Physical Sciences and Mathematics Commons^™

Development Of Membrane Film Fiber Optic Based Sensors For The Remote Monitoring Of The Quality Of Surface And Groundwater, Leonidas G. Bachas

KWRRI Research Reports

The objective of this study was the development of chromo- and fluoroionophores and their subsequent use in sensors capable of surface and groundwater monitoring. Several reagents (modified crown ethers and porphyrins) were synthesized based on principles of chemical recognition and used for metal and pH sensing. The modified crown ether reagents include a chromogenic or fluorogenic group. The selectivity of these reagents is controlled by the size of the crown ether ring and the type of the chromogenic or fluorogenic side-arm. In addition, a fluorogenic crown ether was synthesized that incorporates a fluorogenic side-arm and a perfluorinated carbon chain. The …

Analysis Of Unsteady Flow Toward Artesian Wells By Three-Dimensional Finite Elements, Yang H. Huang, Shen-Jyh Wu

KWRRI Research Reports

A three-dimensional finite element computer program was developed for analyzing unsteady flow toward artesian wells. The program is designed especially for determining the drawdown around an artesian well penetrating fully or partially a nonhomogeneous and anisotropic aquifer of irregular shape and cross section. It can also be used as a general program for aquifer simulation and evaluation. A major advantage of the program lies in the minimum amount of input data required. By assuming the top and bottom boundaries of the aquifer as two arbitrary planes, the aquifer will be divided into six- or eight-node elements, and their nodal coordinates …

Solution Geochemistry Of The Water Of Limestone Terrains, John Thrailkill, David B. Beiter, Michael T. Osolnik, Roger H. Postley, William T. Mitchell, Leonard N. Plummer, James R. Riddell, Richard C. Worley, Robert D. Zwicker

KWRRI Research Reports

Limestone groundwater flows mainly in openings it has solutionally enlarged, thus an understanding of the water's state of saturation relative to calcite (the principal mineral component of limestone) is fundamental to an understanding of the nature and evolution of the limestone aquifer. This study investigated the Mammoth Cave-Sinkhole Plain (MCSP) and Cave Hollow (CH) aquifers in Kentucky, both in Missippian limestones.

Both aquifers were always undersaturated with calcite. Except for completely ventilated vadose flows (usually) and some vadose seepage (occasionally), all recharges sampled (sinking streams, vadose flows, and vadose seepage) were also undersaturated. The lack of saturation in the MCSP …