Physical Sciences and Mathematics Commons^™

The Use Of Green Pond Conglomerate As Building Stone In Morris County, New Jersey, Gregory A. Pope

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Green Pond Conglomerate (GPC) is a maroon colored quartzite with white quartz pebbles, a classic “puddingstone”. GPC derives from a NW-SW-trending sliver of Paleozoic sediments, the “Green Pond Outlier”, surrounded by older metamorphic and igneous rocks of Morris and Passaic Counties. Buildings, retaining walls, field fences, and monuments incorporate the durable and attractive stone, in a distinct geographic area of Morris County. Several instances of structures completely constructed or faced with GPC occur in and around Morristown, limited to affluent houses and one prominent church. In these cases, GPC stones were dressed and faced, a labor-intensive effort. Elsewhere in the …

Reconstructing Deep-Ocean Circulation During Cenozoic Climate Transitions From The Marine Sediment Record, Brian Romans

Sustainability Seminar Series

Ocean circulation plays a critical role in the Earth’s climate system through the storage and transfer of heat and carbon dioxide. The North Atlantic and Southern Ocean are of particular interest because these are regions where deep-water components of global circulation develop. Dr. Romans uses the deep-sea sedimentary record to reconstruct past ocean circulation and its relationship to past climatic and tectonic conditions. He integrates information from a broad range of spatial and temporal scales, from seismic-reflection data that reveals regional sedimentation patterns to high resolution records based on quantitative grain-size analysis from cores. Dr. Romans will present research from …

The Boring Millions? Vegetation, Atmospheric Co2 , And Climate Revolutions Of The Late Miocene, Pratigya Polissar

Sustainability Seminar Series

During the late Miocene (11-5 Ma), global ice volume and deep ocean temperatures appear to be relatively unchanging. These “boring millions” suggest stasis of the climate system with the expectation of only moderate global changes in climate, CO2 and vegetation. However, during this time tropical ecosystems underwent profound changes and surface ocean temperatures declined dramatically. When did these changes occur, what drove them, and what role if any did atmospheric carbon dioxide levels play? I will address these questions through new observations of the onset, pace and geographic extent of vegetation transformations and hydrologic changes reconstructed from molecular biomarkers. I …

Potential Economic Impacts Of Allocating More Land For Bioenergy Biomass Production In Virginia, Thomas O. Ochuodho, Janaki Alavalapati, Pankaj Lal, Domena A. Agyeman, Bernabas Wolde, Pralhad Burli

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

The growing attention to renewable energy and rural development has created greater demand for production of biomass feedstock for bioenergy. However, forest growth rates and the amount of land in most existing forests may not be sufficient to sustainably supply the forest biomass required to support existing forest products industries and the expanding bioenergy industry. Additionally, concerns about agricultural land use competition have dampened expansion of biomass production on agricultural land base. One of the ways to meet the growing forest biomass feedstock demand for bioenergy production is by allocating currently marginal non-forested land for growing bioenergy feedstocks. In Virginia, …

The Fate Of Sulfur During Melting And Crystallization: Implications For Sulfur Transfer From Mantle To The Crust-Atmosphere System, Shuo Ding

Sustainability Seminar Series

Sulfur (S) is one of the most abundant volatiles; one that has a fundamental impact on various magmatic processes, from the mantle to the Earth’s surface. Ocean island basalts (OIB) are one of the critical probes for understanding the chemical, lithological and thermal variations in the Earth’s mantle. Therefore, S abundances of primary OIB that sample peridotite partial melts, as well as deeply recycled components, can provide a better understanding of the long-term S cycle on Earth. In this study, we developed a model to describe the behavior of sulfide and copper (Cu) during decompression melting of the mantle by …

A Sedimentological Record Of Early Miocene Ice Advance And Retreat, And-2a Drill Hole, Mcmurdo Sound, Antarctica, B. D. Field, G. H. Browne, Christopher R. Fielding, Fabio Florindo, David M. Harwood, Shelley Judge, Lawrence Krissek, Kurt S. Panter, Sandra Passchier, Stephen Pekar, Sonia Sandroni, Franco M. Talarico

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

The lowest 501 m (∼1139–638 m) of the AND-2A core from southern McMurdo Sound is the most detailed and complete record of early Miocene sediments in Antarctica and indicates substantial variability in Antarctic ice sheet activity during early Miocene time. There are two main pulses of diamictite accumulation recorded in the core, and three significant intervals with almost no coarse clasts. Each diamictite package comprises several sequences consistent with ice advance-retreat episodes.

