Physical Sciences and Mathematics Commons^™

Provenance, Composition And Transport Processes Of Pleistocene-Recent Turbidite Sediments Of The Se Nazca Plate, Odp Site 1232, Kimberly D. Beck

FIU Electronic Theses and Dissertations

A 300 meter sequence of Pleistocene turbidite deposits was recovered on the Nazca Plate at the subducting edge of the Peru-Chile Trench at ODP Site 1232. Analysis of the coarsest particles in the turbidite sequences implies sediment was supplied in some proportion by terrestrial erosion and originated in the coastal, central, and Andean volcanic/magmatic belt which parallels the Southern Chilean coast, and the predominant material type is volcanic. Petrographic and geochemical analyses show that samples from 3 - 140 mbsf contain >43% fresh, angular glass. New calcareous nannofossil biostratigraphy brackets the sediment ages of the upper 288 m of cored …

Hydrologic Properties Of Mangrove And Sawgrass Peat In Shark River Slough, Everglades, Florida, Nicole Cordoba

FIU Electronic Theses and Dissertations

Peat sediments are the foundation of most wetlands, acting as a medium for water to flow through, governed by hydraulic conductivity, and as a potential source of nutrients. Shark River Slough is a known, main fresh waterway for Everglades National Park, distributing essential nutrients and freshwater into the wetland. Hydraulic conductivity was calculated through experimental (both in situ water and higher salinity water) falling head tests performed on mangrove and sawgrass peat cores. Nutrient concentrations were analyzed for the pore water released during hydrologic testing. Hydraulic conductivity values were higher in the sawgrass peat than the mangrove peat. No significant …

Volcanic History Of The Izu Bonin Mariana Arc Prior To The First Arc Rift From Volcaniclastic Sediments Of Dsdp Site 296 And Iodp Site 1438, Eshita Samajpati

FIU Electronic Theses and Dissertations

The Izu-Bonin Mariana (IBM) island arc in the western Pacific basin is a volcanic chain formed by subduction of the Pacific lithospheric plate beneath the Philippine Sea plate. Worldwide, subduction causes high-magnitude earthquakes and explosive volcanic activity in addition to forming the Earth’s continental crust and major ore deposits, thus its understanding is important to human concerns. In the IBM, volcanic activity spans 50 million years to the present and the arc has undergone extension and periodic rifting, preserving remnants of its early history. The Kyushu Palau ridge (KPR), an inactive Oligocene remnant of the rifted IBM system, is a …

Lithological And Geochemical Responses To Abrupt Global And Regional Paleoenvironmental Changes During The Aptian In A Hemipelagic Setting Of The Eastern Iberian Peninsula: A Multi-Proxy Approach, Jander Socorro

FIU Electronic Theses and Dissertations

Intense episodes of environmental perturbations and regionally to globally distributed, oxygen-deprived marine facies characterize the Cretaceous sedimentary record. The Organyà Basin in the Spanish Pyrenees chronicles this period in expanded stratigraphic sequences that enabled high-resolution sampling and detailed analysis of disturbances poorly recorded in more lithologically condensed sections. Here, I present an integrated multi-proxy study aimed at understanding the Basin’s response to changing paleoenvironmental conditions during the early Aptian stage of the Cretaceous.

Results from the El Pui section indicate that large-scale (> 1‰), negative carbon isotope excursions (CIEs) that show no corresponding shifts in local sources of organic matter …

Evaluation Of Pre-Eruptive Conditions For Cordon Caulle Rhyo-Dacitic Historic Eruptions, Mauro Andres Mingo

FIU Electronic Theses and Dissertations

For better understanding of Plinian-hybrid eruptive events, I analyzed the variables that affect the pre-eruptive conditions of the latest three eruptive events of the Puyehue Cordon Caulle Volcanic Complex (PCCVC). The analysis was done by performing a petrological study of lava samples followed by Electron Probe Microanalysis (EPMA) on selected mineral phases. Mineral data were then used in established mathematical models to calculate pre-eruptive magma temperature and water content. The acquired data are compared to bulk measured water content, and the difference is utilized to estimate viscosities and evaluate the degassing regime. Results indicate that the historic eruptive events have …

