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Full-Text Articles in Physical Sciences and Mathematics

Dispersion Of Artificial Tracers In Ventilated Caves, Claudio Pastore, Eric Weber, Frédéric Doumenc, Pierre-Yves Jeannin, Marc Lütscher Apr 2024

Dispersion Of Artificial Tracers In Ventilated Caves, Claudio Pastore, Eric Weber, Frédéric Doumenc, Pierre-Yves Jeannin, Marc Lütscher

International Journal of Speleology

Artificial CO2 was used as a tracer along ventilated karst conduits to infer airflow and investigate tracer dispersion. In the karst vadose zone, cave ventilation is an efficient mode of transport for heat, gases and aerosols and thus drives the spatial distribution of airborne particles. Modelling this airborne transport requires geometrical and physical parameters of the conduit system, including the cross-sectional areas, the airflow and average air speed, as well as the longitudinal dispersion coefficient which describes the spreading of a solute. Four gauging tests were carried out in one mine (artificial conduit) and two ventilated caves (natural conduits). …


Estimating Inorganic Carbon Flux From Coal Mining Discharge Portals In The Bituminous Coal Field Region Of Pennsylvania, Lauren J. Rockwell Jan 2024

Estimating Inorganic Carbon Flux From Coal Mining Discharge Portals In The Bituminous Coal Field Region Of Pennsylvania, Lauren J. Rockwell

Graduate Theses, Dissertations, and Problem Reports

A fundamental driver of the adverse effects associated with coal mining is the interplay of water and oxygen within mined sites, leading to the creation of coal mine drainage (CMD). One often overlooked consequence of CMD is the release of geologically-bound carbon as carbon dioxide (CO2). The interaction of CMD with carbonate rocks, specifically the presence of sulfuric acid driving the dissolution of these rocks, leads to the release of dissolved inorganic carbon (DIC). This study examined 25 CMD locations in an approximately 2,370 km2 area within the bituminous coal field region of Pennsylvania (PA), specifically in …


Volatile Cycling And Metasomatism In Flat-Slab Subduction Zones Of The Central Andes, Coleman Hiett Aug 2023

Volatile Cycling And Metasomatism In Flat-Slab Subduction Zones Of The Central Andes, Coleman Hiett

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Flat-slab subduction, where an oceanic plate subducts horizontally below a continental margin for hundreds of kilometers, is an enigmatic but prevalent tectonic configuration in which chemical cycling and alteration of the continental plate is poorly constrained. Geochemical investigations in regions of modern and ancient flat-slab subduction in the Central Andes afford an opportunity to study this process. Certain elements naturally occur with varying number of neutrons in their nuclei (isotopes), and measurements of isotope ratios within geologic materials inform on chemical sources and geologic processes. This research leverages stable isotope analyses and other geochemical tools to investigate volatiles and other …


Orbital Mapping Of Seasonal And Yearly Changes In Co2 And Water Ice On The Southern Polar Cap Of Mars, Victoria Michell Ann Karnes Dec 2022

Orbital Mapping Of Seasonal And Yearly Changes In Co2 And Water Ice On The Southern Polar Cap Of Mars, Victoria Michell Ann Karnes

Graduate Theses and Dissertations

This research exhibits a new foundation for the rates of change in CO2 and water ice on the southern polar cap of Mars, where the annual precipitation cycles are known to fluctuate seasonally between the north and south pole, based on observations from the Compact Reconnaissance Imaging Spectrometer (CRISM). The conventional belief is that both CO2 ice and water ice on the southern polar cap condenses and evaporates over the course of a Martian year (MY), condensing during the Martian spring and summer and evaporating during the Martian fall and winter. With this theory in mind, CO2 and water ice …


Comparison Of Methods For Estimating Carbon Evasion And Export Associated With A Coal Mine Discharge, Kyle Lee, Dorothy J. Vesper May 2021

Comparison Of Methods For Estimating Carbon Evasion And Export Associated With A Coal Mine Discharge, Kyle Lee, Dorothy J. Vesper

Presentations

The evasion of CO2 from terrestrial waters plays a role in the global cycling of carbon but there are few datasets that have an accurate accounting of the flux. It has been shown that discharges from coal mines can have elevated concentrations of CO2 due to sulfuric acid-driven dissolution of carbonate rock. In this study, we compared three methods for calculating the export dissolved inorganic carbon (DIC) and the evaluation of CO2 from an abandoned-mine discharge in West Virginia. In Method #1, the source flux is calculated from the discharge and the concentrations at the portal. In Method #2, the …


Reservoir Characterization And Static Earth Modeling For Potential Co2 Storage In Upper Pennsylvanian Cyclothems Of Midcontinent, Usa, Valerie Lynn Smith Jan 2020

Reservoir Characterization And Static Earth Modeling For Potential Co2 Storage In Upper Pennsylvanian Cyclothems Of Midcontinent, Usa, Valerie Lynn Smith

Graduate Theses, Dissertations, and Problem Reports

This dissertation details the estimation of CO2 storage volume using reservoir characterization and the building of static earth models in two papers: 1) for Sleepy Hollow Field in Red Willow County, Nebraska and, 2) for Huffstutter Field, Phillips County, Kansas. These models are used to obtain estimates of CO2 storage capacity in stacked carbonate intervals of the Pennsylvanian Lansing and Kansas City groups (LKC). The LKC constitutes a regional succession of interbedded carbonates and shales. Located over the Cambridge Arch of Nebraska, these interbedded units were evaluated for carbon storage potential. Understanding the occurrence of carbonate porosity among …


Co2-Enhanced Gas Recovery In Shale: Lessons Learned In The Devonian Ohio Shale Of Eastern Kentucky, Brandon C. Nuttall Jul 2019

