Physical Sciences and Mathematics Commons^™

Hydrogeology And Hydrogeochemistry Of The Shallow Alluvial Aquifer Zone, Las Vegas Valley, Nevada, Harry Stephen Wild Jr.

UNLV Theses, Dissertations, Professional Papers, and Capstones

In Las Vegas Valley, Nevada, the shallow alluvial aquifer zone is a possible source of contamination to the principal alluvial aquifers that provide 30% of the public drinking water supply for the valley. Development of the principal aquifers has lowered pressure head in the principal aquifers and created the potential for downward seepage from the shallow aquifer zone. This study was undertaken to characterize the hydrogeology and hydrogeochemistry of the shallow alluvial aquifer zone and to compare the hydrogeochemistry of the shallow and principal alluvial aquifer zones.

A 37 well shallow ground water monitoring network was established and water-level, water-quality, …

Trace Metals And Pyrite In Sediments Of Chesapeake Bay, Robert S. Kluckhohn

OES Theses and Dissertations

The formation and cycling of iron sulfides within anoxic sediments can affect the cycling of trace metals. The sediments at station CB-27 (near Annapolis, Maryland) in Chesapeake Bay were rich in FeS (39% of TS), low in greigite (3.6% of TS), and has a relatively constant pyrite concentration (50 - 60% of TS) with depth. The percent composition of total metals in pyrite were 25.7% cu, 11.8% Zn, 15.8% Fe, and non-detectable to 2.1% Cd. At Station CB- 28 (near the Choptank River), the sediments were low in FeS (1.7% of TS), richer in greigite (up to 14% of TS), …

Hydrogeology And Hydrogeochemistry Of The Tekonsha Moraine And Adjacent Interlobate Deposits In Charleston Township, Kalamazoo County, Michigan, Victor V. Melbardis

Masters Theses

Hydrogeochemical analyses and hydrogeologic interpretations provide the basis for an understanding of local ground-water flow, in a 12 square mile study area, transected by the Tekonsha Moraine and bound by glaciofluvial deposits. Glacial tills separate an upper and lower aquifer system throughout most of the area.

Degraded and tritiated ground water is present in the lower aquifer system. A negative correlation (-0.62) between tritium concentrations and depth is statistically significant (.04). In this local system, hydrochemical trends are characterized by decreases in sulfate percentages and increases in bicarbonate in the direction of ground-water flow. Statistical evaluation of the hydrochemical data …

Metal Mobilization From A Near-Shore Lake Sediment Under Simulated Acidic Groundwater Inputs, Raveendra V. Ika

OES Theses and Dissertations

Simulation of acidic groundwater passing through lake sediments was conducted under controlled conditions in a laboratory. Three sediment cores collected intact from the near-shore region of an acidic lake were subjected to simulated groundwater inputs of initially identical chemistry for a seven day period. Following this period water being used in the simulation for two of the sediment cores was acidified by hydrochloric acid (HC1) addition to examine the ability of these sediments to neutralize acidic groundwater with varying H⁺ concentration.

Simulated acidic water passing through the sediment cores mobilized significant amounts of metals. The sediment acted as a …

A Comparison Of Metals In Several Ahermatypic Corals And Surficial Sediments: Mobile Pinnacles And Hoffa Reef, Northcentral Gulf Of Mexico, Kathryn M. Conko

OES Theses and Dissertations

Metal concentrations in marine sediment and carbonate secreting invertebrates are representative of surrounding environmental chemistry. Aluminum, Ba Ca, Cd, Cr, Cu, Fe, Mg, Mn, Ni, Pb, Sr, and Zn were measured in carbonate and terrigenous phases of the $<$63 um fraction of sediment samples from two locations in the northcentral Gulf of Mexico. Enrichment factors indicate that Al, Ba, Cu, Cr, Mg, Mn, and Ni are all slightly depleted in these sediments relative to crustal abundances. Discriminant function analyses shows that the concentrations of five elements differ between locations.