The oldest phase of diamictite deposition, Composite Sequence 1 (CS1), has evidence for grounded ice at the drill site and has been dated around 20.2–20.1 Ma. It likely …

Magmatism And Mass Extinction: Resolving The Flood Basalt Carbon Quandary, Benjamin Black

Sustainability Seminar Series

Voluminous flood basalt magmatism has coincided with multiple biotic crises, including the end-Permian, end-Triassic, and end-Cretaceous mass extinctions and the Paleocene-Eocene Thermal Maximum. Geochemical evidence shows that warming and carbon cycle perturbation were features of each of these events. This proxy evidence is at odds with current estimates of the budget and isotopic composition of carbon in flood basalt magmas, which suggest that flood basalt magmatic carbon is inadequate and too isotopically heavy to explain the observations. To address the apparent conflict between paleoclimate and petrology, I present results from melt inclusions, carbonatites, geophysical modeling, and climate modeling to address …

An Antarctic Stratigraphic Record Of Stepwise Ice Growth Through The Eocene-Oligocene Transition, Sandra Passchier, Daniel J. Ciarletta, Triantafilo E. Miriagos, Peter K. Bijl, Steven M. Bohaty

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Earth’s current icehouse phase began ∼34 m.y. ago with the onset of major Antarctic glaciation at the Eocene-Oligocene transition. Changes in ocean circulation and a decline in atmospheric greenhouse gas levels were associated with stepwise cooling and ice growth at southern high latitudes. The Antarctic cryosphere plays a critical role in the ocean-atmosphere system, but its early evolution is still poorly known. With a near-field record from Prydz Bay, Antarctica, we demonstrate that Antarctic ice growth was stepwise and had an earlier onset than previously suggested. Prydz Bay lies downstream of a major East Antarctic Ice Sheet drainage system, and …

Natural And Human-Induced Variability In Barrier-Island Response To Sea Level Rise, Jennifer Miselis, Jorge Lorenzo Trueba

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Storm-driven sediment fluxes onto and behind barrier islands help coastal barrier systems keep pace with sea level rise (SLR). Understanding what controls cross-shore sediment flux magnitudes is critical for making accurate forecasts of barrier response to increased SLR rates. Here, using an existing morphodynamic model for barrier island evolution, observations are used to constrain model parameters and explore potential variability in future barrier behavior. Using modeled drowning outcomes as a proxy for vulnerability to SLR, 0%, 28%, and 100% of the barrier is vulnerable to SLR rates of 4, 7, and 10 mm/yr, respectively. When only overwash fluxes are increased …

Holocene Glacial Activity In Barilari Bay, West Antarctic Peninsula, Tracked By Magnetic Mineral Assemblages: Linking Ice, Ocean, And Atmosphere, Brendan Reilly, Carl Natter, Stefanie A. Brachfeld

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

We investigate the origin and fate of lithogenic sediments using magnetic mineral assemblages in Barilari Bay, west Antarctic Peninsula (AP) from sediment cores recovered during the Larsen Ice Shelf System, Antarctica (LARISSA) NBP10-01 cruise. To quantify and reconstruct Holocene changes in covarying magnetic mineral assemblages, we adopt an unsupervised mathematical unmixing strategy and apply it to measurements of magnetic susceptibility as a function of increasing temperature. Comparisons of the unmixed end-members with magnetic observations of northwestern AP bedrock and the spatial distribution of magnetic mineral assemblages within the fjord, allow us to identify source regions, including signatures for ‘‘inner bay,’’ …

