Physical Sciences and Mathematics Commons^™

Geochemical And Isotopic Characterization Of Shallow Basinal Brines From The Makgadikgadi Pans Complex, Northeastern Botswana: Determination Of The Sources Of Salinity, Loago N. Molwalefhe

Dissertations

Isotopes and chemical tracers have been used to constrain the sources and causes of salinity in shallow groundwater brine from the Makgadikgadi Basin, northeastern Botswana. The brine is massively rich in chloride and sodium, and moderately rich in carbonates, sulphate and potassium, and is distinctively poor in divalent cationic species. Various models that have been advanced to explain the origin of the brines include evaporative enrichment at the surface and density-induced infiltration, dissolution of evaporites, and trapped connate water.

This study presents the compositional variability and behaviors of ·the stable isotopes of carbon (S¹³C) and oxygen (S^{18 …}

Support For The Nye County Early Warning Drilling Program, Irene Farnham, Klaus J. Stetzenbach, Amy J. Smiecinski

Publications (YM)

This final report details the activities completed for Task 8 of the University and Community College System of Nevada (UCCSN) Cooperative Agreement with the US Department of Energy (DOE). Task 8, titled "Support for the Nye County Early Warning Drilling Program" provided for a variety of hydrochemical analyses. The requirements of the University and Community College System of Nevada (UCCSN) Quality Assurance (QA) Program were followed for all work performed on this task. The primary activity performed by the Harry Reid Center for Environmental Studies (HRC) for Task 8 was to provide hydrochemical analyses of the groundwater samples collected from …

Sulfide Mineralization In Deep-Water Marine Sediments Related To Methane Transport, Methane Consumption, And Methane Gas Hydrates, Matthew K. Thompson, Walter S. Borowski, Charles K. Paull, William Ussler Iii

EKU Faculty and Staff Scholarship

Patterns of sulfide sulfur concentration and sulfur isotopic composition (d³⁴S) are perhaps related to upward methane transport, especially in sediments underlain by methane gas hydrate deposits. Increased methane delivery augments the affect of anaerobic methane oxidation (AMO) occurring at the sulfate-methane interface (SMI). Sulfate and methane co-consumption results in production of dissolved sulfide at the interface that is eventually sequestered within sulfide minerals (elemental sulfur, iron monosulfide, pyrite).

We examine the sediments of two piston cores collected over the Blake Ridge gas hydrate deposits (offshore southeastern North America) by extracting total sedimentary sulfide using chromium reduction. We use …

Geogram 2003, David J. Keeling Editor, Wku Department Of Geography And Geology

Earth, Environmental, and Atmospheric Sciences Publications

No abstract provided.

Dissolved Humic Substances: Characterization Of Their Sorption Onto Iron Hydroxide Aluminum Hydroxide Kaolinite And Smectite, Sarah E. Diebel

OES Theses and Dissertations

Humic (HA) and fulvic (FA) acids participate in many geochemical processes and the mechanisms of their sorption to colloidal surfaces are numerous, indicating these substances are complex and heterogeneous. The current study focuses on the interactions of the Fe hydroxide (FE), Al hydroxide, Kaolinite (KA) and Smectite (SM) and these naturally occurring organic acids using Fourier Transform Infrared Spectroscopy (FTIR) and DOC analysis at pH 4. FTIR was used for the initial functional group characterization, as well as the comparison of before and after adsorption spectra of the HA and FA. DOC examined the amounts of HA and FA adsorbed …

Exploring Links Between Physical And Probabilistic Models Of Volcanic Eruptions: The Soufriere Hills Volcano, Montserrat, Charles B. Connor, R. S. J. Sparks, R. M. Mason, Costanza Bonadonna, S. R. Young

Geology Faculty Publications

Probabilistic methods play an increasingly important role in volcanic hazards forecasts. Here we show that a probability distribution characterized by competing processes provides an excellent statistical fit (>99% confidence) to repose intervals between 75 vulcanian explosions of Soufrière Hills Volcano, Montserrat in September–October, 1997. The excellent fit is explained by a physical model in which there are competing processes operating in the upper volcano conduit on different time scales: pressurization due to rheological stiffening and gas exsolution, and depressurization due to development of permeability and gas escape. Our experience with the Soufrière Hills Volcano eruption sequence suggests that volcanic …

Hydrogeologic Principles Useful In Predicting The Effects Of Stream Flow Alterations On Shallow Groundwater And Associated Riparian Vegetation, Mark Cable Rains