Ahermatypic coral (106 specimens) from five genera collected from the study sites were analyzed for Cd, Cu, Cr, Pb, Zn, Mn, Sr, Ba, Fe, Ca and Mg. Eight elements vary between some genera, Al and Ba also vary in concentration in corals between either location. All elements except Sr are significantly depleted in the coral with respect to Ca in the …

Mi̇neral Phases In The Edi̇ge Ophiolite Body, Ayla Tankut, Naci M. Sayin

Bulletin of the Mineral Research and Exploration

No abstract provided.

Nterpretation Of New Geochemical, Radiometric And Isotopic Data On Eastern And Southeastern Anatolia, Tuncay Ercan, Tatsuya Fuji̇tani̇, Jun-Ichi Matsuda, Kenji Notsu, Selçuk Tokel, Tadahide Ui̇

Bulletin of the Mineral Research and Exploration

No abstract provided.

A Northern Hemisphere Volcanic Chemistry Record (1869-1984) And Climatic Implications Using A South Greenland Ice Core, W. B. Lyons, Paul Andrew Mayewski, M. J. Spencer, M. S. Twickler, T. E. Graedel

Earth Science Faculty Scholarship

The effect of volcanic emISSIOn of acidic aerosols on climate is well documented. The presence of acid droplets in the stratosphere can reduce transmissivity and hence decrease surface temperatures. Since the amount and chemical composition of erupted material has important effects on regional climate, knowledge of past volcanic events is of extreme importance. Detailed glaciochemical records provide the only milieu wherein the geochemistry of paleovolcanic events can be fully documented. We present a detailed sulfate and chloride record from an ice core drilled at site 20 D, 40 km SW of Dye 3 in southern Greenland. The record spans the …

Detailed Glaciochemical Investigations In Southern Victoria Land, Antarctica — A Proxy Climate Record, Paul Andrew Mayewski

Earth Science Faculty Scholarship

The production of environmental change records using time-series data retrieved from ice cores has seen minimal application in the Transantarctic Mountains despite the existence of a well-developed lower resolution glacial geologic record for this area which forms the primary basis for understanding the glacial history of East Antarctica. In addition, records derived from marine and lake cores, glacier margin fluctuation studies, measures of volcanic activity, and meteorological data sets from within or close to the Transantarctic Mountains are available for comparison. This emerging environmental data-base provides the tools needed to define the change characteristics, over a period of thousands of …

A 1400-Year Oxygen Isotope History From The Ross Sea Area, Antarctica, P. M. Grootes, M. Stuiver, T. L. Saling, Paul Andrew Mayewski, M. J. Spencer, R. B. Alley, D. Jenssen

Earth Science Faculty Scholarship

Four ice cores from the Ross Sea drainage, Antarctica, show patterns of δ¹⁸O variations on a time scale of decades to centuries over the last 1400 years without change in the long-term average δ¹⁸O. Century scale δ¹⁸O fluctuations in the two cores drilled in the Ross Ice Shelf at Station J-9 (82° 23' S, 168° 38' W, elevation 60 m) are highly correlated (P < 2 x 10^-4). The long isotope record (>30 000 a) of the 1978 1-9 core thus represents local conditions over at least 102 m and on time scales of 100 …

A Review Of Central Asian Glaciochemical Data, Cameron P. Wake, Paul Andrew Mayewski, Mary Jo Spencer

Earth Science Faculty Scholarship

The glaciers of central Asia provide suitable locations from which to recover continuous, high-resolution glaciochemical records on a continental scale. Although the glaciochemical investigations undertaken to date in central Asia are few in number and limited in terms of spatial coverage and length of record, some preliminary observations can be made concerning regional and seasonal trends in snow chemistry in this region.
The sodium chloride ratio for most snow samples collected in central Asia approaches the ratio found in sea water (0.86 in μeq kg^-1), reflecting a marine source for these constituents. Sodium and chloride concentrations are, on …

A Glaciochemical Survey Of The Summit Region, Greenland, Paul Andrew Mayewski, M. J. Spencer, M. S. Twickler, S. Whitlow