Morphodynamic Modeling Of Fluvial Channel Fill And Avulsion Time Scales During Early Holocene Transgression, As Substantiated By The Incised Valley Stratigraphy Of The Trinity River, Texas, Kaitlin Moran, Jeffrey Nittrouer, Mauricio Perillo, Jorge Lorenzo Trueba, John Anderson

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

The Trinity River system provides a natural laboratory for linking fluvial morphodynamics to stratigraphy produced by sea-level rise, because the sediments occupying the Trinity incised valley are well constrained in terms of timing of deposition and facies distribution. Herein, the Trinity River is modeled for a range of base-level rise rates, avulsion thresholds, and water discharges to explore the effects of backwater-induced in-channel sedimentation on channel avulsion. The findings are compared to observed sediment facies to evaluate the capability of a morphodynamic model to reproduce sediment deposition patterns. Base-level rise produces mobile locations of in-channel sedimentation and deltaic channel avulsions. …

Threshold Behavior Of A Marine‐Based Sector Of The East Antarctic Ice Sheet In Response To Early Pliocene Ocean Warming, Melissa A. Hansen, Sandra Passchier, Boo‐Keun Khim, Buhan Song, Trevor Williams

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

We investigate the stability of the East Antarctic Ice Sheet (EAIS) on the Wilkes Land continental margin, Antarctica, utilizing a high‐resolution record of ice‐rafted debris (IRD) mass accumulation rates (MAR) from Integrated Ocean Drilling Program Site U1359. The relationship between orbital variations in the IRD record and climate drivers was evaluated to capture changes in the dynamics of a marine‐based ice sheet in response to early Pliocene warming. Three IRD MAR excursions were observed and confirmed via scanning electron microscope microtextural analysis of sand grains. Time series analysis of the IRD MAR reveals obliquity‐paced expansions of the ice sheet to …

Anthropogenic Controls On Overwash Deposition: Evidence And Consequences, Laura Rogers, Laura Moore, Evan Goldstein, Christopher Hein, Jorge Lorenzo Trueba, Andrew Ashton

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Accelerated sea level rise and the potential for an increase in frequency of the most intense hurricanes due to climate change threaten the vitality and habitability of barrier islands by lowering their relative elevation and altering frequency of overwash. High-density development may further increase island vulnerability by restricting delivery of overwash to the subaerial island. We analyzed pre-Hurricane Sandy and post-Hurricane Sandy (2012) lidar surveys of the New Jersey coast to assess human influence on barrier overwash, comparing natural environments to two developed environments (commercial and residential) using shore-perpendicular topographic profiles. The volumes of overwash delivered to residential and commercial …

Geology In Environmental Management, Michael A. Kruge

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

From the geological perspective, the two overriding environmental management concerns are the destructive impact of hazardous natural events on human health and property and the deleterious impact of human activity on the natural environment. The knowledge derived from the geological sciences serves as the basis for a more enlightened approach to the reduction of unnecessary risk involved in the siting and construction of buildings and transportation networks, as well as the extraction of natural resources and waste management. Armed with such knowledge along with political sensitivity, environmental managers will have opportunities for positive social impact in negotiating the challenges as …

The Effects Of Changes In Population Density On Discharges For The Midwestern United States, Catherine Konieczny

Theses, Dissertations and Culminating Projects

River baseflow is the river discharge supported predominantly by groundwater, and can be greatly impacted by changes in land. Intuitively, the baseflow of a river would decrease with increased urbanization, as urbanization increases the amount of impervious surfaces, limiting the ability of precipitation to infiltrate into the ground and recharge the local groundwater. However, evidence suggests that the baseflow of rivers in urbanized areas can increase as a result of leaky subsurface water infrastructures that add water to groundwater and replenish baseflow. Another reason for the baseflow increase in urbanized watersheds is that water supply systems are over-pressurized by design …

Orbitally Paced Shifts In The Particle Size Of Antarctic Continental Shelf Sediments In Response To Ice Dynamics During The Miocene Climatic Optimum, Sandra Passchier, Candice J. Falk, Fabio Florindo

