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Full-Text Articles in Physical Sciences and Mathematics

Dissolution Of Entrapped Dnapls In Variable Aperture Fractures: Experimental Data And Empirical Model, Sarah E. Dickson, Neil R. Thomson Jan 2003

Dissolution Of Entrapped Dnapls In Variable Aperture Fractures: Experimental Data And Empirical Model, Sarah E. Dickson, Neil R. Thomson

Sarah E Dickson

An appreciation of the dissolution from entrapped nonaqueous phase liquids (NAPLs) in fractures is essential as we attempt to understand and predict the fate of NAPLs present in fractured rock systems. Eight long-term dissolution experiments using 1,1,1-trichloroethane and trichloroethylene were conducted in two laboratory-scale dolomitic limestone variable aperture fractures under various conditions. Between 560 and 2600 fracture volumes of water were passed through the fractures resulting in the removal of 10−60% of the initial mass trapped. The effluent concentration profiles revealed three distinct and characteristic stages of dissolution:  an initial pseudosteady stage, a transient stage, and a tailing stage. On …


Preliminary Investigations Of Seasonal Changes In The Geochemical Evolution Of The Logdson River, Mammoth Cave, Kentucky, Chris Groves, Darlene M. Anthony, Joe Meiman Jan 2003

Preliminary Investigations Of Seasonal Changes In The Geochemical Evolution Of The Logdson River, Mammoth Cave, Kentucky, Chris Groves, Darlene M. Anthony, Joe Meiman

Chris Groves

Many geochemical studies have been made of karst waters worldwide. Most data that provide the framework for our current understanding of the evolution of karst waters have come from sampling at discrete times and locations, such as springs or wells. Relatively few studies have been made of the geochemical evolution of groundwater as it moves through an open flow system. This paper addresses the seasonal changes in the geochemistry of the Logsdon River conduit as it passes through nearly 10km of the carbonate aquifer of south-central Kentucky . The most important control on the ability of groundwaters to dissolve limestone …


Could Mammoth Cave Be Reduced To A Single Equation?, Chris Groves, Joe Meiman Jan 2003

Could Mammoth Cave Be Reduced To A Single Equation?, Chris Groves, Joe Meiman

Chris Groves

Since the evolution of any cave system is largely deterministic, in theory the processes responsible for this development could be described mathematically. In a practical sense, we will never have such a model to realistically describe the evolution of the Mammoth Cave System in detail. However, the search itself can provide a framework within which to understand what processes areimportant. This can guide the design of rate process studies that would eventually be coupled to provide a comprehensive understanding of the cave's evolution. Data gaps, as well, are identified during this process. The geometry of a cave system depends on …