Earth Science Faculty Scholarship

Spatial representativeness and an understanding of controls on chemical species distribution are essential requirements of any significant ice core investigation. Snowpit studies provide an essential tool in this process. In preparation for the central Greenland deep drilling effort a series of snowpits was sampled in detail for oxygen isotopes, major anions, major cations, total acidity and radionuclides. The results of this sampling program are used to define: (I) the chemical composition of the snow in the region, (2) the input timing and spatial distribution of major chemical species, (3) the potential dependence of species concentration on accumulation rate, and (4) …

Geochemistry Of Garnet Xenocrysts And Garnet-Bearing Xenoliths In Ordovician Bentonites, Barbara Bock

Geology Theses and Dissertations

Within outcrops of the black Utica shales south of the Mohawk Valley narrow re-entrants parallel with stratification are visible, often accompanied -by a marked orange-staining of the underlying strata. These rentrant features indicate the presence of bentonites weathered back faster then the enclosing shales. These bentonites are presumably magmatic ashes related to extensive volcanism when an island arc collided with the North American continent in the late Ordovician about 450 million years ago (Taconic orogeny).
Bentonites are good stratigraphic markers because of the short time-interval they represent and the large area they cover. Therefore they are commonly used as correlation …

Petrology And Major Element Geochemistry Of Basaltic Glasses From The Blanco Trough, Northeast Pacific, Glenn A. Gaetani

Geology Theses and Dissertations

The original electron microprobe analyses of suite of basaltic glasses recovered in 1968 by W.G. Melson and co-workers from the Blanco Trough have extremely unusual characteristics. Their compositions plot in a region of the normative Ol-Di-Pl-SiO2 tetrahedron which suggests that they represent liquids in equilibrium with an upper mantle assemblage of olivine + orthopyroxene at 10-15 kb. Given the present state of controversy surrounding the composition and depth of origin of primary MORB, natural examples of such liquids would be very important. The major element variations observed in the suite imply that the dominant phases are olivine and an iron-aluminum …

Application Of A Trace Element Fractionation Model To Cumulate Gabbroic Xenoliths Of Mauna Kea, Hawaii, Ulrike Eberle

Geology Theses and Dissertations

A trace element fractionation model originally designed to relate plutonic rocks containing a trapped glass component to a complementary volcanic rock suite was applied to olivine and opaque-oxide gabbroic xenoliths from the summit cone of Mauna Kea, Hawaii.
The mathematical model which is based on the Rayleigh Fractionation Law was extended to include the various phases present in these two groups of gabbros and was generalized to treat multiple trace elements, in this case four. These results were incorporated in a new FORTRAN program using the interval-bisection method to greatly improve the convergence time in the numerical solutions.
Calculated results …

Origin, Sedimentary Geochemistry, And Correlation Of Middle And Late Ordovician K-Bentonites: Constraints From Melt Inclusions And Zircon Morphology, Carsten Schirnick

Geology Theses and Dissertations

The present study of Paleozoic K-bentonites demonstrates that the geochemistry of melt inclusions and the morphology of zircons can be studied by inexpensive and simple-to-use methods, which rely on phenocrysts. Constraints are obtained that lead to (a) the origin of these altered volcanic ashes, (b) the geochemistry of ash-to-K-bentonite-alteration, and (c) the reliable correlation of extensively altered volcanic ashes (i.e. K-bentonites).
Silicic melt inclusions (i.e. non-devitrified) have been found in quartz and zircon phenocrysts contained within Ordovician and Devonian K-bentonites from New York State, the Upper Mississippi Valley, and Pennsylvania. Origin, source, and tectonic setting of the volcanism that produced …

Characterization Of Organic Sulfur Compounds In Coals And Coal Macerals, Stephen R. Palmer, Edwin J. Hippo, Michael A. Kruge, John C. Crelling

