Physical Sciences and Mathematics Commons^™

Karst Aquifers As Atmospheric Carbon Sinks: An Evolving Global Network Of Research Sites, Chris Groves, Joe Meiman, Joel Despain, Liu Zaihua, Daoxin Yuan

Chris Groves

Karst flow systems formed in carbonate rocks have been recognized as a sink for atmospheric carbon that originates as gaseous carbon dioxide and ends up as dissolved aqueous carbon, primarily as bicarbonate. While measurements of the magnitude of the sink associated with carbonate rock dissolution have assumed that half of the dissolved inorganic carbon leaving a given catchment comes from the mineral and half from the atmosphere, consideration of the kinetics of carbonate mineral dissolution in acid solutions suggests that the ratio is enriched in mineral-source carbon to an extent that depends on the geochemical environment of mineral/fluid contact. After …