. After the Combination Mine was formally abandoned groundwater seeps downgradient of the mine and waste rock pile were found to be above the regulatory water quality standards. Since the groundwater seeps were downgradient of both the mine pool and waste rock pile the source of the groundwater seeps could have been from the mine pool or shallow flow paths through the waste rock pile. In order to properly plan and execute a remedial action on the …


Petrographical And Geochemical Changes In Bosnian Stalagmites And Their Palaeo-Environmental Significance, Veronica Chiarini, Isabelle Couchoud, Russell Drysdale, Petra Bajo, Simone Milanolo, Silvia Frisia, Alan Greig, John Hellstrom, Jo De Waele Jan 2017

Petrographical And Geochemical Changes In Bosnian Stalagmites And Their Palaeo-Environmental Significance, Veronica Chiarini, Isabelle Couchoud, Russell Drysdale, Petra Bajo, Simone Milanolo, Silvia Frisia, Alan Greig, John Hellstrom, Jo De Waele

International Journal of Speleology

Detailed petrographic observations have been coupled with trace element and δ13C - δ18O analyses in order to investigate their dynamics in two Holocene Bosnian speleothems. The potential of this multiproxy approach in providing a means to extract palaeo-environmental information from stalagmites whose stable isotope signals are noisy and without obvious trends has been tested. The studied stalagmites are mostly characterized by columnar microcrystalline fabric. At the sub-millimetre scale of lamination, different microcrystalline columnar sub-types (open and closed) have been detected and classified on the basis of the observed porosity and the crystallite size. The presence of …


Geochemical Attributes Of Hydraulically Active Fractures And Their Influence On Groundwater Quality, Amy L. Hudson Jul 2016

Geochemical Attributes Of Hydraulically Active Fractures And Their Influence On Groundwater Quality, Amy L. Hudson

Doctoral Dissertations

This study utilized discrete interval diffusion sampling of a fractured bedrock well completed in schist to investigate if a natural weathering signal can be used to identify hydraulically active fractures. The open borehole well MFS-1, is the focus of the study, which is in close proximity to the recharge zone making it ideal for testing the hypotheses of this study. The hydraulically active fractures of Well MFS-1 were identified, and the dominant mixing force of the water column of the well was determined to be thermal convection in the upper portion of the well and upward gradients. The isotopic data …


Using Stable Isotope Hydrology To Partition Evapotranspiration In The Sagebrush Steppe, Kellie Jo Rey May 2016

Using Stable Isotope Hydrology To Partition Evapotranspiration In The Sagebrush Steppe, Kellie Jo Rey

Boise State University Theses and Dissertations

Evapotranspiration (ET) is a major part of ecosystem water loss. This thesis aims to develop methods that partition soil water loss into evaporation (E) and transpiration (T). Water balance methods may improve with relative contributions of evaporation (E) and transpiration (T). Isotopic fractionation distinguishes soil water loss due to evaporation from that of plant uptake. This provides a means to assess E and T in retrospect rather than only measuring ET fluxes. To measure the isotopic composition of soil water, we used a liquid-vapor equilibration method following Wassenaar (2008). Experimental trials of different soil amounts and equilibration times were performed …


Pore Water Extraction For Unsaturated Zone Isotope Research: An Investigation Using An Immiscible Displacement Fluid And A Centrifuge, Caitlin Burnett Weaver May 2014

Pore Water Extraction For Unsaturated Zone Isotope Research: An Investigation Using An Immiscible Displacement Fluid And A Centrifuge, Caitlin Burnett Weaver

Department of Earth and Atmospheric Sciences: Dissertations, Theses, and Student Research

Accurate and reliable pore water extraction techniques are important to an array of scientific fields including, but not limited to, hydrogeology, soil science, and paleoenvironmental research. The aim of the current project is to test the applicability of an immiscible displacement extraction technique for stable isotopes of water under a range of textural, hydrologic, and chemical conditions. In this study, laboratory experiments were conducted to establish the extent to which the proposed method 1) achieves sufficient yield for laboratory isotopic analyses, 2) results in isotopic exchange between water and the displacement fluid, 3) conserves initial isotopic compositions of spike test …