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

The AND-2A drill hole (ANDRILL [Antarctic Geological Drilling Program] Southern McMurdo Sound Project), ∼10 km from the East Antarctica coastline, records nearly 6 m.y. of sedimentation across the Miocene climatic optimum at a high-latitude site. Sedimentological studies of bedforms and particle size distributions indicate that the paleoenvironment was strongly affected by waves and currents, consistent with deposition in a glacially influenced neritic environment. We document abrupt shifts in mud percent within glacial-interglacial cycles ca. 17.8 Ma and between ca. 16.7 and 15.7 Ma that we attribute to the hydrodynamic effects of wave stirring tied to episodes of ice growth and …

Early Eocene To Middle Miocene Cooling And Aridification Of East Antarctica, Sandra Passchier, Steven M. Bohaty, Francisco J. Jiménez‐Espejo, Jörg Pross, Ursu Röhl, Tina Van De Flierdt, Carlota Escutia, Henk Brinkhuis

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

[1] Few high‐latitude terrestrial records document the timing and nature of the Cenozoic “Greenhouse” to “Icehouse” transition. Here we exploit the bulk geochemistry of marine siliciclastic sediments from drill cores on Antarctica's continental margin to extract a unique semiquantitative temperature and precipitation record for Eocene to mid‐Miocene (~54–13 Ma). Alkaline elements are strongly enriched in the detrital mineral fraction in fine‐grained siliciclastic marine sediments and only occur as trace metals in the biogenic fraction. Hence, terrestrial climofunctions similar to the chemical index of alteration (CIA) can be applied to the alkaline major element geochemistry of marine sediments on continental margins …

Chemical Contaminants As Stratigraphic Markers For The Anthropocene, Michael A. Kruge

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Thousands and even millions of years from now, widespread anthropogenic contaminants in sediments would likely persist, incorporated into the geological record. They would inadvertently preserve evidence of our present era (informally designated as the Anthropocene Epoch) characterized by large human populations engaged in intensive industrial and agricultural activities.

Hypothetical geologists in the distant future would likely find unusually high concentrations of a wide variety of contaminants at stratigraphic levels corresponding to our present time, analogous to the iridium anomaly marking the bolide impact event at the close of the Cretaceous Period. These would include both organic and inorganic substances, such …

Chronostratigraphic Framework For The Iodp Expedition 318 Cores From The Wilkes Land Margin: Constraints For Paleoceanographic Reconstruction, Lisa Tauxe, Catherine E. Stickley, Saiko Sugisaki, Peter K. Bijl, Steven M. Bohaty, Henk Brinkhuis, Carlota Escutia, J. A. Flores, A. J. P. Houben, M. Iwai, Francisco J. Jiménez‐Espejo, Robert Mckay, Sandra Passchier, Jörg Pross, Christina Riesselman, Ursula Röhl, Francesca Sangiorgi, Kevin Welsh, Adam Klaus, Annick Fehr, James Bendle, Robert B. Dunbar, J. Gonzàlez, T. Hayden, K. Katsuki, M. P. Olney, Stephen Pekar, P. K. Shrivastava, Tina Van De Flierdt, Trevor Williams, M. Yamane

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

[1] The Integrated Ocean Drilling Program Expedition 318 to the Wilkes Land margin of Antarctica recovered a sedimentary succession ranging in age from lower Eocene to the Holocene. Excellent stratigraphic control is key to understanding the timing of paleoceanographic events through critical climate intervals. Drill sites recovered the lower and middle Eocene, nearly the entire Oligocene, the Miocene from about 17 Ma, the entire Pliocene and much of the Pleistocene. The paleomagnetic properties are generally suitable for magnetostratigraphic interpretation, with well‐behaved demagnetization diagrams, uniform distribution of declinations, and a clear separation into two inclination modes. Although the sequences were discontinuously …

Exploring The Role Of Organic Matter Accumulation On Delta Evolution, Jorge Lorenzo Trueba, Vaughan Voller, Chris Paola, Robert Twilley, Azure Bevington

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

We explore the role of plant matter accumulation in the sediment column in determining the response of fluvial-deltas to base-level rise and simple subsidence profiles. Making the assumption that delta building processes operate to preserve the geometry of the delta plain, we model organic sedimentation in terms of the plant matter accumulation and accommodation (space made for sediment deposition) rates. A spatial integration of the organic sedimentation, added to the known river sediment input, leads to a model of delta evolution that estimates the fraction of organic sediments preserved in the delta. The model predicts that the maximum organic fraction …