Geology Faculty Publications

Numerous studies have shown that stream water and shallow groundwater are tightly linked in alluvial settings, and that changes in stream stage are propagated rapidly across alluvial aquifers (Castro and Hornberger 1991, Sophocleous 1991). Thus, many researchers have assumed that stream stages approximate water tables in alluvial aquifers (Auble et al. 1994, Stromberg and Patten 1996). This assumption is valid in some cases but invalid in other cases, particularly in arid basin terrain and more humid mountain terrain. Even when this assumption is valid, this relationship only implies correlation and not causation so the potential effects of stream flow alterations …

Antarctic Oversnow Traverse-Based Southern Hemisphere Climate Reconstruction, Paul Andrew Mayewski

Earth Science Faculty Scholarship

On 2 January 2003, the U.S. component of the International Trans Antarctic Scientific Expedition (U.S. ITASE) (Figure 1) arrived at the South Pole after completing more than 5000 km of oversnow traverses that included much of west Antarctica and a portion of east Antarctica (Figure 2). During the traverses, which were performed from 1999 through 2003, U.S. ITASE focused on collecting data that will allow the reconstruction of sub-annual scale climate variability and changes in the chemistry of the atmosphere over the last 200+ years.

ITASE is a multi-disciplinary research program supported by 19 nations and endorsed by the Scientific …

Melting Processes And Fluid And Sediment Transport Rates Along The Alaska-Aleutian Arc From An Integrated U-Th-Ra-Be Isotope Study, Rhiannon George, Simon Turner, Chris Hawkesworth, Julie Morris, Chris Nye, Jeffrey G. Ryan, Shu-Hui Zheng

Geology Faculty Publications

A comprehensive data set for young lavas erupted along the Alaska-Aleutian arc is used to examine how fluid and sediment transport rates and melting processes vary in response to systematic changes in subduction rate and dip along the arc and across the ocean-continent boundary. Positive correlations between convergence rate, volcano volume, and ²³⁸U excesses suggest that magmatic output is closely linked to the size of the fluid flux which occurred <10 kyr prior to eruption. Sediment-sensitive tracers like Th/Nb, Ce/Ce*, and ¹⁰Be/⁹Be also increase with convergence rate. However, the inferred ¹⁰Be/⁹Be ratio of this component is low relative to that in the incoming sediments, …

A Geochemical Survey Of The Natural Waters Of Belize, Central America, Anthony D. Marfia

Masters Theses

A geochemical survey of the natural waters in Belize, Central America was carried out to compliment routine water quality analysis and to identify processes affecting water quality. The objective of this research was to provide a geochemical assessment of natural waters throughout Belize by examining select major ions (Ca²⁺, Mg²⁺ , SO₄^2-), and stable isotopes of carbon (¹³C), oxygen (¹⁸O) and hydrogen (²H).

The dominant geology relevant to this investigation comprises a varied landscape of carbonates and elastic sediments in a subtropical rainforest/savannah climate. Stable oxygen and hydrogen …

Enrichments Of 34s In Sulfide Minerals Of Deep-Water Marine Sediments Of The Blake Ridge, Offshore Southeastern United States, Kathryn G. Takacs, Walter S. Borowski

EKU Faculty and Staff Scholarship

Past research shows that active sulfide mineralization occurs at the base of the sulfate reduction zone (SRZ) in modern, deep-water, continental-margin sediments that overlie methane gas hydrate. These sulfide minerals (elemental sulfur, Sº; iron monosulfides, ~FeS; and pyrite, FeS₂) are enriched in ³⁴S because of sulfate reduction and anaerobic methane oxidation (AMO) processes occurring above and near the sulfate-methane interface (SMI).

The data in this study show that 5 discrete zones of sulfide minerals are preserved in a 703.8-meter sediment column associated with methane gas hydrate. These zones of sulfide minerals are also enriched in ³⁴S. …

Energy‐Constrained Open‐System Magmatic Processes Iv: Geochemical, Thermal And Mass Consequences Of Energy‐Constrained Recharge, Assimilation And Fractional Crystallization (Ec‐Rafc), Wendy A. Bohrson, Frank J. Spera

All Faculty Scholarship for the College of the Sciences

A wealth of geochemical and petrological data provide evidence that the processes of fractional crystallization, assimilation, and magma recharge (replenishment) dominate the chemical signatures of many terrestrial igneous rocks. Previous work [Spera and Bohrson, 2001; Bohrson and Spera, 2001] has established the importance of integrating energy, species and mass conservation into simulations of complex magma chamber processes. An extended version of the energy‐constrained formulation, Energy‐Constrained Recharge, Assimilation, Fractional Crystallization (EC‐RAFC), tracks mass and compositional variations of melt, cumulates, and enclaves in a magma body undergoing simultaneous recharge, assimilation, and fractional crystallization [Spera and Bohrson, 2002]. …

