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Full-Text Articles in Physical Sciences and Mathematics

Petrogenesis Of Basaltic Lavas In Iceland And The Springerville Volcanic Field, U.S.A.: The Influence Of Tectonic Setting, Depth Of Melting And Volatiles, Marissa Mnich Nov 2019

Petrogenesis Of Basaltic Lavas In Iceland And The Springerville Volcanic Field, U.S.A.: The Influence Of Tectonic Setting, Depth Of Melting And Volatiles, Marissa Mnich

Doctoral Dissertations

Icelandic basalts were long thought to be low in water (e.g. Gunnarsson et al., 1998), but more recent studies suggest that hotspots, like the Iceland mantle plume, may be a source of hydrous basaltic melts (Nichols et al., 2002). To explore a possible link between location, volatile concentration and resulting petrogenetic implications, samples were collected from eleven volcanic centers throughout Iceland. Water concentrations were measured in melt inclusions and phenocrysts using Fourier transform infrared (FTIR) spectroscopy. Results for a subset of samples indicate variable water in melt inclusions ranging from approximately 50 ppm to over 3000 ppm. Samples from southwestern …


Middle To Late Pleistocene Paleoenvironmental Reconstructions From Lake El'gygytgyn, Arctic Russia, Mary Helen Habicht Oct 2019

Middle To Late Pleistocene Paleoenvironmental Reconstructions From Lake El'gygytgyn, Arctic Russia, Mary Helen Habicht

Doctoral Dissertations

Climate change is a major issue challenging the world today. Our global society faces rising temperatures, variable weather patterns, and rising sea level among other associated issues. Our action (or inaction) to address current changes will have serious ramifications for life on our planet in the coming centuries and millennia. In order to provide context for these present and future changes, we can utilize the paleo record to understand the natural variability of Earth’s climate system. One region of the world is changing more rapidly than the global average. Over recent decades, the Arctic has experienced warmer temperatures, reduced sea …


Spatial And Temporal Mapping Of Distributed Precipitation, Surface And Groundwater Stable Isotopes Enables Insights Into Hydrologic Processes Operating At A Catchment Scale, Alison Cole Oct 2019

Spatial And Temporal Mapping Of Distributed Precipitation, Surface And Groundwater Stable Isotopes Enables Insights Into Hydrologic Processes Operating At A Catchment Scale, Alison Cole

Masters Theses

Isotopic analyses of d18O and d2H of water through the hydrologic cycle have allowed hydrologists to make better interpretations related to climate and relationships between precipitation, surface water, and groundwater. In this study 394 precipitation samples 1917 surface water samples and 1405 groundwater samples across Massachusetts was used to create an isoscape for each respective water. All samples have been collected by volunteers throughout Massachusetts. A state meteoric water line: d2H = 7.7*d18O + 9.8, surface water line: d2H = 5.7*d18O – 4.2, and groundwater line: d2 …


Sorption Temperature And And The Stability Of Iron-Bound Soil Organic Matter, Michael L. Nguyen Jul 2019

Sorption Temperature And And The Stability Of Iron-Bound Soil Organic Matter, Michael L. Nguyen

Doctoral Dissertations

The preservation of soil organic matter (SOM) is an important control on the global cycling of carbon. Long-term preservation of SOM has important implications on soil fertility and climate regulation. Minerals, such as iron oxides, can react with SOM and serve as a preservation mechanism for SOM. Globally, iron oxide-SOM interactions form a “rusty carbon sink” which protects up to 22% of organic carbon in marine sediments. Climate changes, such as warming, may alter the size or efficacy of the “rusty carbon sink.” The effects of temperature, SOM composition, and mineral particle size on the formation and stability of iron …


Root-Driven Weathering Impacts On Mineral-Organic Associations Over Pedogenic Time Scales, Mariela Garcia Arredondo Mar 2019

Root-Driven Weathering Impacts On Mineral-Organic Associations Over Pedogenic Time Scales, Mariela Garcia Arredondo

Masters Theses

Plant roots are critical weathering agents in deep soils, yet the impact of resulting mineral transformations on the vast deep soil carbon (C) reservoir are largely unknown. Root-driven weathering of primary minerals may cause the formation of reactive secondary minerals, which protect mineral-organic associations (MOAs) for centuries or millennia. Conversely, root-driven weathering may also transform secondary minerals, potentially enhancing the bioavailability of C previously protected in MOAs. Here we examined the impact of root-driven weathering on MOAs and their capacity to store C over pedogenic time scales. I compared soil that experienced root-driven weathering, resulting in the formation of discrete …