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Local Environmental Controls On Sulfur Isotope Ratios In Marine Sedimentary Iron Sulfide Minerals, Roger Nicholas Bryant
Local Environmental Controls On Sulfur Isotope Ratios In Marine Sedimentary Iron Sulfide Minerals, Roger Nicholas Bryant
Arts & Sciences Electronic Theses and Dissertations
The controls on the bulk sulfur isotopic composition of marine sedimentary iron sulfides (often referred to simply as pyrite; δ34Spyr) are poorly understood. Nevertheless, many have employed δ34Spyr in efforts to reconstruct the past operation of the biogeochemical sulfur cycle, from the planetary scale down to individual microbial metabolisms. This practice has been thrown into doubt by a growing body of evidence that suggests δ34Spyr is strongly controlled by local environmental conditions. This dissertation describes efforts to determine the mechanisms responsible for the link between local environmental conditions and δ34Spyr. In order to do this, we developed novel laboratory procedures …