Preliminary Investigations Of Seasonal Changes In The Geochemical Evolution Of The Logdson River, Mammoth Cave, Kentucky, Chris Groves, Darlene M. Anthony, Joe Meiman

Earth, Environmental, and Atmospheric Sciences Faculty Publications

Many geochemical studies have been made of karst waters worldwide. Most data that provide the framework for our current understanding of the evolution of karst waters have come from sampling at discrete times and locations, such as springs or wells. Relatively few studies have been made of the geochemical evolution of groundwater as it moves through an open flow system. This paper addresses the seasonal changes in the geochemistry of the Logsdon River conduit as it passes through nearly 10km of the carbonate aquifer of south-central Kentucky . The most important control on the ability of groundwaters to dissolve limestone …

Preliminary Investigations Of Seasonal Changes In The Geochemical Evolution Of The Logdson River, Mammoth Cave, Kentucky, Chris Groves, Darlene M. Anthony, Joe Meiman

Chris Groves

Many geochemical studies have been made of karst waters worldwide. Most data that provide the framework for our current understanding of the evolution of karst waters have come from sampling at discrete times and locations, such as springs or wells. Relatively few studies have been made of the geochemical evolution of groundwater as it moves through an open flow system. This paper addresses the seasonal changes in the geochemistry of the Logsdon River conduit as it passes through nearly 10km of the carbonate aquifer of south-central Kentucky . The most important control on the ability of groundwaters to dissolve limestone …

Stable Sulfur Isotope Rations From West Antarctica And The Tien Shan Mountains: Sulfur Cycle Characteristics From Two Environmentally Distinct Areas, Lee Pruett

Electronic Theses and Dissertations

Continuous snow pit and ice core samples from two distinct environments (West Antarctica and the Tien Shan mountains in central Asia) were analyzed for 6 3 4 ~ and used to assess different regional sulfur cycle characteristics. In West Antarctica, 18 continuous samples were obtained from the RIDSA ice core (78.73"S, 116.33"W, 1740 m asl), covering the years 1935 to 1976. Each sample represents from 2 to 3 years of snow deposition, and the combination of summer and winter seasons varies by sample. 6 3 4 ~ values range from 3.1 %O to 9.9%0, and reflect the overall isotopic composition …

Rare-Earth Elements And Nd And Pb Isotopes As Source Indicators For Labrador Sea Clay-Size Sediments During Heinrich Event 2, Larry V. Benson, Don Barber, John T. Andrews, Howard E. Taylor, Paul Lamothe

United States Geological Survey: Staff Publications

Elemental abundances and Nd and Pb isotope ratios were determined on samples from the carbonate-free, clay-size fractions of sediments from intervals above, within, and below Heinrich event 2 (H-2) in core HU87-9 from the Northwest Labrador Sea slope. In HU87-9, rare-earth element (REE) distributions and elemental concentrations within the H-2 event are distinct from those outside this event. ɛ_Nd(0) and ²⁰⁶Pb/²⁰⁴Pb data also indicate different values for sediments deposited within and outside the H-2 event. Comparisons of REE patterns from the H-2 interval with those from bedrock units in Baffin Island, northern Quebec, and Labrador …

Methods And Models For Estimating Advective Pore Water Exchange In Tidal Flats, Timothy J. Shaw

Faculty Publications

No abstract provided.

Laboratory Oxide Coatings: Physical Form And Surface Chemistry, Kea U. Duckenfield

Dissertations, Theses, and Masters Projects

The impact of dissolved trace metals on aquatic ecosystems and human health is controlled by sorption, i.e., binding to the surfaces of environmental particles. Since many environmental particles are coated with highly reactive substances, and since discrepancies in trace metal sorption behavior persist between oxides developed in the laboratory and environmental oxide phases, it was hypothesized that the physical form of oxide coatings may influence the chemical properties of the coated particle. Therefore, relationships between the physical forms of several different Fe(III) oxide coatings and the Cu(II) sorption behavior of the coated solids were investigated in comparison with the component …

Polycyclic Aromatic Hydrocarbon Sources And Distribution In An Urban Estuary, Shelby E. Walker

Dissertations, Theses, and Masters Projects

As part of the assessment of the potential risk posed by contaminated sediments to the environment and human health, the United States Environmental Protection Agency (USEPA) is developing a set of sediment quality criteria (SQC) that are based on equilibrium partitioning (EqP). While EqP theory has often been used to predict contaminant concentrations within a factor of two for a range of sediment types, substantial deviations from predicted values have also been documented. The objective of this research was to evaluate the influence of PAH source on PAH sediment-pore water partitioning and distribution in sediments. The Elizabeth River is one …