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Peroxyacetic acid oxidation has been used to investigate the type and distribution of organic sulfur species in samples of vitrinite, sporinite and inertinite, separated from the Herrin No.6 and an Indiana No.5 coal seam. It was established that organic sulfur species were selectively preserved during oxidation and their analysis led to some of the first sulfur-33 NMR spectra obtained for coal. The effects of maceral separation processes on model compounds were also studied. Results from our studies support the following conclusions: 1). Different macerals have different distributions and types of organic sulfur species. 2). Organic sulfur compounds in coal occur …

Mining In Maine : Past, Present, And Future, Carolyn A. Lepage

Maine Collection

Mining in Maine : Past, Present, and Future

by Carolyn A. Lepage, Michael E. Foley, and Woodrow B. Thompson

Maine Geological Survey, Department of Conservation, Augusta, Me., 1990.

Contents: Introduction / The Early Years: Pre-Civil War / The Civil War to World War II / The War Years of the 1940's / The Postwar Years: 1940's to 1960 / The 1960's / The 1970's / Maine Mineral Resources Association / The 1980's / Current Mining and Exploration / Future Potential / Acknowledgments / References

Geochemistry Of Selected Maine Peat Deposits, Stephen A. Norton

Maine Collection

Geochemistry of Selected Maine Peat Deposits

by Steven Allen Norton

Maine Geological Survey, Department of Conservation, Augusta, Maine, 1990.

Contents: Introduction / Purpose of Study / Location of Study Sites / Methods / Acknowledgements / Results / Water Chemistry / Dating of Short Cores / Chemistry of Short Cores / Core Interpretations / Summary / References Cited

Geochemical Evolution Of Ferruginous Bauxite Deposits In Northwestern Oregon And Southwestern Washington, Joseph Michael Fassio

Dissertations and Theses

Ferruginous bauxite deposits developed from flows of the Columbia River Basalt Group in northwestern Oregon and southwestern Washington. Samples of the iron pisolite and the gibbsite nodular zones from the upper portion of the weathering profile of drill core from Columbia County, Oregon and Cowlitz County, Washington, were analyzed by instrumental neutron activation. The mineralogy was determined using Xray diffraction and Mossbauer spectroscopy.

The gibbsite nodular zone is above the clay-rich saprolite or relic basalt zone. The nodules contain relic vesicles and well preserved relic plagioclase microlites. Gibbsite occurs with poorly crystalline goethite and hematite in the gibbsite nodular zone. …

Biological Markers In Lower Jurassic Synrift Lacustrine Black Shales, Hartford Basin, Connecticut, U.S.A., Michael A. Kruge, John F. Hubert, Jay F. Akes, Paul E. Meriney

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

The East Berlin Formation (Lower Jurassic, Hartford basin, Connecticut, U.S.A.) is distinctive for its six cyclic units of lacustrine black shale and gray mudstone. separated by playa and fluvial redbeds. The black shales arc each about a meter thick and were deposited in subtropical, thermally stratified, oligomictic lakes, the youngest of which (lakes 3 through 6) were large enough to flood most of the basin and attained depths of several tens of meters.

The saturate fractions of solvent extracts of organic-rich black shales from each of the six lakes, collected at fresh roadcuts near East Berlin, arc dominated by extended …

Organic Geochemistry Of A Lower Jurassic Synrift Lacustrine Sequence, Hartford Basin, Connecticut, U.S.A., Michael A. Kruge, John F. Hubert, David F. Bensley, John C. Crelling, R Jay Akes, Paul E. Meriney

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Synrift terrestrial strata of the Lower Jurassic East Berlin Formation (Hartford basin, Connecticut, U.S.A.) record cyclical expansion and contraction of major lakes, six of which were deep enough to develop anoxic bottom waters. We have studied one representative lacustrine sequence in detail, sampling a new roadcut near the village of East Berlin. The section examined is 4 m thick, with a gray siltstone at the base, deposited in shallow water, overlain by an organic-rich black shale (deep water), succeeded in turn by another gray siltstone, deposited as the lake waters gradually receded. The upper gray siltstone is chemically distinct from …