Linkages Between East Antarctic Ice Sheet Extent And Southern Ocean Temperatures Based On A Pliocene High‐Resolution Record Of Ice‐Rafted Debris Off Prydz Bay, East Antarctica, Sandra Passchier

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

[1] Ice‐rafted debris mass accumulation rates (IRD MAR) at a drill site on the Antarctic continental margin are investigated to evaluate the linkages between East Antarctic Ice Sheet extent and Southern Ocean temperatures in the early to mid‐Pliocene. ODP Site 1165 is within 400 km of the Antarctic coastline and in the direct pathway of icebergs released by the Amery Ice Shelf. The Amery Ice Shelf is the largest ice shelf in East Antarctica and it buttresses the Lambert Glacier drainage system, which accounts for 14% of the outflow from the East Antarctic Ice Sheet. IRD MAR were low during …

Variations In Concentrations And Compositions Of Polycyclic Aromatic Hydrocarbons (Pahs) In Coals Related To The Coal Rank And Origin, Susanne Laumann, Vesna Micic Batka, Michael A. Kruge, Christine Achten, Reinhard Sachsenhofer, Jan Schwarzbauer, Thilo Hofmann

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

The release of unburnt coal particles and associated polycyclic aromatic hydrocarbons (PAHs) may cause adverse impacts on the environment. This study assessed variations in the concentration and composition of PAHs in a set of fifty coal samples from eleven coal basins worldwide. The maximum PAH concentrations at high volatile bituminous rank were recorded in samples from a single basin. Considering the entire sample, the highest PAH concentrations were in fact found outside of this rank range, suggesting that the maceral composition and thus the coal's origin also influenced PAH concentrations. The examination of the PAH compositions revealed that alkylated 2-3 …

Observations Of Sand Waves, Megaripples, And Hummocks In The Dutch Coastal Area And Their Relation To Currents And Combined Flow Conditions, Sandra Passchier, Maarten Kleinhans

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

[1] This paper aims to investigate the distribution and stability of large‐scale bed forms in response to storm and fair‐weather conditions in a shallow marine environment. Multibeam and side‐scan sonar data off the Dutch coast (median grain size 0.25–0.35 mm) were collected to monitor sand waves (λ = 100–800 m) and superimposed megaripples (λ = 1–40 m) through multiple storm and fair‐weather events. Box cores were used to observe the vertical bed structure and grain size. In the Dutch coastal area, two‐dimensional (2‐D) megaripples (λ = 1–15 m) are the dominant bed forms in current‐dominated (>0.4 m/s) tidal flow …

Geomorphology’S Role In The Study Of Weathering Of Cultural Stone, Gregpry A. Pope, Thomas R. Paradise, Thomas Meierding

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Great monumental places—Petra, Giza, Angkor, Stonehenge, Tikal, Macchu Picchu, Rapa Nui, to name a few—are links to our cultural past. They evoke a sense of wonderment for their aesthetic fascination if not for their seeming permanence over both cultural and physical landscapes. However, as with natural landforms, human constructs are subject to weathering and erosion. Indeed, many of our cultural resources suffer from serious deterioration, some natural, some enhanced by human impact. Groups from the United Nations to local civic and tourism assemblies are deeply interested in maintaining and preserving such cultural resources, from simple rock art to great temples. …

Carbon Dynamics In Peat Bogs: Insights From Substrate Macromolecular Chemistry, Kuder Tomasz, Michael A. Kruge

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

The macromolecular compositions of subfossil plants from boreal Sphagnum bogs and restiad bogs (New Zealand) have been studied by pyrolysis-gas chromatography/mass spectrometry to evaluate the extent of degradation in the anoxic zone (catotelm) of a peat bog. Degradation of vascular plant polysaccharides was apparent only into the upper catotelm. Sphagnum was degraded more slowly than vascular plants, but no cessation of degradation was observed. The inferred rate of degradation varied depending on type of plant, extent of aerobic, precatotelmic degradation, and mode of litter deposition (rooting versus at the surface). Environmental forcing on anaerobic carbon dynamics would potentially be largest …