Identifying The Origins Of Volcanic Ash Deposits Using Their Chemical And Physical Compositions, Emmanuel Soto

FIU Electronic Theses and Dissertations

Recent ocean sediments collected offshore Chile by Ocean Drilling Program Leg 202 contained layers of volcanic ash of unknown origin. These deposits may have originated from sources in the Southern Volcanic Zone (SVZ) within the Andean Volcanic Belt to the east, or from explosive volcanoes in the southwestern Pacific transported by westerly prevailing winds. In this study, mineral and glass textures and compositions of Leg 202 ashes were evaluated to try to determine the sources of the ash layers. Ash fragments were imaged and analyzed for major elements using an SEM with X-Ray detector and for trace elements using LA-ICPMS. …

Water-Rock Interactions And Seasonal Hydrologic Processes In Constructed Everglades Tree Islands, Andres E. Prieto Estrada

FIU Electronic Theses and Dissertations

The decline of tree islands in the freshwater-Everglades wetland because of hydrologic manipulation, has compromised valuable ecosystem services. Although the role of tree islands in maintaining freshwater quality stems largely from evapotranspiration processes, fundamental questions remain about the effects of different geologic materials on their hydrogeochemical functioning. To reduce this uncertainty, the lithological composition of a set of man-made tree islands was investigated coupled with long-term hydrologic and hydrochemical data. Key results indicate that limestone substrates and peat substrates with elevated proportions of sand, facilitated surface water-groundwater interactions and mineral dissolution. However, limestone-based islands were more effective in lowering the …

Hydrogeochemical Modeling Of Saltwater Intrusion And Water Supply Augmentation In South Florida, Yonas T. Habtemichael

FIU Electronic Theses and Dissertations

The Biscayne Aquifer is a primary source of water supply in Southeast Florida. As a coastal aquifer, it is threatened by saltwater intrusion (SWI) when the natural groundwater flow is altered by over-pumping of groundwater. SWI is detrimental to the quality of fresh groundwater sources, making the water unfit for drinking due to mixing and reactions with aquifer minerals. Increasing water demand and complex environmental issues thus force water utilities in South Florida to sustainably manage saltwater intrusion and develop alternative water supplies (e.g., aquifer storage and recovery, ASR).

The objectives of this study were to develop and use calibrated …

Investigation Of The Lead Isotope Signatures Of Marine Sediments In Relation To The Lead Isotope Signatures Of Northern Andean Ores, Kimberly D. Beck

FIU Electronic Theses and Dissertations

Lead isotope ratios of ores and igneous rocks in the Central and Southern Andes show a large-scale geographic pattern related to magmatic source processes. This pattern changes in the Northern Andes for reasons that are not well understood; this study is an investigation of potential causes of this change. Deep ocean sediment samples from the Nazca Plate were analyzed for ²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb and ²⁰⁸Pb/²⁰⁴Pb, and the data were compared with published data on central Andean ores and ores and igneous rocks from Ecuador. Lead isotopic compositions of the Nazca Plate sediments …

Hydrologic Controls Of Coastal Groundwater Discharge In Southern Taylor Slough, Everglades National Park, Florida, Edward Linden

FIU Electronic Theses and Dissertations

This project empirically determined the controls of groundwater discharge potential and surface water chemistry in southern Taylor Slough, Everglades National Park, Florida. Potential for groundwater discharge was calculated as the difference in equivalent freshwater stage between groundwater and surface water on a daily basis for two sites (upland and coastal) along southern Taylor Slough. Upstream water stages were shown to vary most similarly to the timing of groundwater discharge potential in coastal Taylor Slough. Surface water major ion chemistry did not apparently change as a result of groundwater discharge potential. Surface water major ion chemistry at the coastal site was …

Changes Of Soil Biogeochemistry Under Native And Exotic Plants Species, Yujie Hua

