Physical Sciences and Mathematics Commons^™

Concentrations And Isotope Ratios Of Dissolved Inorganic Carbon In Denitrifying Environments, C. Nascimento, Eliot A. Atekwana, R. V. Krishnamurthy

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

We measured the concentration and isotope ratio of dissolved inorganic carbon (DIC) in groundwater associated with denitrification (C_org + NO₃^- = CO₂ + N₂) in an agriculturally impacted site in southwestern Michigan. Samples with the lowest nitrate levels also had low dissolved oxygen content and were more depleted in δ¹³C than background groundwater. All the samples had DIC concentrations in excess of titratable alkalinity. The magnitude of this DIC in excess of alkalinity correlated with a decreasing δ¹³C attesting to the presence of CO₂ derived from organic carbon. Carbon …