Co2-Enhanced Gas Recovery In Shale: Lessons Learned In The Devonian Ohio Shale Of Eastern Kentucky, Brandon C. Nuttall

Report of Investigations--KGS

The Kentucky Geological Survey tested CO2-enhanced gas recovery in the Devonian shale in Johnson County, in response to a directive from the Kentucky General Assembly in 2007; the study site included a fracture-stimulated shale-gas well. To supplement a standard suite of open-hole logs acquired when the well was drilled, a well-logging program was designed to identify open perforations, construct a flow profile, and acquire pre-injection baseline data to characterize the Devonian Ohio Shale for a pressure falloff test. Tubing and packer were installed, with gel and brine filling the annulus between the tubing and packer to block flow-through …


Hydrocarbon And Co2 Emissions From Oil And Gas Production Well Pad Soils Comparative To Background Soil Emissions In Eastern Utah, Cody S. Watkins May 2017

Hydrocarbon And Co2 Emissions From Oil And Gas Production Well Pad Soils Comparative To Background Soil Emissions In Eastern Utah, Cody S. Watkins

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

What effect does the development of oil and gas have on the observed air quality (i.e., increased ozone, carbon dioxide (CO2), volatile organic compounds (VOCs), and/or methane emissions) in northeastern Utah? What percentage of these gases is natural background emissions, and what percentage is due to the recent oil and gas development in the region? Emissions in this text refer to gases released from the earth’s surface to the atmosphere. Methane is the primary compound in natural gas. Natural gas is a naturally occurring hydrocarbon gas mixture. Emissions of methane, non-methane hydrocarbons (NMHC), and CO2 at 27 …


A Physicochemical Prediction Of Prolonged Natural Co2 Leakage In The Little Grand Wash Fault Zone, Green River, Utah, Kyungdoe Han May 2016

A Physicochemical Prediction Of Prolonged Natural Co2 Leakage In The Little Grand Wash Fault Zone, Green River, Utah, Kyungdoe Han

Theses and Dissertations

Physicochemical investigation on a natural CO2 system and the accommodated fault-controlled fluids using a geochemical modeling method provides important information regarding the security assessment for geological carbon sequestration (GCS), which is the most promising method for enhancing our knowledge of the side effects of GCS. By employing an utilized series of regional fluid chemistry and hydrogeologic parameters, this study investigated the consequences caused by migration of CO2 in a naturally leaking CO2 system that developed in normal faults in the southwestern U.S. 1-D and 2-D models were conducted using the multi-phase, multi-component reactive transport simulator, TOUGHREACT, to establish sets of …


Storing Co2 Deep Underground, Stephen F. Greb Jan 2016

Storing Co2 Deep Underground, Stephen F. Greb

Map and Chart--KGS

No abstract provided.


3-D Numerical Simulation Of Carbon Dioxide Injection Into The South Georgia Rift Basin For Geologic Storage, Daniel Eric Taylor Brantley Jan 2015

3-D Numerical Simulation Of Carbon Dioxide Injection Into The South Georgia Rift Basin For Geologic Storage, Daniel Eric Taylor Brantley

Theses and Dissertations

This study numerically simulated the injection of supercritical phase CO2 into the South Georgia Rift (SGR) basin to evaluate the feasibility and efficacy of long term geologic storage. The injection simulation modeling was divided into two phases. During phase one of the modeling, very little geologic and reservoir dynamics data was known about the SGR basin. Due to lack of basin data, an equilibrium model was used to estimate the initial hydrostatic pressure, temperature and salinity gradients that represent our study area. For the equilibrium model, the USGS SEAWAT program was used and for the CO2 injection simulation, TOUGH2-ECO2N was …


Shallow Groundwater Monitoring Associated With The Deep Saline Reservoir Co2 Storage Test In Hancock County, Kentucky, E. Glynn Beck Jan 2014

Shallow Groundwater Monitoring Associated With The Deep Saline Reservoir Co2 Storage Test In Hancock County, Kentucky, E. Glynn Beck

Report of Investigations--KGS

A carbon dioxide injection test well was drilled in 2009 to a depth of 8,126 ft below ground surface in Hancock County, Kentucky. Six hundred ninety tons of CO2 was successfully injected into Knox Group saline aquifers. Two domestic wells (MB and GB) and two domestic springs (CA and RC) were sampled to monitor any potential changes in groundwater quality associated with possible migration of CO2 from deeper saline aquifers into shallow freshwater aquifers. The four sites were sampled for pH, bicarbonate, total dissolved solids, turbidity, anions, total dissolved metals, dissolved inorganic carbon, total CO2, and …


Seasonal Variations Of Co2 And 222Rn In A Mediterranean Sinkhole - Spring (Causse D’Aumelas, Se France), Christelle Batiot-Guilhe, Jean-Luc Seidel, Hervé Jourde, Olivier Hébrard, Vincent Bailly-Comte Jan 2007

Seasonal Variations Of Co2 And 222Rn In A Mediterranean Sinkhole - Spring (Causse D’Aumelas, Se France), Christelle Batiot-Guilhe, Jean-Luc Seidel, Hervé Jourde, Olivier Hébrard, Vincent Bailly-Comte

International Journal of Speleology

Carbon dioxide and 222Rn monitoring of the atmosphere of a Mediterranean sink hole - spring (SE France) during two hydrological cycles (from September 2004 to September 2006) showed seasonal variations with very high concentrations during summer (greater than 6% and 20 000 Bq/m3, respectively). Gas dynamics in caves often show seasonal variations. Meteorological parameters (barometric pressure and temperature mainly), cave geometry and fracture networks control exchanges between the cavity and outside atmosphere. Carbon dioxide and 222Rn may have different sources (atmosphere, soil, bedrock, deep gas diffusion, in situ oxidation of organic matter and, in some caves, …