FIU Electronic Theses and Dissertations

Invasive plant species are major threats to the biodiversity and ecosystem stability. The purpose of this study is to understand the impacts of invasive plants on soil nutrient cycling and ecological functions. Soil samples were collected from rhizosphere and non-rhizosphere of both native and exotic plants from three genera, Lantana, Ficus and Schinus, at Tree Tops Park in South Florida, USA. Experimental results showed that the cultivable bacterial population in the soil under Brazilian pepper (invasive Schinus) was approximately ten times greater than all other plants. Also, Brazilian pepper lived under conditions of significantly lower available phosphorus …

Paleoenvironments And Geochemical Signals From The Late Barremian To The Middle Aptian In A Tethyan Marginal Basin, Northeast Spain: Implications For Carbon Sequestration In Restricted Basins, Yosmel Sanchez Hernandez Mr.

FIU Electronic Theses and Dissertations

The hallmark of oceanic anoxic event 1a (OAE1a) (early Aptian ~125 Ma) corresponds to worldwide deposition of black shales with total organic carbon (TOC) content > 2% and a d¹³C positive excursion up to ~5‰. OAE1a has been related to large igneous province volcanism and dissociation of methane hydrates during the Lower Cretaceous. However, the occurrence of atypical, coeval and diachronous organic-rich deposits associated with OAE1a, which are also characterized by positive spikes of the d¹³C in epicontinental to restricted marine environments of the Tethys Ocean, indicates localized responses decoupled from complex global forcing factors.

The present …

A Geochemical Study Of Crustal Plutonic Rocks From The Southern Mariana Trench Forearc: Relationship To Volcanic Rocks Erupted During Subduction Initiation, Julie A. Johnson

FIU Electronic Theses and Dissertations

Two suites of intermediate-felsic plutonic rocks were recovered by dredges RD63 and RD64 (R/V KK81-06-26) from the northern wall of the Mariana trench near Guam, which is located in the southern part of the Izu-Bonin-Mariana (IBM) island arc system. The locations of the dredges are significant as the area contains volcanic rocks (forearc basalts and boninites) that have been pivotal in explaining processes that occur when one lithospheric plate initially begins to subduct beneath another. The plutonic rocks have been classified based on petrologic and geochemical analyses, which provides insight to their origin and evolution in context of the surrounding …

Elemental Analysis And Forensic Comparison Of Soils By Laser-Induced Breakdown Spectroscopy (Libs) And Laser Ablation Inductively Coupled Plasma Mass Spectrometry (La-Icp-Ms), Sarah C. Jantzi

FIU Electronic Theses and Dissertations

The elemental analysis of soil is useful in forensic and environmental sciences. Methods were developed and optimized for two laser-based multi-element analysis techniques: laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) and laser-induced breakdown spectroscopy (LIBS). This work represents the first use of a 266 nm laser for forensic soil analysis by LIBS.

Sample preparation methods were developed and optimized for a variety of sample types, including pellets for large bulk soil specimens (470 mg) and sediment-laden filters (47 mg), and tape-mounting for small transfer evidence specimens (10 mg). Analytical performance for sediment filter pellets and tape-mounted soils was similar …

Lower Aptian Comparative Stratigraphy Of The Basco-Cantabrian Region (Spain) And Eastern Cordillera (Colombia): Implications For Local Factors In The Depositional Record Of Oceanic Anoxic Event 1a (Oae-1a), Tatiana Gaona Narvaez

FIU Electronic Theses and Dissertations

An important episode of carbon sequestration, Oceanic Anoxic Event 1a (OAE-1a), characterizes the Lower Aptian worldwide, and is mostly known from deeper-water settings. The present work of two Lower Aptian deposits, Madotz (N Spain) and Curití Quarry (Colombia), is a multiproxy study that includes fossil assemblages, microfacies, X-ray diffraction bulk and clay mineralogy, elemental analyses (major, minor, trace elements), Rock-Eval pyrolysis, biomarkers, inorganic and organic carbon content, and stable carbon isotopes. The results provide baseline evidence of the local and global controlling environmental factors influencing OAE-1a in shallow-water settings. The data also improve our general understanding of the conditions under …