Bacterial Residues In Coprolite Of Herbivorous Dinosaurs: Role Of Bacteria In Mineralization Of Feces, Thomas C. Hollocher, Karen Chin, Kurt T. Hollocher, Michael A. Kruge

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

The Cretaceous Two Medicine Formation of northwestern Montana has yielded blocky, calcareous coprolites that contain abundant fragments of conifer wood and were produced by large herbivorous dinosaurs. The coprolites are generally dark gray to black in color due to a dark substance confined chiefly within what originally were the capillaries of tracheid and ray cells of xylem. This substance is a kerogen which consists in part of thin-walled vesicles 0.1-1.3 µm in diameter. Pyrolysis products of this kerogen are diagnostic of a bacterial origin with a possible contribution from terrestrial plants. The vesicular component is interpreted as the residue of …

Multibeam Sonar Backscatter Lineaments And Anthropogenic Organic Components In Lacustrine Silty Clay, Evidence Of Shipping In Western Lake Ontario, C F Michael Lewis, L A. Mayer, Prasanta K. Mukhopadhyay, Michael A. Kruge, John P. Coakley, M D. Smith

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

A multibeam sonar survey (95 kHz) covering more than 500 km² of western Lake Ontario revealed anomalous lineaments of relatively high backscatter. The lineaments did not align with or parallel the most prominent structural zones beneath the lake as expected. Instead, the principal lineaments lay on lines between ports on opposite sides of the lake, especially between Toronto and Welland Canal, and Toronto and Niagara River mouth. As the lineaments underlie current and historical shipping routes used during the steamship era, they are interpreted as an acoustic response to shipping debris cumulated in the near-surface bottom sediment. An exploratory …

Classification Of Torbanite And Cannel Coal. Ii. Insights From Organic Geochemical And Multivariate Statistical Analysis, Zhiwen Han, Michael A. Kruge

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Petrographic and megascopic criteria have traditionally been used as the basis for the classification of torbanite and cannel coal. For this study, it was hypothesized that modern analytical organic geochemical and multivariate statistical techniques could provide an alternative approach. Towards this end, the demineralized residues of 14 torbanite (rich in Botryococcus-related alginite) and cannel (essentially, rich in organic groundmass and/or sporinite) coal samples were analyzed by pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS). Cluster analysis performed on the Py-GC/MS data clearly distinguished the torbanite from the cannel coal, demonstrating a consistency between the chemical properties and the petrographic composition. All the torbanite …

Classification Of Torbanite And Cannel Coal. I. Insights From Petrographic Analysis Of Density Fractions., Zhiwen Han, Michael A. Kruge, John C. Crelling, David F. Bensley

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Torbanite and cannel coal are considered to be coals because of their low mineral content and overall physical morphology. However, the texture and composition of the organic matter in torbanite and cannel coal are similar to the kerogen occurring in oil shales and lacustrine source rocks. Therefore, understanding the nature and origin of organic components in torbanite and cannel coal is of significance in the study of kerogen and petroleum formation. In this research, a set of torbanites and cannel coals from different locations throughout the world were petrographically characterized and processed using a density gradient centrifugation (DGC) technique. Microscopically, …

Chemistry Of Maceral And Groundmass Density Fractions Of Torbanite And Cannel Coal, Zhiwen Han, Michael A. Kruge

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Microscopically, torbanite and cannel coal are composed of coarser macerals set in a fine-grained to amorphous groundmass. It is often assumed that the amorphous groundmass is genetically related to the distinct macerals. The separation of macerals and groundmass from 14 late Paleozoic torbanite, cannel, and humic coals permits the analysis of individual constituents using elemental analysis and flash pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS). Cluster and principal component analyses of the Py-GC/MS data further reveal the chemical similarities and differences between the various constituents. Pyrolyzates of Botryococcus-related alginites are characterized by an abundance of normal alkadienes, alkenes, and alkanes. Even their …