Isotopic Fingerprinting Of Shallow And Deep Groundwaters In Southwestern Ontario And Its Applications To Abandoned Well Remediation, Mitchell E. Skuce Mar 2014

Isotopic Fingerprinting Of Shallow And Deep Groundwaters In Southwestern Ontario And Its Applications To Abandoned Well Remediation, Mitchell E. Skuce

Electronic Thesis and Dissertation Repository

Abandoned hydrocarbon wells in southwestern Ontario can act as conduits for Sulphur water, brines, and hydrocarbons from deep Paleozoic bedrock aquifers. Such leakage may pose a threat to shallow groundwater and the environment. Cost-effective plugging of these wells requires knowledge of the sources of the leaking fluids. This study characterizes the isotopic compositions (δ18OH2O, δ2HH2O, δ34SSO4, δ18OSO4, δ13CDIC, 87Sr/86Sr) of groundwaters in the region, which are distinct in different bedrock formations. A Bayesian mixing model was applied to these data to develop a tool for identifying the source(s) of leaking fluids. The geochemical data also improve our understanding of groundwater …


A Combined Radio- And Stable-Isotopic Study Of A California Coastal Aquifer System, Peter W. Swarzenski, Mark Baskaran, Robert J. Rosenbauer, Brian D. Edwards, Michael Land Apr 2013

A Combined Radio- And Stable-Isotopic Study Of A California Coastal Aquifer System, Peter W. Swarzenski, Mark Baskaran, Robert J. Rosenbauer, Brian D. Edwards, Michael Land

Environmental Science and Geology Faculty Research Publications

Stable and radioactive tracers were utilized in concert to characterize geochemical processes in a complex coastal groundwater system and to provide constraints on the kinetics of rock/water interactions. Groundwater samples from wells within the Dominguez Gap region of Los Angeles County, California were analyzed for a suite of major cations (Na+, K+, Mg2+, Ca2+) and anions (Cl, SO42−), silica, alkalinity, select trace elements (Ba, B, Sr), dissolved oxygen, stable isotopes of hydrogen (δD), oxygen (δ18O), dissolved inorganic carbon (δ13CDIC), and radioactive …


Evaluating Recharge And Dynamics Of Flow In The Lower Virgin River Basin, Usa: Interpretation Of Hydrochemical And Stable Isotopic Data, Joseph Asante May 2012

Evaluating Recharge And Dynamics Of Flow In The Lower Virgin River Basin, Usa: Interpretation Of Hydrochemical And Stable Isotopic Data, Joseph Asante

UNLV Theses, Dissertations, Professional Papers, and Capstones

Because of the complex geologic setting of the Basin and Range province, groundwater flow systems of the Intermountain basins of the southwestern United States are complex and remain poorly understood. Understanding these flow systems is important for water budgeting on a regional and local scale, and development of robust numerical groundwater models for sustainable water use and protection of water-dependent ecosystems. Although for decades hydrochemistry and isotopes have been used to characterize and trace subsurface water and surface water, effectively interpreting these data are still challenging, which can be attributed to existing subjective grouping of these data and the lack …


Fate Of Stable Isotope Label During Predation Of 15N-Tagged Wild-Type Escherichia Coli By Protozoa, Ashley M. Barton Jan 2011

Fate Of Stable Isotope Label During Predation Of 15N-Tagged Wild-Type Escherichia Coli By Protozoa, Ashley M. Barton

University of Kentucky Master's Theses

Currently, bacterial movement in karst aquifers is not well understood. Use of stable isotopes to label non-pathogenic Escherichia coli as a particulate groundwater tracer in karst systems has been examined in previous studies. Loss of the stable isotope signal is anticipated in traces greater than 500 m in length. Potential loss of 15N due to predation by protozoa was examined. Filter-sterilized water from Royal Spring in Georgetown, Kentucky, was inoculated with a mixture of either Tetrahymena pyriformis or Colpoda steinii and 15N-enriched E. coli and stored in the dark at 14°C. Samples were analyzed for their nitrogen isotope …